Citation: Zekun Xin, Xiaodong Zhao, Huiming Ji, Tianyi Ma, Hui Li, Shuhui Zhong, Zhurui Shen. Amorphous carbon-linked TiO₂/carbon nanotube film composite with enhanced photocatalytic performance: The effect of interface contact and hydrophilicity[J]. Chinese Chemical Letters, ;2021, 32(7): 2151-2154. doi: 10.1016/j.cclet.2020.11.054 shu

Amorphous carbon-linked TiO₂/carbon nanotube film composite with enhanced photocatalytic performance: The effect of interface contact and hydrophilicity

Zekun Xin ^a ,
Xiaodong Zhao ^a ,
Huiming Ji ^a ,
Tianyi Ma ^d ,
Hui Li ^{c, **,} ,
Shuhui Zhong ^{b, **,} ,
Zhurui Shen ^{a, c, *,}

a.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology, Ministry of Education, Tianjin University, Tianjin 300350, China
b.
School of Mathematics, Tianjin University, Tianjin 300350, China
c.
School of Materials Science and Engineering, Nankai University, Tianjin 300350, China
d.
Centre for Translational Atomaterials, Faculty of Science, Engineering & Technology, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia

^**

lihui@nankai.edu.cn

zhshuhui@tju.edu.cn

shenzhurui@nankai.edu.cn

Received Date: 21 September 2020
Revised Date: 23 October 2020
Accepted Date: 13 November 2020
Available Online: 1 December 2020

Figures(3)

