Citation: Tian Bai, Kongyin Zhao, Zijie Lu, Xuefang Liu, Ze Lin, Mengmeng Cheng, Ziyi Li, Dunwan Zhu, Linhua Zhang. Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties[J]. Chinese Chemical Letters, ;2021, 32(3): 1051-1054. doi: 10.1016/j.cclet.2020.07.034 shu

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

Tian Bai ^a ,
Kongyin Zhao ^{a, *,} ,
Zijie Lu ^a ,
Xuefang Liu ^a ,
Ze Lin ^a ,
Mengmeng Cheng ^a ,
Ziyi Li ^a ,
Dunwan Zhu ^b ,
Linhua Zhang ^b

a.
State Key Laboratory of Separation Membranes and Membrane Processes, Tiangong University, Tianjin 300387, China
b.
Tianjin Key Laboratory of Biomedical Materials, Key Laboratory of Biomaterials and Nanotechnology for Cancer Immunotherapy, Institute of Biomedical Engineering, Chinese Academy of Medical Sciences & Peking Union Medical College, Tianjin 300192, China

Received Date: 11 May 2020
Revised Date: 16 July 2020
Accepted Date: 17 July 2020
Available Online: 18 July 2020

Figures(4)

Herein, copper ion doped calcium alginate (Cu²⁺/CaAlg) composite hydrogel filtration membranes were prepared by using natural polymer sodium alginate (NaAlg) as raw material. The thermal stability and structure of the composite membranes were characterized by thermogravimetric analysis and infrared spectroscopy. The mechanical strength, anti-fouling performance, hydrophilicity and filtration performance of the membrane were studied. The results show that Cu²⁺/CaAlg hydrogel membrane has excellent mechanical properties and thermal stability. The anti-swelling ability of the membrane was greatly enhanced by doping Cu²⁺. After three alternate filtration cycles, the flux recovery rate of Cu²⁺/CaAlg hydrogel membrane can still reach 85%, indicating that the membrane has good anti-pollution performance. When the operation pressure was 0.1 MPa, the rejection of coomassie brilliant blue G250 reached 99.8% with a flux of 46.3 L m^-2 h^-1, while the Na₂SO₄ rejectionwas less than 10.0%. The Cu²⁺/CaAlg membrane was recycled after 24 h in the filtration process, and its flux and rejection rate did not decrease significantly, indicating that the hydrogel membrane has long-term application potential. The Cu²⁺/CaAlg membrane has a wide range of applications prospect in dye desalination, fine separation and biopharmaceutical technology fields.
- Calcium alginate,
- Cu²⁺ doped,
- Hydrogel,
- Filtration membrane,
- Antibacterial,
- Anti-fouling
1. [1]
  X. Wang, Y. Pan, H. Yuan, et al., Chin. Chem. Lett. 31(2020) 365-368. doi: 10.1016/j.cclet.2019.07.044
2. [2]
  J. Shan, W. Wei, D. Yonghong, et al., Chin. Chem. Lett. 29(2018) 390-394. doi: 10.1016/j.cclet.2018.01.006
3. [3]
  S. Yuan, G. Zhang, J. Zhu, J. Mater. Chem. A 8(2020) 3238-3245. doi: 10.1039/C9TA12984G
4. [4]
  Q. Nie, F. Ran, C. He, et al., Chin. Chem. Lett. 22(2011) 370-373. doi: 10.1016/j.cclet.2010.10.017
5. [5]
  J. Guo, K. Zhao, X. Zhang, et al., Mater. Lett. 157(2015) 112-115. doi: 10.1016/j.matlet.2015.05.080
6. [6]
  J. Li, S. Li, X. Wang, et al., Chin. Chem. Lett. 30(2019) 239-242. doi: 10.1016/j.cclet.2018.07.016
7. [7]
  J. Zhu, M. Tian, J. Hou, et al., J. Mater. Chem. A 4(2016) 1980-1990. doi: 10.1039/C5TA08024J
8. [8]
  S. Gao, Y. Zhu, Y. Gong, et al., ACS Nano 13(2019) 5278-5290. doi: 10.1021/acsnano.8b09761
9. [9]
  P. Zhong, N. Widjojo, T. Chung, et al., J. Membr. Sci. 417(2012) 52-60.
10. [10]
  J.H. Jhaveri, Z.V.P. Murthy, Desalination 379(2016) 137-154. doi: 10.1016/j.desal.2015.11.009
11. [11]
  M. Min, Y. Liu, C. Song, et al., ACS Appl. Mater. Inter. 10(2018) 21246-21253. doi: 10.1021/acsami.8b03411
12. [12]
  X. Deng, N. Chao, W. Ding, et al., J. Biomed. Nanotechnol. 15(2019) 756-768. doi: 10.1166/jbn.2019.2713
13. [13]
  Y. Cai, J. Zhang, Y. He, et al., Int. J. Biomed. Nanotechnol. 14(2018) 257-266. doi: 10.1166/jbn.2018.2483
14. [14]
  S. Gao, S.Y. Zhu, J. Wang, et al., Adv. Funct. Mater. 28(2018) 1801944. doi: 10.1002/adfm.201801944
15. [15]
  E.G. Deze, S.K. Papageorgiou, E.P. Favvas, et al., Chem. Eng. J. 209(2012) 537-546. doi: 10.1016/j.cej.2012.07.133
16. [16]
  K. Zhao, X. Zhang, J. Wei, et al., J. Membr. Sci. 492(2015) 536-546. doi: 10.1016/j.memsci.2015.05.075
17. [17]
