Citation: Nan Hao, Yu Qiu, Jinwen Lu, Xu Han, Yaqi Li, Jing Qian, Kun Wang. Flexibly regulated electrochemiluminescence of all-inorganic perovskite CsPbBr₃ quantum dots through electron bridge to across interfaces between polar and non-polar solvents[J]. Chinese Chemical Letters, ;2021, 32(9): 2861-2864. doi: 10.1016/j.cclet.2021.01.029 shu

Flexibly regulated electrochemiluminescence of all-inorganic perovskite CsPbBr₃ quantum dots through electron bridge to across interfaces between polar and non-polar solvents

Nan Hao ^a,, ,
Yu Qiu ^a ,
Jinwen Lu ^a ,
Xu Han ^c ,
Yaqi Li ^d ,
Jing Qian ^a ,
Kun Wang ^{a, b,,}

a.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China
b.
Key Laboratory of Sensor Analysis of Tumor Marker, Ministry of Education, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
c.
Science and Technology on Space Physics Laboratory, Beijing 10076, China
d.
School of Grain Science and Technology, Jiangsu University of Science and Technology, Zhenjiang 212003, China

Corresponding author: Nan Hao, hn@ujs.edu.cn Kun Wang, wangkun@ujs.edu.cn
Received Date: 15 October 2020
Revised Date: 3 December 2020
Accepted Date: 15 January 2021
Available Online: 20 January 2021

Figures(4)