Carbon nanotube film (CNTF) can be used for photocatalysis and water treatment due to its porous structure, good stability and excellent electrical properties. In this work, TiO₂/amorphous carbon/carbon nanotube film (TCC) composite with uniform structure was prepared by a simple atomization spraying method. Rhodamine B (RhB) was used to test the photocatalytic activity of TCC. TCC composite exhibits good photocatalytic activity under ultraviolet light. In particular, the degradation efficiency of rhodamine B (RhB) by TCC sprayed with 9 layers of TiO₂ (9TCC) increased by 1.45 times than of TiO₂ under ultraviolet light. The enhanced photocatalytic activity of TCC is attributed to the CNTF, which can broaden the light response range of TCC and improve the migration efficiency of electrons. The existence of amorphous carbon will promote these advances. Moreover, the better hydrophilic properties would enhance the catalytic performance happened on the solid-liquid interface. Finally, the photocatalytic mechanism and degradation intermediates of the TCC composite were proposed.
- Carbon nanotube film,
- Photocatalysis,
- Hydrophilia,
- Rhodamine B
1. [1]
  Z. Bian, F. Cao, J. Zhu, H. Li, Environ. Sci. Technol. 49 (2015) 2418-2424. doi: 10.1021/es505540x
2. [2]
  F. Mashkoor, A. Nasar, J. Magn. Magn. Mater. 500 (2020) 166408. doi: 10.1016/j.jmmm.2020.166408
3. [3]
  M. Ji, Z. Zhang, J. Xia, et al., Chin. Chem. Lett. 29 (2018) 805-810. doi: 10.1016/j.cclet.2018.05.002
4. [4]
  S. He, C. Yan, X.Z. Chen, et al., Appl. Catal. B 276 (2020)119138. doi: 10.1016/j.apcatb.2020.119138
5. [5]
  S. Hu, Y. Yu, Y. Guan, et al., Chin. Chem. Lett. 31 (2020) 2839-2842. doi: 10.1016/j.cclet.2020.08.021
6. [6]
  F.C. Ferreira, R.S. Babu, A.L.F. de Barros, et al., Spectroc. Acta Part A 233 (2020) 118198. doi: 10.1016/j.saa.2020.118198
7. [7]
  K. Ilić, A. Selmani, M. Milić, et al., J. Nanopart. Res. 22 (2020) 71. doi: 10.1007/s11051-020-04791-0
8. [8]
  J. Krýsa, G. Waldner, H. Měšt'ánková, J. Jirkovský, G. Grabner, Appl. Catal. B 64 (2006) 290-301. doi: 10.1016/j.apcatb.2005.11.007
9. [9]
  S. Fukugaichi, T. Henmi, N. Matsue, Catal. Lett. 143 (2013) 1255-1259. doi: 10.1007/s10562-013-1119-y
10. [10]
  H. Yu, S.C. Lee, J. Yu, C.H. Ao, J. Mol, Catal. A Chem. 246 (2006) 206-211. doi: 10.1016/j.molcata.2005.11.007
11. [11]
  P. Karami, B. Khorshidi, M. McGregor, et al., J. Clean. Prod. 250 (2020) 119447. doi: 10.1016/j.jclepro.2019.119447
12. [12]
  Y. Liu, J. Yin, P. Wang, et al., ACS Appl. Mater. Interfaces 10 (2018) 36304-36311. doi: 10.1021/acsami.8b14386
13. [13]
  M. Zhu, M. Fujitsuka, L. Zeng, M. Liu, T. Majima, Appl. Catal. B 256 (2019) 117864. doi: 10.1016/j.apcatb.2019.117864
14. [14]
  M. Wongaree, S. Chiarakorn, S. Chuangchote, T. Sagawa, Environ. Sci. Pollut. Res. 23 (2016) 21395-21406. doi: 10.1007/s11356-016-7348-z
15. [15]
  T.V. Cuong, H.N. Tien, V.H. Luan, et al., Phys. Status Solidi A: Appl. Mat. 208 (2011) 943-946. doi: 10.1002/pssa.201026553
16. [16]
  M.S. Balogun, H. Yang, Y. Luo, et al., Energy Environ. Sci. 11 (2018) 1859-1869. doi: 10.1039/C8EE00522B
17. [17]
  Q. Liu, L. Ai, J. Jiang, J. Mater. Chem. A 6 (2018) 4102-4110. doi: 10.1039/C7TA09350K
18. [18]
  A. Jian, M. Wang, L. Wang, et al., RSC Adv. 9 (2019) 41540-41548. doi: 10.1039/C9RA07767G
19. [19]
  H. Liu, W. Li, D. Shen, D. Zhao, G. Wang, J. Am. Chem. Soc. 137 (2015) 13161-13166. doi: 10.1021/jacs.5b08743
20. [20]
  H. Yin, X. Wang, L. Wang, et al., Mater. Res. Bull. 72 (2015) 176-183. doi: 10.1016/j.materresbull.2015.07.030
21. [21]
  T. Onoe, S. Iwamoto, M. Inoue, Catal. Commun. 8 (2007) 701-706. doi: 10.1016/j.catcom.2006.08.018
22. [22]
  H.U. Farouk, A.A.A. Raman, W.M.A.W. Daud, J. Ind. Eng. Chem. 33 (2016) 11-21. doi: 10.1016/j.jiec.2015.10.022
23. [23]
  M.M. Hossain, H. Shima, M.A. Islam, M. Hasan, M. Lee, J. Phys. Chem. C 120 (2016) 17670-17682. doi: 10.1021/acs.jpcc.6b03484
24. [24]
  J.Y. Kim, Materials 2 (2009) 1955-1974. doi: 10.3390/ma2041955
25. [25]
  N. Ohtsu, N. Masahashi, Y. Mizukoshi, K. Wagatsuma, Langmuir 25 (2009) 11586-11591. doi: 10.1021/la901505m
26. [26]
  M.E. Simonsen, Z. Li, E.G. Søgaard, Appl. Surf. Sci. 255 (2009) 8054-8062. doi: 10.1016/j.apsusc.2009.05.013
27. [27]
  B. Gong, X. Luo, N. Bao, et al., Surf. Interface Anal. 46 (2014) 1043-1046. doi: 10.1002/sia.5397
28. [28]
  F. Boccuzzi, A. Chiorino, M. Manzoli, et al., J. Catal. 202 (2001) 256-267. doi: 10.1006/jcat.2001.3290
29. [29]
  Z. Wei, Y. Liu, J. Wang, et al., Nanoscale 7 (2015) 13943-13950. doi: 10.1039/C5NR02345A
30. [30]
  B. Li, Z. Cao, S. Wang, Q. Wei, Z. Shen, Dalton Trans. 47 (2018) 10288-10298. doi: 10.1039/C8DT02402B
31. [31]
  H. Wang, X. Yuan, Y. Wu, et al., Appl. Catal. B 186 (2016) 19-29. doi: 10.1016/j.apcatb.2015.12.041
32. [32]
  Y. Zhang, Z. Shen, Z. Xin, Z. Hu, H. Ji, J. Colloid Interface Sci. 554 (2019) 743-751. doi: 10.1016/j.jcis.2019.07.077
33. [33]
  J. Duan, Q. Tang, B. He, L. Yu, Electrochim. Acta 139 (2014) 381-385. doi: 10.1016/j.electacta.2014.06.165
34. [34]
  Y.S. Li, T.T. Li, X.F. Song, et al., Appl. Surf. Sci. 514 (2020) 145789. doi: 10.1016/j.apsusc.2020.145789
35. [35]
  R. Mimouni, B. Askri, T. Larbi, M. Amlouk, A. Meftah, Inorg. Chem. Commun. 115 (2020)107889. doi: 10.1016/j.inoche.2020.107889
36. [36]
  Z. Li, H. Dong, Z. Wu, et al., Appl. Surf. Sci. 529 (2020) 147162. doi: 10.1016/j.apsusc.2020.147162
37. [37]
  D. Jiang, L. Chen, J. Zhu, et al., Dalton Trans. 42 (2013) 15726-15734. doi: 10.1039/c3dt52008k
38. [38]
  X. Wu, M. Li, J. Li, G. Zhang, S. Yin, Appl. Catal. B 219 (2017) 132-141. doi: 10.1016/j.apcatb.2017.07.025
39. [39]
  Y. Chen, J.F. Li, P.Y. Liao, et al., Chin. Chem. Lett. 31 (2020) 1516-1519. doi: 10.1016/j.cclet.2019.12.013
40. [40]
  N. Guo, H. Liu, Y. Fu, J. Hu, Optik 201 (2020) 163537. doi: 10.1016/j.ijleo.2019.163537
41. [41]
  G. Sharma, D.D. Dionysiou, S. Sharma, et al., Catal. Today 335 (2019) 437-451. doi: 10.1016/j.cattod.2019.03.063
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Amorphous carbon-linked TiO2/carbon nanotube film composite with enhanced photocatalytic performance: The effect of interface contact and hydrophilicity

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通讯作者: 陈斌, bchen63@163.com

Amorphous carbon-linked TiO₂/carbon nanotube film composite with enhanced photocatalytic performance: The effect of interface contact and hydrophilicity