Citation: Jinrong Huo, Ling Fu, Chenxu Zhao, Chaozheng He. Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure[J]. Chinese Chemical Letters, ;2021, 32(7): 2269-2273. doi: 10.1016/j.cclet.2020.12.059 shu

Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure

Jinrong Huo ^{a, c} ,
Ling Fu ^d ,
Chenxu Zhao ^{b, c} ,
Chaozheng He ^{b, c, *,}

a.
School of Sciences, Xi'an Technological University, Xi'an 710021, China
b.
Shaanxi Key Laboratory of Optoelectronic Functional Materials and Devices, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
c.
Institute of Environmental and Energy Catalysis, School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
d.
College of Resources and Environmental Engineering, Tianshui Normal University, Tianshui 741001, China

hecz2019@xatu.edu.cn

Received Date: 11 December 2020
Revised Date: 28 December 2020
Accepted Date: 29 December 2020
Available Online: 5 January 2021

Figures(5)

In this paper, the process of ammonia borane (AB) hydrolysis generate H₂ on the transition metal Fe@Co core-shell structure has been obtained. According to the different roles played by H₂O molecules and the number of H₂O molecules involved, there are three schemes of reaction paths. Route Ⅰ does not involve the dissociation of H₂O molecules and all H atoms come from AB. Moreover, the H₂O molecule has no effect on the breaking of the BH bond or the NH bond. The reaction absorbs more heat during the formation of the second and third H₂ molecules. Route Ⅱ includes the dissociation of H₂O molecules and the cleavage of BH or NH bonds, respectively, and the reaction shows a slight exotherm. Route Ⅲ started from the break of the BN bond and obtained 3H₂ molecules through the participation of different numbers of H₂O molecules. After multiple comparative analyses, the optimal hydrolysis reaction path has been obtained, and the reaction process can proceed spontaneously at room temperature.
- Fe₂₂@Co₅₈ core-shell,
- Hydrolysis reaction,
- Catalyst,
- Ammonia borane,
- Hydrogen generation
1. [1]
  A. Rossin, M.J.C.R. Peruzzini, Chem. Rev. 116 (2016) 8848-8872. doi: 10.1021/acs.chemrev.6b00043
2. [2]
  A. Staubitz, A.P. Robertson, I.J.C.R. Manners, Chem. Rev. 110 (2010) 4079-4124. doi: 10.1021/cr100088b
3. [3]
  W.C. Wu, Z.M. Ao, T. Wang, et al., Phys. Chem. Chem. Phys. 16 (2014) 16588-16594. doi: 10.1039/C4CP01416B
4. [4]
  G.L. Liu, J.H. Zhou, W.N. Zhao, et al., Chin. Chem. Lett. 31 (2020) 1966-1969. doi: 10.1016/j.cclet.2019.12.023
5. [5]
  Q.G. Jiang, Z.M. Ao, S. Li, et al., RSC Adv. 4 (2014) 20290-20296. doi: 10.1039/C4RA01908C
6. [6]
  Y. Lei, Y. Wang, Y. Liu, et al., Angew. Chem. Int. Ed. 59 (2020) 20794-20812. doi: 10.1002/anie.201914647
7. [7]
  C. Lei, W. Zhou, Q. Feng, et al., Nano-Micro Lett. 11 (2019) 45. doi: 10.1007/s40820-019-0279-8
8. [8]
  Y. Liu, Q. Feng, W. Liu, et al., Nano Energy 81 (2020) 105641.
9. [9]
  C. He, R. Wang, H. Yang, et al., Appl. Surf. Sci. 507 (2020) 145076. doi: 10.1016/j.apsusc.2019.145076
10. [10]
  C. He, R. Wang, D. Xiang, et al., Appl. Surf. Sci. 509 (2020) 145392. doi: 10.1016/j.apsusc.2020.145392
