Citation: Hui Chong, Cuiyun Nie, Lihong Wang, Sicong Wang, Ying Han, Yang Wang, Chengyin Wang, Chaoguo Yan. Construction and investigation of photo-switch property of azobenzene-bridged pillar[5]arene-based [3]rotaxanes[J]. Chinese Chemical Letters, ;2021, 32(1): 57-61. doi: 10.1016/j.cclet.2020.11.020 shu

Construction and investigation of photo-switch property of azobenzene-bridged pillar[5]arene-based [3]rotaxanes

College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China

hanying@yzu.edu.cn

cgyan@yzu.edu.cn

Received Date: 22 September 2020
Revised Date: 5 November 2020
Accepted Date: 10 November 2020
Available Online: 10 November 2020

Figures(7)

Series of azobenzene-bridged pillar[5]arene-based [3]rotaxanes with different alkyl chain length of guest molecules were constructed by threading-endcapping method with alkylenetriazole as axile and tetrahydrochromene as endcapping group. The encapsulation of pillar[5]arenes were proved by high-resolution mass, ¹H NMR and NOESY spectra. The photo-responsive property were examined by irradiation of the synthesized [3]rotaxanes with 365 nm and blue light LED, which caused trans to cis and cis to trans isomerization, respectively. Irradiation of corresponding model guest compounds without pillar[5]arene encapsulation resulted in near completely trans to cis and cis to trans isomerization, indicating the existence of pillar[5]arenes is the determining factor for the comprised photo isomerization efficiency.
- Pillar[5]arene,
- [3]Rotaxane,
- Azobenzene,
- Supramolecule,
- Photo-switch
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