Citation: Ziyu Gan, Xiaolong Zhu, Qiuli Yan, Xiuyan Song, Daoshan Yang. Oxidative dual C–H sulfenylation: A strategy for the synthesis of bis (imidazo [1, 2-a]pyridin-3-yl)sulfanes under metal-free conditions using sulfur powder[J]. Chinese Chemical Letters, ;2021, 32(5): 1705-1708. doi: 10.1016/j.cclet.2020.12.046 shu

Oxidative dual C–H sulfenylation: A strategy for the synthesis of bis (imidazo [1, 2-a]pyridin-3-yl)sulfanes under metal-free conditions using sulfur powder

Ziyu Gan ^{a, b} ,
Xiaolong Zhu ^b ,
Qiuli Yan ^b ,
Xiuyan Song ^b ,
Daoshan Yang ^{b, *,}

a.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China
b.
Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science, MOE, State Key Laboratory Base of Eco-Chemical Engineering, College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, China

yangdaoshan@tsinghua.org.cn

Received Date: 21 October 2020
Revised Date: 20 December 2020
Accepted Date: 23 December 2020
Available Online: 28 December 2020

Figures(6)

An efficient approach to sulfur-bridged imidazopyridines has been developed under metal-free conditions using inexpensive sulfur powder as the sulfur source. Most appealingly, the reaction can proceed smoothly without addition of any additives, ultimately decreasing the production of chemical waste. The inexpensive and green method should provide a useful strategy for constructing a library of novel and biological interesting heteroaromatic sulfides.
- C-S bond,
- Metal-free,
- Sulfur powder,
- Disulfides,
- Heterocycle
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