Citation: Xun-Heng Jiang, Fan Yu, Dai-She Wu, Lei Tian, Ling-Ling Zheng, Li-Sha Chen, Peng Chen, Long-Shuai Zhang, Hui Zeng, Ying Chen, Jian-Ping Zou. Isotypic heterojunction based on Fe-doped and terephthalaldehyde-modified carbon nitride for improving photocatalytic degradation with simultaneous hydrogen production[J]. Chinese Chemical Letters, ;2021, 32(9): 2782-2786. doi: 10.1016/j.cclet.2021.01.011 shu

Isotypic heterojunction based on Fe-doped and terephthalaldehyde-modified carbon nitride for improving photocatalytic degradation with simultaneous hydrogen production

Xun-Heng Jiang ^{a, b, c, 1} ,
Fan Yu ^{b, c, 1} ,
Dai-She Wu ^a ,
Lei Tian ^{a, b, c} ,
Ling-Ling Zheng ^{a, b, c} ,
Li-Sha Chen ^a ,
Peng Chen ^{a, b, c} ,
Long-Shuai Zhang ^{b, c, *,} ,
Hui Zeng ^{a, b, c} ,
Ying Chen ^{a, b, c} ,
Jian-Ping Zou ^{a, b, c, *,}

a.
Key Laboratory of Poyang Lake Environment and Resource Utilization of Ministry of Education, School of Resources Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
b.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China
c.
National-Local Joint Engineering Research Center of Heavy Metals Pollutants Control and Resource Utilization, Nanchang Hangkong University, Nanchang 330063, China

L_S_Zhang1990@163.com

zjp_112@126.com

Received Date: 2 November 2020
Revised Date: 2 December 2020
Accepted Date: 7 January 2021
Available Online: 12 January 2021

Figures(6)