11. [11]
  H. Hu, H. Yang, X. Yang, et al., Chin. Chem. Lett. 31 (2020) 3213–3215. doi: 10.1016/j.cclet.2020.08.025
12. [12]
  L. Chen, C. He, R. Wang, et al., Chin. Chem. Lett. 32 (2021) 53–56. doi: 10.1016/j.cclet.2020.11.013
13. [13]
  J. Zhang, F. Lin, L. Yang, et al., Chin. Chem. Lett. 31 (2020) 2019-2022. doi: 10.1016/j.cclet.2019.11.042
14. [14]
  N.M. Alyami, A.P. LaGrow, D.H. Anjum, et al., Cryst. Growth Des. 18 (2018) 1509-1516. doi: 10.1021/acs.cgd.7b01489
15. [15]
  Y. Men, J. Su, C. Huang, et al., Chin. Chem. Lett. 29 (2018) 1671-1674. doi: 10.1016/j.cclet.2018.04.009
16. [16]
  K. Yao, C. Zhao, N. Wang, et al., Nanoscale 12 (2020) 638-647. doi: 10.1039/c9nr07144j
17. [17]
  Y. Song, X. Li, C. He, Chin. Chem. Lett. 32 (2021) 1106-1110. doi: 10.1016/j.cclet.2020.08.024
18. [18]
  J. Zhang, F. Lin, L. Yang, et al., Chin. Chem. Lett. 31 (2020) 2019-2022. doi: 10.1016/j.cclet.2019.11.042
19. [19]
  A. Gellé, T. Jin, L. de la Garza, et al., Chem. Rev. 120 (2019) 986-1041.
20. [20]
  M. Chandra, Q. Xu, J. Power Sources 159 (2006) 855-860. doi: 10.1016/j.jpowsour.2005.12.033
21. [21]
  S. Chavez, U. Aslam, S. Linic, ACS Energy Lett. 3 (2018) 1590-1596. doi: 10.1021/acsenergylett.8b00841
22. [22]
  U. Aslam, S. Chavez, S. Linic, Nat. Nanotechnol. 12 (2017) 1000. doi: 10.1038/nnano.2017.131
23. [23]
  J.M. Yan, X.B. Zhang, S. Han, et al., Angew. Chem. 120 (2008) 2319-2321. doi: 10.1002/ange.200704943
24. [24]
  J.M. Yan, X.B. Zhang, S. Han, et al., J. Power Sources 194 (2009) 478-481. doi: 10.1016/j.jpowsour.2009.04.023
25. [25]
  J.M. Yan, X.B. Zhang, H. Shioyama, et al., J. Power Sources 195 (2010) 1091-1094. doi: 10.1016/j.jpowsour.2009.08.067
26. [26]
  Y. Yamada, K. Yano, Q. Xu, et al., J. Phys. Chem. C 114 (2010) 16456-16462. doi: 10.1021/jp104291s
27. [27]
  T. Umegaki, J.M. Yan, X.B. Zhang, et al., J. Power Sources 191 (2009) 209-216. doi: 10.1016/j.jpowsour.2009.02.054
28. [28]
  T. Umegaki, J.M. Yan, X.B. Zhang, et al., Int. J. Hydrogen Energy 34 (2009) 3816-3822. doi: 10.1016/j.ijhydene.2009.03.003
29. [29]
  F. Qiu, Y. Wang, Y. Wang, et al., Catal. Today 170 (2011) 64-68. doi: 10.1016/j.cattod.2011.02.026
30. [30]
  C. Cui, Y. Liu, S. Mehdi, et al., Appl. Catal. B 265 (2020) 118612. doi: 10.1016/j.apcatb.2020.118612
31. [31]
  W. Chen, W. Fu, G. Qian, et al., Iscience 23 (2020) 100922. doi: 10.1016/j.isci.2020.100922
32. [32]
  D. Zhou, X. Huang, H. Wen, et al., Sustain. Energy Fuels, 4 (2020)3677-3686. doi: 10.1039/d0se00660b
33. [33]
  C. Wang, L. Li, X. Yu, et al., ACS Sustain. Chem. Eng., 8 (2020) 8256–8266. doi: 10.1021/acssuschemeng.0c01475
34. [34]
  P.E. Blöchl, O. Jepsen, O.K. Andersen, Phy. Rev. B 49 (1994) 16223. doi: 10.1103/PhysRevB.49.16223
35. [35]
  G. Kresse, J. Hafner, Phy. Rev. B 47 (1993) 558. doi: 10.1103/PhysRevB.47.558
36. [36]
  G. Kresse, J. Hafner, Phy. Rev. B 49 (1994) 14251. doi: 10.1103/PhysRevB.49.14251
37. [37]
  J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 77 (1996) 3865. doi: 10.1103/PhysRevLett.77.3865
38. [38]