All-inorganic perovskite quantum dots (QDs) have attracted great interests due to its outstanding properties. But their poor stability in polar solvents seriously hampered wide applications in analytical chemistry. In this work, strong, stable and flexibly regulated the electrochemiluminescence (ECL) emission form CsPbBr₃ QDs was successfully obtained and applied in the analysis of polar solvents through the unique structure of closed bipolar electrode (BPE). To demonstrate the feasibility, it was successfully used in the detection of tetracycline (Tc) aqueous solution. CsPbBr₃ QDs was immersed into organic solution in anode microcell of closed BPE while Tc aqueous solution was added into cathode microcell. The two microcells were physically separated and would not interfere with each other. But the bio-recognition event between aptamer and Tc in cathode microcell would induce the ECL signal change in anode microcell through the electrons conducted by BPE as the bridge. The ECL emission can be flexibly regulated by environmental factors of both polar and non-polar solvents and the interface status of the BPE. Compared with traditional methods to overcome the intrinsic instability in polar medium, the reported method does not need any further surface modifications, has no limitations on the targets and can provide wide development space for further deep research, which may open a new direction for the ECL sensing of CsPbBr₃ QDs.
- Electrochemiluminescence,
- Perovskite,
- Quantum dots,
- Closed bipolar electrode,
- Tetracycline
1. [1]
  L. Protesescu, S. Yakunin, M.I. Bodnarchuk, et al., Nano Lett. 15(2015) 3692-3696. doi: 10.1021/nl5048779
2. [2]
  A. Swarnkar, V.K. Ravi, A. Nag, ACS Energy Lett. 2(2017) 1089-1098. doi: 10.1021/acsenergylett.7b00191
3. [3]
  F. Palazon, Q.A. Akkerman, M. Prato, et al., ACS Nano 10(2016) 1224-1230. doi: 10.1021/acsnano.5b06536
4. [4]
  M. Saliba, T. Matsui, K. Domanski, et al., Science 354(2016) 206-209. doi: 10.1126/science.aah5557
5. [5]
  Y. Cao, W. Zhu, H. Wei, et al., Anal. Chem. 92(2020) 4123-4130. doi: 10.1021/acs.analchem.0c00070
6. [6]
  H. Peng, W. Wu, Z. Huang, et al., Electrochem. Commun 111(2020) 106667.
7. [7]
  C. Chen, Q. Cai, F. Luo, Anal. Chem. 91(2019) 15915-15921. doi: 10.1021/acs.analchem.9b04387
8. [8]
  Z. Cai, F. Li, W. Xu, et al., Nano Res. 11(2018) 1447-1455. doi: 10.1007/s12274-017-1760-7
9. [9]
  Y. Huang, M. Fang, G. Zou, et al., Nanoscale 8(2016) 18734-18739. doi: 10.1039/C6NR06456F
10. [10]
  Y. Huang, X. Long, D. Shen, et al., Inorg. Chem. 56(2017) 10135-10138. doi: 10.1021/acs.inorgchem.7b01515
11. [11]
  J. Xue, Z. Zhang, F. Zheng, et al., Anal. Chem. 89(2017) 8212-8216. doi: 10.1021/acs.analchem.7b02291
12. [12]
  L. Li, Z. Zhang, Y. Chen, et al., Adv. Funct. Mater. 29(2019) 1902533. doi: 10.1002/adfm.201902533
13. [13]
  A. Arora, J.C.T. Eijkel, W.E. Morf, et al., Anal. Chem. 73(2001) 5633-5633. doi: 10.1021/ac011762v
14. [14]
  L. Koefoed, S.U. Pedersen, K. Daasbjerg, Curr. Opin. Electrochem. 2(2017) 13-17. doi: 10.1016/j.coelec.2017.02.001
15. [15]
  O. Phuakkong, M. Sentic, H. Li, et al., Langmuir 32(2016) 12995-13002. doi: 10.1021/acs.langmuir.6b03040
16. [16]
  M.H. Khan, H. Bae, J. -Y. Jung, J. Hazard. Mater. 181(2010) 659-665. doi: 10.1016/j.jhazmat.2010.05.063
17. [17]
  W. Yang, F. Zheng, Y. Lu, et al., Ind. Eng. Chem. Res. 50(2011) 13892-13898. doi: 10.1021/ie202166g
18. [18]
  L. Zhou, D.J. Li, L. Gai, et al., Sens. Actuator B: Chem. 162(2012) 201-208. doi: 10.1016/j.snb.2011.12.067
19. [19]
  X.D. Zhu, Y.J. Wang, R.J. Sun, et al., Chemosphere 92(2013) 925-932. doi: 10.1016/j.chemosphere.2013.02.066
20. [20]
  L. Long, Y. Han, X. Yuan, et al., Food Chem. 331(2020) 127359. doi: 10.1016/j.foodchem.2020.127359
21. [21]
  J. Qian, H. Cui, X. Lu, et al., Chem. Eng. J. 401(2020) 126017. doi: 10.1016/j.cej.2020.126017
22. [22]
  X. Lin, L. Zheng, G. Gao, et al., Anal. Chem. 84(2012) 7700-7707. doi: 10.1021/ac300875x
23. [23]
  S. Wu, Z. Zhou, L. Xu, et al., Biosens. Bioelectron. 53(2014) 148-153. doi: 10.1016/j.bios.2013.09.042
24. [24]
  X. Zhang, C. Chen, J. Li, et al., Anal. Chem. 85(2013) 5335-5339. doi: 10.1021/ac400805f
25. [25]
  K. Yan, Y. Liu, Y. Yang, et al., Anal. Chem. 87(2015) 12215-12220. doi: 10.1021/acs.analchem.5b03139
26. [26]
  H.M. Meng, H. Liu, H. Kuai, et al., Chem. Soc. Rev. 45(2016) 2583-2602. doi: 10.1039/C5CS00645G
27. [27]
  S. Deng, H. Ju, Analyst 138(2013) 43-61. doi: 10.1039/C2AN36122A
28. [28]
  X. Tan, B. Zhang, G. Zou, J. Am. Chem. Soc. 139(2017) 8772-8776. doi: 10.1021/jacs.7b05073
29. [29]
  L. Bouffier, S. Arbault, A. Kuhn, et al., Anal. Bioanal. Chem. 408(2016) 7003-7011. doi: 10.1007/s00216-016-9606-9