To achieve an efficient photocatalytic for clean energy production and environmental remediation, the highly active Fe-doped and terephthalaldehyde-modified carbon nitride (Fe-CN/NTE) isotypic heterojunction photocatalyst is constructed via a simple annealing method for degradation of organic pollutants with simultaneous resource recovery. The Fe-CN/NTE catalyst exhibits a 93% removal rate of p-nitrophenol (4-NP) and a 1.72 mmol/g H₂ evolution rate in 2 h simultaneously under visible light irradiation, which are higher than those of pristine CN, Fe-CN, and NTE, respectively. Photoelectrochemical tests show that the excellent photocatalytic performance of Fe-CN/NTE comes from the improved migration, transportation, and separation of photoinduced charge carriers and expanded light-harvesting range. Moreover, hydroxyl radical (OH), electron (e⁻), and hole (h⁺) are the main active species and the rational mechanism of 4-NP photodegradation was proposed based on scavenger measurements and liquid chromatography-mass spectrometry (LC-MS), respectively. Isotypic heterojunction Fe-CN/NTE photocatalyst possesses excellent stability in the H₂ evolution and 4-NP degradation during five-run cycle tests, posing as a promising candidate in practical works for organic pollution and energy challenges.
- Isotypic heterojunction,
- Photocatalytic degradation,
- Simultaneous hydrogen evolution,
- Carbon nitride
1. [1]
  H.R. Wei, S.K. Loeb, J.H. Kim, et al., Proc. Natl. Acad. Sci. 117(2020) 15473-15481. doi: 10.1073/pnas.2003362117
2. [2]
  T. Takata, J.Z. Jiang, K. Domen, et al., Nature 581(2020) 411-414. doi: 10.1038/s41586-020-2278-9
3. [3]
  F. Chen, H.W. Huang, Y.H. Zhang, et al., Chin. Chem. Lett. 28(2017) 2244-2250. doi: 10.1016/j.cclet.2017.09.017
4. [4]
  Y. Yang, G.M. Zeng, D.L. Huang, et al., Water Res. 184(2020) 116200. doi: 10.1016/j.watres.2020.116200
5. [5]
  Y.B. Chen, J.F. Li, Z.Q. Liu, et al., Chin. Chem. Lett. 31(2020) 1516-1519. doi: 10.1016/j.cclet.2019.12.013
6. [6]
  L. Tian, H.L. Jiang, X.B. Luo, et al., Chem. Eng. J. 343(2018) 607-618. doi: 10.1016/j.cej.2018.03.015
7. [7]
  D.D. Zheng, X.N. Cao, X.C. Wang, Angew. Chem. Int. Ed. 55(2016) 11512-11516. doi: 10.1002/anie.201606102
8. [8]
  C.C. Dong, M.Y. Xing, J.L. Zhang, et al., Environ. Sci. Technol. 52(2018) 11297-11308. doi: 10.1021/acs.est.8b02403
9. [9]
  Y.G. Zhou, X.X. Wang, G.H. Yu, et al., Proc. Natl. Acad. Sci. 116(2019) 10232-10237. doi: 10.1073/pnas.1901631116
10. [10]
  Y.C. Zhang, N. Afzal, J.J. Zou, et al., Adv. Sci. 6(2019) 1900053.
11. [11]
  L. Pan, J.J. Zou, W.B. Mi, et al., Nat. Commun. 11(2020) 418. doi: 10.1038/s41467-020-14333-w
12. [12]
  N. Chen, H. Li, L.Z. Zhang, et al., Environ. Sci. Technol. 52(2018) 12656-12666. doi: 10.1021/acs.est.8b03882
13. [13]
  X.H. Jiang, L.S. Zhang, J.P. Zou, et al., Angew. Chem. Int. Ed. 59(2020) 23112-23116. doi: 10.1002/anie.202011495
14. [14]
  A. Kumar, A. Rana, F.J. Stadler, et al., ACS Appl. Mater. Interfaces 10(2018) 40474-40490. doi: 10.1021/acsami.8b12753
15. [15]
  Y.C. Nie, J.P. Zou, S.L. Suib, et al., App. Catal. B: Environ. 227(2018) 312-321. doi: 10.1016/j.apcatb.2018.01.033
16. [16]
  X.H. Jiang, Q.J. Xing, J.P. Zou, et al., ACS Sustainable Chem. Eng. 6(2018) 12695-12705. doi: 10.1021/acssuschemeng.8b01695
17. [17]
  S.V.P. Vattikuti, P.A.K. Reddy, C. Byon, et al., ACS Omega 3(2018) 7587-7602. doi: 10.1021/acsomega.8b00471
