Citation: Kaiyue Zhang, Guilong Lu, Zuoshuai Xi, Yaqiong Li, Qingjie Luan, Xiubing Huang. Covalent organic framework stabilized CdS nanoparticles as efficient visible-light-driven photocatalysts for selective oxidation of aromatic alcohols[J]. Chinese Chemical Letters, ;2021, 32(7): 2207-2211. doi: 10.1016/j.cclet.2020.12.021 shu

Covalent organic framework stabilized CdS nanoparticles as efficient visible-light-driven photocatalysts for selective oxidation of aromatic alcohols

Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory of Function Materials for Molecule & Structure Construction, School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China

xiubinghuang@ustb.edu.cn

Received Date: 28 October 2020
Revised Date: 16 November 2020
Accepted Date: 11 December 2020
Available Online: 2 March 2021

Figures(5)

Noble-metal-free photocatalysts with high and stable performance provide an environmentally-friendly and cost-efficient route for green organic synthesis. In this work, CdS nanoparticles with small particle size and different amount were successfully deposited on the surface of covalent organic frameworks (COFs). The deposition of suitable content of CdS on COFs could not only modify the light adsorption ability and the intrinsic electronic properties, but also enhance the photocatalytic activity and cycling performance of CdS for the selective oxidation of aromatic alcohols under visible light. Especially, COF/CdS-3 exhibited the highest yield (97.1%) of benzaldehyde which is approximately 2.5 and 15.9 times as that of parental CdS and COF, respectively. The results show that the combination of CdS and COF can improve the utilization of visible light and the separation of photo-generated charge carriers, and COF with the π-conjugated system as supports for CdS nanoparticles could provide efficient electron transport channels and improve the photocatalytic performance. Therefore, this kind of COF-supported photocatalysts with accelerated photo-induced electrons and charge-carrier separation between semiconductors possesses great potentials in future green organic synthesis.
- Covalent organic frameworks,
- CdS nanoparticles,
- Photocatalyst,
- Selective alcohol oxidation,
- Visible light,
- Green organic synthesis
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