Citation: Yunrui Wei, Xixi Zhang, Zonghua Wang, Jiangmei Yin, Jinzhao Huang, Gang Zhao, Xijin Xu. Metal-organic framework derived NiCoP hollow polyhedrons electrocatalyst for pH-universal hydrogen evolution reaction[J]. Chinese Chemical Letters, ;2021, 32(1): 119-124. doi: 10.1016/j.cclet.2020.10.046 shu

Metal-organic framework derived NiCoP hollow polyhedrons electrocatalyst for pH-universal hydrogen evolution reaction

School of Physics and Technology, University of Jinan, Ji'nan 250022, China

sps_zhaog@ujn.edu.cn

sps_xuxj@ujn.edu.cn

Received Date: 19 July 2020
Revised Date: 30 September 2020
Accepted Date: 29 October 2020
Available Online: 1 November 2020

Figures(4)

Hollow nanostructures have attracted increasing research interest in hydrogen evolution reaction owing to their unique structural features. Herein, Ni–Co mixed metal phosphide hollow and porous polyhedrons was successfully composited (expressed as NiCoP). Benefiting from the synergistic effects of ZIF-67 by doping Ni elements and the well-defined hollow and porous structure, the as-synthesized NiCoP hollow and porous polyhedrons exhibit better electrochemical properties and mechanical stability for hydrogen evolution reaction over a pH-universal range, with a small Tafel slopes of 72, 101, 176 mV/dec, and a low overpotential of 82, 102, 261 mV at a current density of 10 mA/cm² in 0.5 mol/L H₂SO₄, 1 mol/L KOH and 1 mol/L phosphate buffer solution (PBS). This general strategy can also be applied to fabricate other hollow cobalt-based phosphides and MOFs-derived materials for HER.
- Hollow structure,
- ZIF-67,
- NiCoP,
- Hydrogen evolution reaction,
- pH-Universal range
1. [1]
  Y. Xie, M. Chen, M. Cai, et al., Inorg. Chem. 58 (2019) 14652-14659. doi: 10.1021/acs.inorgchem.9b02333
2. [2]
  D.V. Shinde, L.D. Trizio, Z. Dang, et al., Chem. Mater. 29 (2017) 7032-7041. doi: 10.1021/acs.chemmater.7b02666
3. [3]
  J. Duan, Y. Zou, Z. Li, et al., J. Electroanal. Chem. 847 (2019) 113187. doi: 10.1016/j.jelechem.2019.113187
4. [4]
  A.M. El-Toni, M.A. Habila, J.P. Labis, et al., Nanoscale 8 (2016) 2510-2531. doi: 10.1039/C5NR07004J
5. [5]
  X. Wang, L. Yu, B.Y. Guan, et al., Adv. Mater. 30 (2018) 1801211. doi: 10.1002/adma.201801211
6. [6]
  Y. Lu, Y. Deng, S. Lu, et al., Nanoscale 11 (2019) 21259-21265. doi: 10.1039/C9NR07002H
7. [7]
  J. Hu, J. Chen, H. Lin, et al., J. Solid State Chem. 259 (2018) 1-4. doi: 10.1016/j.jssc.2017.12.030
8. [8]
  J. Hao, W. Yang, Z. Zhang, et al., Nanoscale 7 (2015) 11055-11062. doi: 10.1039/C5NR01955A
9. [9]
  B.Y. Guan, X.Y. Yu, H.B. Wu, et al., Adv. Mater. 29 (2017) 1703614. doi: 10.1002/adma.201703614
10. [10]
  Y. Feng, X.Y. Yu, U. Paik, Chem. Commun. 52 (2016) 6269-6272. doi: 10.1039/C6CC02093C
11. [11]
  J. Jiang, L. Zhu, Y. Sun, et al., J. Power Sources 426 (2019) 74-83. doi: 10.1016/j.jpowsour.2019.04.022