  G. Kresse, D. Joubert, Phys. Rev. B: Condens. Matter Mater. Phys. 59 (1999) 1758-1775. doi: 10.1103/PhysRevB.59.1758
39. [39]
  S. Grimme, J. Antony, S. Ehrlich, et al., J. Chem. Phys. 132 (2010) 154104. doi: 10.1063/1.3382344
40. [40]
  S. Grimme, S. Ehrlich, L. Goerigk, J. Comput. Chem., 32 (2011) 1456-1465. doi: 10.1002/jcc.21759
41. [41]
  J. Harl, L. Schimka, G. Kresse, Phy. Rev. B 81 (2010) 115126. doi: 10.1103/PhysRevB.81.115126
42. [42]
  D. Zhou, C. Li, F. Yin, et al., Chin. Chem. Lett. 31 (2020) 2325-2329. doi: 10.1016/j.cclet.2020.04.045
43. [43]
  Chunying Pu, Jiahui Yu, Ling Fu, et al., Chin. Chem. Lett. 32 (2021) 1081-1085. doi: 10.1016/j.cclet.2020.08.042
44. [44]
  G. Henkelman, B.P. Uberuaga, H. Jónsson, J. Chem. Phys. 113 (2000) 9901-9904. doi: 10.1063/1.1329672
45. [45]
  X. Fu, H. Yang, L. Fu, et al., Chin. Chem. Lett. 32 (2021) 1089-1094. doi: 10.1016/j.cclet.2020.08.031
46. [46]
  C. Tsai, H. Chen, R. Liu, et al., Int. J. Hydrogen Energy 37 (2012) 3338-3343. doi: 10.1016/j.ijhydene.2011.11.038
47. [47]
  B. Xiao, Y. Zhu, X. Lang, et al., Sci. Rep. 4 (2014) 5205. doi: 10.1038/srep05205
48. [48]
  Y. Chen, F. Yang, Y. Dai, et al., J. Phys. Chem. C 112 (2008) 1645-1649. doi: 10.1021/jp709886y
49. [49]
  X.B. Zhang, J.M. Yan, S. Han, et al., J. Am. Chem. Soc. 131 (2009) 2778-2779. doi: 10.1021/ja808830a
50. [50]
  S. Alayoglu, B. Eichhorn, J. Am. Chem. Soc. 130 (2008) 17479-17486. doi: 10.1021/ja8061425
1. [1]
  Luyan Shi , Ke Zhu , Yuting Yang , Qinrui Liang , Qimin Peng , Shuqing Zhou , Tayirjan Taylor Isimjan , Xiulin Yang . Phytic acid-derivative Co₂B-CoPO_x coralloidal structure with delicate boron vacancy for enhanced hydrogen generation from sodium borohydride. Chinese Chemical Letters, 2024, 35(4): 109222-. doi: 10.1016/j.cclet.2023.109222
2. [2]
  Chunru Liu , Ligang Feng . Advances in anode catalysts of methanol-assisted water-splitting reactions for hydrogen generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100136-100136. doi: 10.1016/j.cjsc.2023.100136
3. [3]
  Ke Wang , Jia Wu , Shuyi Zheng , Shibin Yin . NiCo Alloy Nanoparticles Anchored on Mesoporous Mo2N Nanosheets as Efficient Catalysts for 5-Hydroxymethylfurfural Electrooxidation and Hydrogen Generation. Chinese Journal of Structural Chemistry, 2023, 42(10): 100104-100104. doi: 10.1016/j.cjsc.2023.100104
4. [4]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
5. [5]
  Jinli Chen , Shouquan Feng , Tianqi Yu , Yongjin Zou , Huan Wen , Shibin Yin . Modulating Metal-Support Interaction Between Pt3Ni and Unsaturated WOx to Selectively Regulate the ORR Performance. Chinese Journal of Structural Chemistry, 2023, 42(10): 100168-100168. doi: 10.1016/j.cjsc.2023.100168
6. [6]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
7. [7]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
8. [8]
  Yufei Liu , Liang Xiong , Bingyang Gao , Qingyun Shi , Ying Wang , Zhiya Han , Zhenhua Zhang , Zhaowei Ma , Limin Wang , Yong Cheng . MOF-derived Cu based materials as highly active catalysts for improving hydrogen storage performance of Mg-Ni-La-Y alloys. Chinese Chemical Letters, 2024, 35(12): 109932-. doi: 10.1016/j.cclet.2024.109932