18. [18]
  W.J. Ong, L.L. Tan, S.P. Chai, et al., Chem. Rev. 116(2016) 7159-7329. doi: 10.1021/acs.chemrev.6b00075
19. [19]
  G.F. Liao, H.Y. Gao, G.J. Yang, et al., Energy Environ. Sci. 12(2019) 2080-2147. doi: 10.1039/C9EE00717B
20. [20]
  L.H. Lin, X. Cai, X.C. Wang, et al., Nat. Catal. 3(2020) 649-655. doi: 10.1038/s41929-020-0476-3
21. [21]
  F. Yu, F.R. Ai, J.P. Zou, et al., Chin. Chem. Lett. 31(2020) 1648-1653. doi: 10.1016/j.cclet.2019.08.020
22. [22]
  L.S. Zhang, D.M. Li, Q.B. Meng, et al., Adv. Funct. Mater. 29(2019) 1806774. doi: 10.1002/adfm.201806774
23. [23]
  Y. Zheng, Y.L. Chen, X.C. Wang, et al., Adv. Funct. Mater. 30(2020) 2002021. doi: 10.1002/adfm.202002021
24. [24]
  L.W. Ruan, G.S. Xu, Y.J. Zhu, et al., Mater. Res. Bull. 66(2015) 156-162. doi: 10.1016/j.materresbull.2015.02.044
25. [25]
  L.S. Zhang, D.M. Li, Q.B. Meng, et al., Nano Res. 11(2018) 2295-2309. doi: 10.1007/s12274-017-1853-3
26. [26]
  G.M. Liu, G.H. Dong, Y.B. Zeng, et al., Chin. J. Catal. 41(2020) 1564-1572. doi: 10.1016/S1872-2067(19)63518-7
27. [27]
  Y.T. Wang, T. Yang, J.H. Wang, et al., Nanoscale 10(2018) 4913-4920. doi: 10.1039/C7NR09342J
28. [28]
  H.J. Kong, D.H. Won, S.I. Woo, et al., Chem. Mater. 28(2016) 1318-1324. doi: 10.1021/acs.chemmater.5b04178
29. [29]
  J.R. Ran, T.Y. Ma, S.Z. Qiao, et al., Energy Environ. Sci. 8(2015) 3708-3717. doi: 10.1039/C5EE02650D
30. [30]
  W. Che, Q.H. Liu, S.Q. Wei, et al., J. Am. Chem. Soc. 139(2017) 3021-3026. doi: 10.1021/jacs.6b11878
31. [31]
  Y. Yu, W.G. Song, K.J. Ding, et al., J. Mater. Chem. A 5(2017) 17199-17203. doi: 10.1039/C7TA05744J
32. [32]
  P.Y. Kuang, L. Zhuo, Z.Q. Liu, et al., Appl. Sur. Sci. 358(2015) 296-303. doi: 10.1016/j.apsusc.2015.08.066
33. [33]
  J.H. Liu, L.M. Duan, Y.G. Zhang, et al., Nano Lett. 16(2016) 6568-6575. doi: 10.1021/acs.nanolett.6b03229
34. [34]
  K. Wei, K.X. Li, S.L. Luo, et al., App. Catal. B: Environ. 222(2018) 88-98. doi: 10.1016/j.apcatb.2017.09.070
35. [35]
  Q.H. Liang, Z.H. Huang, Q.H. Yang, et al., Small 13(2017) 1603182. doi: 10.1002/smll.201603182
36. [36]
  Z.G. Liu, G. Wang, P. Yang, et al., Chem. Commun. 54(2018) 4720-4723. doi: 10.1039/C8CC01824C
37. [37]
  L.B. Jiang, X.Z. Yuan, J. Liang, et al., Environ. Sci. Nano 5(2018) 2604-2617. doi: 10.1039/C8EN00807H
38. [38]
  Z.Y. Fang, Y.J. Bai, W.D. Shi, et al., Nano Energy 75(2020) 104865. doi: 10.1016/j.nanoen.2020.104865
39. [39]
  J.S. Hu, Y.H. Liang, W.Q. Cui, et al., App. Catal. B: Environ. 245(2019) 130-142. doi: 10.1016/j.apcatb.2018.12.029
40. [40]
  S. Mandal, S.Y. Pu, X.K. Wang, et al., Sci. Total Environ. 708(2020) 134831. doi: 10.1016/j.scitotenv.2019.134831
41. [41]
  Y. Huang, J. Zhang, W.K. Ho, et al., Solar RRL 4(2020) 202000170.
42. [42]
  J.J. Tian, L.X. Zhang, J.L. Shi, et al., J. Mater. Chem. A 4(2016) 13814-13821. doi: 10.1039/C6TA04297J
43. [43]
  H.C. Li, C. Shan, B.C. Pan, Environ. Sci. Technol. 52(2018) 2197-2205. doi: 10.1021/acs.est.7b05563
44. [44]
  X.H. Jiang, J.P. Zou, X.K. Wang, et al., App. Catal. B: Environ. 228(2018) 29-38. doi: 10.1016/j.apcatb.2018.01.062
45. [45]
  Q.Y. Yi, J.L. Zhang, M.Y. Xing, et al., Environ. Sci. Technol. 53(2019) 9725-9733. doi: 10.1021/acs.est.9b01676
1. [1]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
2. [2]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
3. [3]
