Citation: Yunrui Wei, Xixi Zhang, Zonghua Wang, Jiangmei Yin, Jinzhao Huang, Gang Zhao, Xijin Xu. Metal-organic framework derived NiCoP hollow polyhedrons electrocatalyst for pH-universal hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2021, 32(1): 119-124. doi: 10.1016/j.cclet.2020.10.046 shu

Metal-organic framework derived NiCoP hollow polyhedrons electrocatalyst for pH-universal hydrogen evolution reaction

School of Physics and Technology, University of Jinan, Ji'nan 250022, China

sps_zhaog@ujn.edu.cn

sps_xuxj@ujn.edu.cn

Received Date: 19 July 2020
Revised Date: 30 September 2020
Accepted Date: 29 October 2020
Available Online: 1 November 2020

Figures(4)

Hollow nanostructures have attracted increasing research interest in hydrogen evolution reaction owing to their unique structural features. Herein, Ni–Co mixed metal phosphide hollow and porous polyhedrons was successfully composited (expressed as NiCoP). Benefiting from the synergistic effects of ZIF-67 by doping Ni elements and the well-defined hollow and porous structure, the as-synthesized NiCoP hollow and porous polyhedrons exhibit better electrochemical properties and mechanical stability for hydrogen evolution reaction over a pH-universal range, with a small Tafel slopes of 72, 101, 176 mV/dec, and a low overpotential of 82, 102, 261 mV at a current density of 10 mA/cm² in 0.5 mol/L H₂SO₄, 1 mol/L KOH and 1 mol/L phosphate buffer solution (PBS). This general strategy can also be applied to fabricate other hollow cobalt-based phosphides and MOFs-derived materials for HER.
- Hollow structure,
- ZIF-67,
- NiCoP,
- Hydrogen evolution reaction,
- pH-Universal range
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