Citation: Zhen Fang, Yuting Liang, Xiaomei Wang, Shuhan Zhang, Jun Yu, Hu Xu, Yuhong Wang. A novel phosphorus oxide quantum dots as an emissive nanomaterial for inorganic ions screening and bioimaging[J]. Chinese Chemical Letters, ;2021, 32(9): 2856-2860. doi: 10.1016/j.cclet.2021.02.024 shu

A novel phosphorus oxide quantum dots as an emissive nanomaterial for inorganic ions screening and bioimaging

Research Institute of Applied Catalysis, School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China

xuhu@sit.edu.cn

yuhong_wang502@sit.edu.cn

Received Date: 6 November 2020
Revised Date: 10 January 2021
Accepted Date: 9 February 2021
Available Online: 15 February 2021

Figures(4)

In this work, a novel blue-green fluorescence phosphorous oxide quantum dots (PO QDs) was synthesized by solvothermal method in N-methyl-2-pyrrolidone (NMP) solution without any protection treatment during synthesis. Upon excitation at 400 nm, PO QDs emitted blue-green fluorescence with quantum yield of 0.28. PO QDs exhibited the high inertness to air or moisture, the excellent water solubility, and stable emission intensity in a wide pH range and in high ionic strength solution. Interestingly, PO QDs could give the positive optical response to iron ions (Fe³⁺) and iodine ion (I⁻). The photoluminescence (PL) of PO QDs could be directly quenched by Fe³⁺. While I⁻ quenched the PO QDs PL by means of Ag⁺-mediated PO QDs system via the internal filtration effects (IFE) induced by the formation of AgI. Moreover, the biocompatibility and low toxicity of PO QDs verified in bean sprout and Hela cells indicated the promising application of PO QDs in medicine related fields. Furthermore, PO QDs could also be utilized in luminescent composite film for various application scenarios
- Phosphorus oxide quantum dots,
- Emissive material,
- Bioimaging,
- Ion screening,
- Iodine ion,
- Iron ion
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