12. [12]
  X. Gao, H. Zhang, Q. Li, et al., Angew. Chem. Int. Ed. 55 (2016) 6290-6294. doi: 10.1002/anie.201600525
13. [13]
  K. An, S.G. Kwon, M. Park, et al., Nano Lett. 8 (2008) 4252-4258. doi: 10.1021/nl8019467
14. [14]
  R. Wu, X. Qian, X. Rui, et al., Small 10 (2014) 1932-1938. doi: 10.1002/smll.201303520
15. [15]
  J. Li, S. Lu, H. Huang, et al., ACS Sustain. Chem. Eng. 6 (2018) 10021-10029. doi: 10.1021/acssuschemeng.8b01332
16. [16]
  L. Li, W. Xie, J. Chen, et al., J. Solid State Chem. 264 (2018) 1-5. doi: 10.1016/j.jssc.2018.04.035
17. [17]
  S. Payra, S. Challagulla, C. Chakraborty, et al., J. Electroanal. Chem. 853 (2019) 113545. doi: 10.1016/j.jelechem.2019.113545
18. [18]
  L. Han, T. Yu, W. Lei, et al., J. Mater. Chem. A 5 (2017) 16568-16572. doi: 10.1039/C7TA05146H
19. [19]
  Z. Li, M. Shao, L. Zhou, et al., Nano Energy 25 (2016) 100-109. doi: 10.1016/j.nanoen.2016.04.041
20. [20]
  M. Guo, Y. Qu, F. Zeng, et al., Electrochim. Acta 292 (2018) 88-97. doi: 10.1016/j.electacta.2018.09.159
21. [21]
  P. Jiang, Q. Liu, C. Ge, et al., J. Mater. Chem. A 2 (2014) 14634-14640. doi: 10.1039/C4TA03261F
22. [22]
  Y. Feng, X.Y. Yu, U. Paik, Chem. Commun. 52 (2016) 1633-1636. doi: 10.1039/C5CC08991C
23. [23]
  J. Qin, S. Wang, X. Wang, Appl. Catal. B: Environ. 209 (2017) 476-482. doi: 10.1016/j.apcatb.2017.03.018
24. [24]
  X. Cai, X. Shen, L. Ma, et al., Chem. Eng. J. 268 (2015) 251-259. doi: 10.1016/j.cej.2015.01.072
25. [25]
  H. Hu, B. Guan, B.Y. Xia, et al., J. Am. Chem. Soc. 137 (2015) 5590-5595. doi: 10.1021/jacs.5b02465
26. [26]
  G. Zhao, K. Rui, S.X. Dou, et al., Adv. Funct. Mater. 28 (2018) 1803291. doi: 10.1002/adfm.201803291
27. [27]
  T. Wu, M. Pi, X. Wang, et al., J. Alloys Compd. 729 (2017) 203-209. doi: 10.1016/j.jallcom.2017.09.118
28. [28]
  H. Sun, X. Xu, Z. Yan, et al., Chem. Mater. 29 (2017) 8539-8547. doi: 10.1021/acs.chemmater.7b03627
29. [29]
  Y. Shi, Y. Xu, S. Zhuo, et al., ACS Appl. Mater. Interfaces 7 (2015) 2376-2384. doi: 10.1021/am5069547
30. [30]
  Y. Lin, K. Sun, S. Liu, et al., Adv. Energy Mater. 9 (2019) 1901213. doi: 10.1002/aenm.201901213
31. [31]
  H. Liu, X. Ma, H. Hu, et al., ACS Appl. Mater. Interfaces 11 (2019) 15528-15536. doi: 10.1021/acsami.9b00592
32. [32]
  H. Du, R.M. Kong, X. Guo, et al., Nanoscale 10 (2018) 21617-21624. doi: 10.1039/C8NR07891B
33. [33]
  L. Feng, H. Vrubel, M. Bensimon, X. Hu, Phys. Chem. Chem. Phys. 16 (2014) 5917-5921. doi: 10.1039/c4cp00482e
34. [34]
  M.B. Gawande, A. Goswami, T. Asefa, et al., Chem. Soc. Rev. 44 (2015) 7540-7590. doi: 10.1039/C5CS00343A
35. [35]
  W. Li, S. Zhang, Q. Fan, et al., Nanoscale 9 (2017) 5677-5685. doi: 10.1039/C7NR01017F
36. [36]
  J. Wang, W. Cui, Q. Liu, et al., Adv. Mater. 28 (2016) 215-230. doi: 10.1002/adma.201502696
37. [37]
  P. Xiao, W. Chen, X. Wang, Adv. Energy Mater. 5 (2015) 1500985. doi: 10.1002/aenm.201500985
