Citation: Chenghao Hou, Lijing Liu, Siyang Meng, Yue Wu, Meiran Xie, Yongkui Shan, Pingang He, Pengfei Sun, Xiaojuan Liao. Hybrid vesicles of pillar[5]arene/silica: Host-guest complexation and application in pH-triggered release[J]. Chinese Chemical Letters, ;2021, 32(1): 214-217. doi: 10.1016/j.cclet.2020.11.030 shu

Hybrid vesicles of pillar[5]arene/silica: Host-guest complexation and application in pH-triggered release

Chenghao Hou ^a ,
Lijing Liu ^a ,
Siyang Meng ^a ,
Yue Wu ^a ,
Meiran Xie ^a ,
Yongkui Shan ^a ,
Pingang He ^a ,
Pengfei Sun ^b ,
Xiaojuan Liao ^{a, b, *,}

a.
School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China
b.
Key Laboratory for Organic Electronics and Information Displays, Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

xjliao@chem.ecnu.edu.cn

Received Date: 1 September 2020
Revised Date: 14 November 2020
Accepted Date: 16 November 2020
Available Online: 20 November 2020

Figures(5)

Integrating silica with organic nanoparticles can generate unique properties. Here pillar[5]arene/silica hybrid vesicles were constructed based on the amphiphilic and rigid properties of pillararenes, as well as the catalytic hydrolysis of tetraethoxysilane. Such vesicles exhibited the high strength of silica and unique molecular recognition of pillararenes, both of which could tune the pH-triggered release behavior. Furthermore, a rhodamine B derivative with hexyl group (RhB-C6) was synthesized, which can form a complex with the pillar[5]arene. Based on the host-guest interaction and high strength of silica, the hybrid vesicles could load more RhB-C6 and the rhodamine B was released more slowly compared with the organic vesicles.
- Pillararenes,
- Hybrid materials,
- Supramolecular chemistry,
- Silica nanoparticles,
- Host-guest interaction
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