9. [9]
  Gang Hu , Chun Wang , Qinqin Wang , Mingyuan Zhu , Lihua Kang . The controlled oxidation states of the H₄PMo₁₁VO₄₀ catalyst induced by plasma for the selective oxidation of methacrolein. Chinese Chemical Letters, 2025, 36(2): 110298-. doi: 10.1016/j.cclet.2024.110298
10. [10]
  Guanxiong Yu , Chengkai Xu , Huaqiang Ju , Jie Ren , Guangpeng Wu , Chengjian Zhang , Xinghong Zhang , Zhen Xu , Weipu Zhu , Hao-Cheng Yang , Haoke Zhang , Jianzhao Liu , Zhengwei Mao , Yang Zhu , Qiao Jin , Kefeng Ren , Ziliang Wu , Hanying Li . Key progresses of MOE key laboratory of macromolecular synthesis and functionalization in 2023. Chinese Chemical Letters, 2024, 35(11): 109893-. doi: 10.1016/j.cclet.2024.109893
11. [11]
  Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
12. [12]
  Yulong Liu , Haoran Lu , Tong Yang , Peng Cheng , Xu Han , Wenyan Liang . Catalytic applications of amorphous alloys in wastewater treatment: A review on mechanisms, recent trends, challenges and future directions. Chinese Chemical Letters, 2024, 35(10): 109492-. doi: 10.1016/j.cclet.2024.109492
13. [13]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
14. [14]
  Hong Yin , Zhipeng Yu . Hexavalent iridium catalyst enhances efficiency of hydrogen production. Chinese Journal of Structural Chemistry, 2025, 44(1): 100382-100382. doi: 10.1016/j.cjsc.2024.100382
15. [15]
  Bin Dong , Ning Yu , Qiu-Yue Wang , Jing-Ke Ren , Xin-Yu Zhang , Zhi-Jie Zhang , Ruo-Yao Fan , Da-Peng Liu , Yong-Ming Chai . Double active sites promoting hydrogen evolution activity and stability of CoRuOH/Co₂P by rapid hydrolysis. Chinese Chemical Letters, 2024, 35(7): 109221-. doi: 10.1016/j.cclet.2023.109221
16. [16]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
17. [17]
  Yiwen Xu , Chaozheng He , Chenxu Zhao , Ling Fu . Single-atom Ti doping on S-vacancy two-dimensional CrS₂ as a catalyst for ammonia synthesis: A DFT study. Chinese Chemical Letters, 2025, 36(4): 109797-. doi: 10.1016/j.cclet.2024.109797
18. [18]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
19. [19]
  Peng Wang , Daijie Deng , Suqin Wu , Li Xu . Cobalt-based deep eutectic solvent modified nitrogen-doped carbon catalyst for boosting oxygen reduction reaction in zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(1): 100199-100199. doi: 10.1016/j.cjsc.2023.100199
20. [20]
  Lizhang Chen , Yu Fang , Mingxin Pang , Ruoxu Sun , Lin Xu , Qixing Zhou , Yawen Tang . Interfacial engineering of core/satellite-structured RuP/RuP2 heterojunctions for enhanced pH-universal hydrogen evolution reaction. Chinese Journal of Structural Chemistry, 2025, 44(1): 100461-100461. doi: 10.1016/j.cjsc.2024.100461

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(976)
HTML views(135)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe22@Co58 core-shell structure

Metrics

通讯作者: 陈斌, bchen63@163.com

Hydrogen generation of ammonia borane hydrolysis catalyzed by Fe₂₂@Co₅₈ core-shell structure