38. [38]
  Y. Li, J. Liu, C. Chen, X. Zhang, J. Chen, ACS Appl. Mater. Interfaces 9 (2017) 5982-5991. doi: 10.1021/acsami.6b14127
39. [39]
  Y. Yin, R.M. Rioux, C.K. Erdonmez, et al., Science 304 (2004) 711-714. doi: 10.1126/science.1096566
40. [40]
  X.Y. Yu, Y. Feng, Y. Jeon, et al., Adv. Mater. 28 (2016) 9006-9011. doi: 10.1002/adma.201601188
41. [41]
  J. Zhang, L. Zhang, X. Wang, W. Zhu, Z. Zhuang, Chem. Commun. 56 (2020) 90-93. doi: 10.1039/C9CC08256E
42. [42]
  Y.X. Zhu, L. Zhang, G.G. Zhu, X. Zhang, S.Y. Lu, Nanoscale 12 (2020) 5848-5856. doi: 10.1039/D0NR00051E
43. [43]
  Y. Meng, P. Sun, W. He, B. Teng, X. Xu, Nanoscale 11 (2019) 688-697. doi: 10.1039/C8NR07454B
44. [44]
  W. He, G. Zhao, P. Sun, et al., Nano Energy 56 (2019) 207-215. doi: 10.1016/j.nanoen.2018.11.048
45. [45]
  R. Cao, H. Yang, S. Zhang, X. Xu, Appl. Catal. B: Environ. 258 (2019) 117997. doi: 10.1016/j.apcatb.2019.117997
46. [46]
  G.L. Lu, X.B. Huang, Y. Li, et al., J. Energy Chem. 43 (2020) 8-15. doi: 10.1016/j.jechem.2019.07.014
47. [47]
  G. Zhao, S.H. Hao, J.H. Guo, et al., Chin. J. Catal. 42 (2021) 501-509. doi: 10.1016/S1872-2067(20)63670-1
48. [48]
  H.Y. Zheng, X.B. Huang, Z.Y. Wu, et al., Chem. Asian J. 12 (2017) 2956-2961. doi: 10.1002/asia.201701255
49. [49]
  Y.Q. Jia, J.Q. Xie, Y. Yang, et al., Chin. Chem. Lett. 31 (2020) 855-858. doi: 10.1016/j.cclet.2019.06.021
50. [50]
  H.Y. Zheng, X.B. Huang, H.Y. Gao, et al., Chem. Eur. J. 25 (2019) 1083-1089.
51. [51]
  G. Zhao, Y.M. Chen, P.X. Sun, et al., Nanoscale 12 (2020) 17849-17857. doi: 10.1039/D0NR05377E
52. [52]
  H.Y. Zheng, X.B. Huang, H.Y. Gao, et al., Appl. Surface Sci. 479 (2019) 1254-1261. doi: 10.1016/j.apsusc.2019.01.258
53. [53]
  L. Jiang, Z.Y. Wu, Y.N. Wang, et al., ACS Nano 13 (2019) 10376-10385. doi: 10.1021/acsnano.9b04165
54. [54]
  P.Y. Yang, Z.Y. Wu, Y.C. Jiang, et al., Adv. Energy Mater. 8 (2018) 1801392. doi: 10.1002/aenm.201801392
55. [55]
  Y.C. Jiang, Z.Y. Wu, L. Jiang, et al., Nanoscale 10 (2018) 12003-12010. doi: 10.1039/C8NR02924E
56. [56]
  Y.C. Jiang, Y. Song, Y.M. Li, et al., ACS Appl. Mater. Interfaces 9 (2017) 37645-37654. doi: 10.1021/acsami.7b09373
57. [57]
  M. Li, L. Xiao, D. Wang, et al., Chin. Chem. Lett. 30 (2019) 2328-2332. doi: 10.1016/j.cclet.2019.07.011
58. [58]
  Y.Q. Jiang, J.P. Liu, Energy Environ. Mater. 2 (2019) 30-37. doi: 10.1002/eem2.12028
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2. [2]
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  Haibin Yang , Duowen Ma , Yang Li , Qinghe Zhao , Feng Pan , Shisheng Zheng , Zirui Lou . Mo doped Ru-based cluster to promote alkaline hydrogen evolution with ultra-low Ru loading. Chinese Journal of Structural Chemistry, 2023, 42(11): 100031-100031. doi: 10.1016/j.cjsc.2023.100031
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