  Yuhao Ma , Yufei Zhou , Mingchuan Yu , Cheng Fang , Shaoxia Yang , Junfeng Niu . Covalently bonded ternary photocatalyst comprising MoSe₂/black phosphorus nanosheet/graphitic carbon nitride for efficient moxifloxacin degradation. Chinese Chemical Letters, 2024, 35(9): 109453-. doi: 10.1016/j.cclet.2023.109453
4. [4]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
5. [5]
  Xiaoming Fu , Haibo Huang , Guogang Tang , Jingmin Zhang , Junyue Sheng , Hua Tang . Recent advances in g-C3N4-based direct Z-scheme photocatalysts for environmental and energy applications. Chinese Journal of Structural Chemistry, 2024, 43(2): 100214-100214. doi: 10.1016/j.cjsc.2024.100214
6. [6]
  Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
7. [7]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
8. [8]
  Wen-Jing Li , Jun-Bo Wang , Yu-Heng Liu , Mo Zhang , Zhan-Hui Zhang . Molybdenum-doped carbon nitride as an efficient heterogeneous catalyst for direct amination of nitroarenes with arylboronic acids. Chinese Chemical Letters, 2025, 36(3): 110001-. doi: 10.1016/j.cclet.2024.110001
9. [9]
  Hao Lv , Zhi Li , Peng Yin , Ping Wan , Mingshan Zhu . Recent progress on non-metallic carbon nitride for the photosynthesis of H₂O₂: Mechanism, modification and in-situ applications. Chinese Chemical Letters, 2025, 36(1): 110457-. doi: 10.1016/j.cclet.2024.110457
10. [10]
  Wengao Zeng , Yuchen Dong , Xiaoyuan Ye , Ziying Zhang , Tuo Zhang , Xiangjiu Guan , Liejin Guo . Crystalline carbon nitride with in-plane built-in electric field accelerates carrier separation for excellent photocatalytic hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109252-. doi: 10.1016/j.cclet.2023.109252
11. [11]
  Fabrice Nelly Habarugira , Ducheng Yao , Wei Miao , Chengcheng Chu , Zhong Chen , Shun Mao . Synergy of sodium doping and nitrogen defects in carbon nitride for promoted photocatalytic synthesis of hydrogen peroxide. Chinese Chemical Letters, 2024, 35(8): 109886-. doi: 10.1016/j.cclet.2024.109886
12. [12]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
13. [13]
  Xinlong Zheng , Zhongyun Shao , Jiaxin Lin , Qizhi Gao , Zongxian Ma , Yiming Song , Zhen Chen , Xiaodong Shi , Jing Li , Weifeng Liu , Xinlong Tian , Yuhao Liu . Recent advances of CuSbS₂ and CuPbSbS₃ as photocatalyst in the application of photocatalytic hydrogen evolution and degradation. Chinese Chemical Letters, 2025, 36(3): 110533-. doi: 10.1016/j.cclet.2024.110533
14. [14]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
15. [15]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
16. [16]
  Chao-Long Chen , Rong Chen , La-Sheng Long , Lan-Sun Zheng , Xiang-Jian Kong . Anchoring heterometallic cluster on P-doped carbon nitride for efficient photocatalytic nitrogen fixation in water and air ambient. Chinese Chemical Letters, 2024, 35(4): 108795-. doi: 10.1016/j.cclet.2023.108795
17. [17]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
18. [18]
  Yueying Wang , Jianming Xiong , Linwei Xin , Yuanyuan Li , He Huang , Wenjun Miao . Photosensitizer-synergized g-carbon nitride nanosheets with enhanced photocatalytic activity for eradicating drug-resistant bacteria and promoting wound healing. Chinese Chemical Letters, 2025, 36(4): 110003-. doi: 10.1016/j.cclet.2024.110003
19. [19]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
20. [20]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(554)
HTML views(30)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142