Citation: Hongfei Li, Liwei Wang, Yingke Zhu, Pingkai Jiang, Xingyi Huang. Tailoring the polarity of polymer shell on BaTiO₃ nanoparticle surface for improved energy storage performance of dielectric polymer nanocomposites[J]. Chinese Chemical Letters, ;2021, 32(7): 2229-2232. doi: 10.1016/j.cclet.2020.12.032 shu

Tailoring the polarity of polymer shell on BaTiO₃ nanoparticle surface for improved energy storage performance of dielectric polymer nanocomposites

Shanghai Key Laboratory of Electrical Insulation and Thermal Aging, The State Key Laboratory of Metal Matrix Composites, Department of Polymer Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

xyhuang@sjtu.edu.cn

Received Date: 5 November 2020
Revised Date: 14 December 2020
Accepted Date: 17 December 2020
Available Online: 18 March 2021

Figures(4)

Nanocomposites comprising flexible polymers and high dielectric constant inorganic nanoparticles are considered to be one of the promising candidates for electrostatic capacitor dielectrics. However, the effect of interfacial property on electrical energy storage of dielectric polymer nanocomposites is still not clear. Herein, the role of the polarity of the interfacial region is investigated. For this purpose, three polymers with different polarity, polymethyl methacrylate (PMMA), polyglycidyl methacrylate, and polymethylsulfonyl ethyl methacrylate (PMSEMA) are attached onto BaTiO₃ (BT) nanoparticle surface via surface-initiated reversible addition-fragmentation chain transfer polymerization. It is found that the polarity of shell polymers shows an apparent effect on the dielectric and energy storage of dielectric polymer nanocomposites. For example, PMSEMA@BT (shell polymer possesses the highest polarity) increases dielectric loss and decreases the breakdown strength of the nanocomposites, leading to lower energy storage capability. However, PMMA@BT (shell polymer possesses the lowest polarity) can induce higher breakdown strength of the nanocomposites. As a result, the PMMA@BT nanocomposite exhibits the highest electrical energy storage capability among the three nanocomposites. This research provides new insight into the design of core-shell nanofillers for dielectric energy storage applications.
- Core-shell,
- Dielectric constant,
- Polarity,
- Space charge,
- Energy density
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沈阳化工大学材料科学与工程学院沈阳 110142

Tailoring the polarity of polymer shell on BaTiO3 nanoparticle surface for improved energy storage performance of dielectric polymer nanocomposites

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通讯作者: 陈斌, bchen63@163.com

Tailoring the polarity of polymer shell on BaTiO₃ nanoparticle surface for improved energy storage performance of dielectric polymer nanocomposites