Citation: Chenyang Zhao, Xiaoju Yin, Zhikun Guo, Dan Zhao, Guiye Yang, Aosai Chen, Lishuang Fan, Yu Zhang, Naiqing Zhang. High lithiophilic nitrogen-doped carbon nanotube arrays prepared by in-situ catalyze for lithium metal anode[J]. Chinese Chemical Letters, ;2021, 32(7): 2254-2258. doi: 10.1016/j.cclet.2020.12.056 shu

High lithiophilic nitrogen-doped carbon nanotube arrays prepared by in-situ catalyze for lithium metal anode

Chenyang Zhao ^a ,
Xiaoju Yin ^{a, b, *,} ,
Zhikun Guo ^a ,
Dan Zhao ^a ,
Guiye Yang ^a ,
Aosai Chen ^a ,
Lishuang Fan ^{a, b, *,} ,
Yu Zhang ^a ,
Naiqing Zhang ^{a, b, *,}

a.
State Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
b.
Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150001, China

yinxiaoju@sina.com

fanlsh@hit.edu.cn

znqmww@163.com

Received Date: 22 October 2020
Revised Date: 18 November 2020
Accepted Date: 17 December 2020
Available Online: 5 January 2021

Figures(4)

Lithium metal has a very outstanding theoretical capacity (3860 mAh/g) and is one of the most superior anode materials for high energy density batteries. However, the uncontrollable dendrite growth and the formation of "dead lithium" are the important hidden dangers of short cycle life and low safety. However, the uncontrollable dendrite growth and the formation of dead lithium leads to short cycle life and hidden danger, which hinder its practical application. Controlling the nucleation and growth process of lithium is an effective strategy to inhibit lithium dendrite. Herein, a simple in situ self-catalytic method is used to construct nitrogen doped carbon nanotube arrays on stainless steel mesh (N-CNT@SS) as a lithium composite anode. The N-doped CNTs provide a great number of N-functional groups, which enhance the lithiophilic of anode and provide a large number of uniform nucleation sites, hence it has excellent structural stability for cycles. The arrays provide neat lithium-ion transport channels to uniform lithium-ion flux and inhibits dendrite generation, revealed by the COMSOL multi-physics concentration field simulation. The N-CNT@SS composite anode sustain stable at 98.9% over 300 cycles at 1 mA/cm². N-CNT@SS as the anode is coupled LiFePO₄ (LFP) as the cathode construct a full battery, demonstrating excellent cycling stability with a capacity of 152.33 mAh/g and capacity retaining ratio of 95.4% after 100 cycles at 0.5 C.
- Lithium metal batteries,
- Nitrogen doped carbon nanotubes,
- Stainless steel mesh,
- COMSOL multi-physics concentration field,
- Simulation,
- Lithiophilic anode
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