30. [30]
  N. Hao, J. Lu, Z. Dai, et al., Electrochem. commun. 108(2019) 106559. doi: 10.1016/j.elecom.2019.106559
1. [1]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
2. [2]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
3. [3]
  Wenli Xu , Yingzhao Zhang , Rui Wang , Chenyang Liu , Jialin Liu , Xiangyu Huo , Xinying Liu , He Zhang , Jianxu Ding . In-situ passivating surface defects of ultra-thin MAPbBr3 perovskite single crystal films for high performance photodetectors. Chinese Journal of Structural Chemistry, 2025, 44(1): 100454-100454. doi: 10.1016/j.cjsc.2024.100454
4. [4]
  Yuyang Zhou , Ziwang Mao , Jing-Juan Xu . Recent advances in near infrared (NIR) electrochemiluminescence luminophores. Chinese Chemical Letters, 2024, 35(11): 109622-. doi: 10.1016/j.cclet.2024.109622
5. [5]
  Benjian Xin , Rui Wang , Lili Liu , Zhiqiang Niu . Metal-organic framework derived MnO@C/CNTs composite for high-rate lithium-based semi-solid flow batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100116-100116. doi: 10.1016/j.cjsc.2023.100116
6. [6]
  Husitu Lin , Shuangkun Zhang , Dianfa Zhao , Yongkang Wang , Wei Liu , Fan Yang , Jianjun Liu , Dongpeng Yan , Zhanpeng Wu . Flexible polyphosphazene nanocomposite films: Enhancing stability and luminescence of CsPbBr₃ perovskite nanocrystals. Chinese Chemical Letters, 2025, 36(4): 109795-. doi: 10.1016/j.cclet.2024.109795
7. [7]
  Hao Deng , Yuxin Hui , Chao Zhang , Qi Zhou , Qiang Li , Hao Du , Derek Hao , Guoxiang Yang , Qi Wang . MXene−derived quantum dots based photocatalysts: Synthesis, application, prospects, and challenges. Chinese Chemical Letters, 2024, 35(6): 109078-. doi: 10.1016/j.cclet.2023.109078
8. [8]
  Zhanheng Yan , Weiqing Su , Weiwei Xu , Qianhui Mao , Lisha Xue , Huanxin Li , Wuhua Liu , Xiu Li , Qiuhui Zhang . Carbon-based quantum dots/nanodots materials for potassium ion storage. Chinese Chemical Letters, 2025, 36(4): 110217-. doi: 10.1016/j.cclet.2024.110217
9. [9]
  Dan-Ying Xing , Xiao-Dan Zhao , Chuan-Shu He , Bo Lai . Kinetic study and DFT calculation on the tetracycline abatement by peracetic acid. Chinese Chemical Letters, 2024, 35(9): 109436-. doi: 10.1016/j.cclet.2023.109436
10. [10]
  Biao Huang , Tao Tang , Fushou Liu , Shi-Hui Chen , Zhi-Ling Zhang , Mingxi Zhang , Ran Cui . Quantum dots boost large-view NIR-Ⅱ imaging with high fidelity for fluorescence-guided tumor surgery. Chinese Chemical Letters, 2024, 35(12): 109694-. doi: 10.1016/j.cclet.2024.109694
11. [11]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
12. [12]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
13. [13]
  Xin Dong , Jing Liang , Zhijin Xu , Huajie Wu , Lei Wang , Shihai You , Junhua Luo , Lina Li . Exploring centimeter-sized crystals of bismuth-iodide perovskite toward highly sensitive X-ray detection. Chinese Chemical Letters, 2024, 35(6): 108708-. doi: 10.1016/j.cclet.2023.108708
14. [14]
  Botao Gao , He Qi , Hui Liu , Jun Chen . Role of polarization evolution in the hysteresis effect of Pb-based antiferroelecrtics. Chinese Chemical Letters, 2024, 35(4): 108598-. doi: 10.1016/j.cclet.2023.108598
15. [15]
  Ying-Yu Zhang , Jia-Qi Luo , Yan Han , Wan-Ying Zhang , Yi Zhang , Hai-Feng Lu , Da-Wei Fu . Bistable switch molecule DPACdCl₄ showing four physical channels and high phase transition temperature. Chinese Chemical Letters, 2025, 36(1): 109530-. doi: 10.1016/j.cclet.2024.109530
16. [16]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
17. [17]
  Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO₃₋_x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
18. [18]
  Junjie Zhang , Yue Wang , Qiuhan Wu , Ruquan Shen , Han Liu , Xinhua Duan . Preparation and Selective Separation of Lightweight Magnetic Molecularly Imprinted Polymers for Trace Tetracycline Detection in Milk. University Chemistry, 2024, 39(5): 251-257. doi: 10.3866/PKU.DXHX202311084
19. [19]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091
20. [20]
  Lin Song , Dourong Wang , Biao Zhang . Innovative Experimental Design and Research on Preparing Flexible Perovskite Fluorescent Gels Using 3D Printing. University Chemistry, 2024, 39(7): 337-344. doi: 10.3866/PKU.DXHX202310107

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(618)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Flexibly regulated electrochemiluminescence of all-inorganic perovskite CsPbBr3 quantum dots through electron bridge to across interfaces between polar and non-polar solvents

Metrics

通讯作者: 陈斌, bchen63@163.com

Flexibly regulated electrochemiluminescence of all-inorganic perovskite CsPbBr₃ quantum dots through electron bridge to across interfaces between polar and non-polar solvents