  Y.N. Mata, M.L. Blázquez, A. Ballester, et al., J. Hazard. Mater. 163(2009) 555-562. doi: 10.1016/j.jhazmat.2008.07.015
18. [18]
  L.D. Nghiem, A.I. Schäfer, M. Elimelech, et al., J. Membr. Sci. 286(2006) 52-59. doi: 10.1016/j.memsci.2006.09.011
19. [19]
  W. Ye, K. Ye, F. Lin, et al., Chem. Eng. J. 379(2020) 122321. doi: 10.1016/j.cej.2019.122321
20. [20]
  N. Wang, X. Li, L. Wang, et al., ACS Appl. Mater. Interfaces 8(2016) 21979-21983. doi: 10.1021/acsami.6b08581
1. [1]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
2. [2]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
3. [3]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
4. [4]
  Xiaoliu Liang , Chunliu Huang , Hui Liu , Hu Chen , Jiabao Shou , Hongwei Cheng , Gang Liu . Natural hydrogel dressings in wound care: Design, advances, and perspectives. Chinese Chemical Letters, 2024, 35(10): 109442-. doi: 10.1016/j.cclet.2023.109442
5. [5]
  Haijun Shen , Yi Qiao , Chun Zhang , Yane Ma , Jialing Chen , Yingying Cao , Wenna Zheng . A matrix metalloproteinase-sensitive hydrogel combined with photothermal therapy for transdermal delivery of deferoxamine to accelerate diabetic pressure ulcer healing. Chinese Chemical Letters, 2024, 35(12): 110283-. doi: 10.1016/j.cclet.2024.110283
6. [6]
  Xi Chen , Xue Zhang , Shuai Yang , Jie Wang , Tian Tang , Maling Gou . An adhesive hydrogel for the treatment of oral ulcers. Chinese Chemical Letters, 2025, 36(3): 110021-. doi: 10.1016/j.cclet.2024.110021
7. [7]
  Yue Ren , Kang Li , Yi-Zi Wang , Shao-Peng Zhao , Shu-Min Pan , Haojie Fu , Mengfan Jing , Yaming Wang , Fengyuan Yang , Chuntai Liu . Swelling and erosion assisted sustained release of tea polyphenol from antibacterial ultrahigh molecular weight polyethylene for joint replacement. Chinese Chemical Letters, 2025, 36(2): 110468-. doi: 10.1016/j.cclet.2024.110468
8. [8]
  Ningyue Xu , Jun Wang , Lei Liu , Changyang Gong . Injectable hydrogel-based drug delivery systems for enhancing the efficacy of radiation therapy: A review of recent advances. Chinese Chemical Letters, 2024, 35(8): 109225-. doi: 10.1016/j.cclet.2023.109225
9. [9]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
10. [10]
  Feng Cui , Fangman Chen , Xiaochun Xie , Chenyang Guo , Kai Xiao , Ziping Wu , Yinglu Chen , Junna Lu , Feixia Ruan , Chuanxu Cheng , Chao Yang , Dan Shao . Scalable production of mesoporous titanium nanoparticles through sequential flash nanocomplexation. Chinese Chemical Letters, 2024, 35(4): 108681-. doi: 10.1016/j.cclet.2023.108681
11. [11]
  Wen Zhong , Dan Zheng , Xukun Liao , Yadi Zhou , Yan Jiang , Ting Gao , Ming Li , Chengli Yang . Elaborate construction of pH-sensitive polymyxin B loaded nanoparticles for safe and effective treatment of carbapenem-resistant Klebsiella pneumoniae. Chinese Chemical Letters, 2025, 36(3): 110448-. doi: 10.1016/j.cclet.2024.110448
12. [12]
  Yueying Wang , Jianming Xiong , Linwei Xin , Yuanyuan Li , He Huang , Wenjun Miao . Photosensitizer-synergized g-carbon nitride nanosheets with enhanced photocatalytic activity for eradicating drug-resistant bacteria and promoting wound healing. Chinese Chemical Letters, 2025, 36(4): 110003-. doi: 10.1016/j.cclet.2024.110003
13. [13]
  Yang Xu , Le Ma , Yang Wang , Chunmeng Shi . Engineering strategies of biomaterial-assisted exosomes for skin wound repair: Latest advances and challenges. Chinese Chemical Letters, 2025, 36(1): 109766-. doi: 10.1016/j.cclet.2024.109766
14. [14]
  Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012
15. [15]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
16. [16]
  Qiang Zhou , Pingping Zhu , Wei Shao , Wanqun Hu , Xuan Lei , Haiyang Yang . Innovative Experimental Teaching Design for 3D Printing High-Strength Hydrogel Experiments. University Chemistry, 2024, 39(6): 264-270. doi: 10.3866/PKU.DXHX202310064
17. [17]
  Qingyang Cui , Feng Yu , Zirun Wang , Bangkun Jin , Wanqun Hu , Wan Li . From Jelly to Soft Matter: Preparation and Properties-Exploring of Different Kinds of Hydrogels. University Chemistry, 2024, 39(9): 338-348. doi: 10.3866/PKU.DXHX202309046
18. [18]
  Xinyue Lan , Junguang Liang , Churan Wen , Xiaolong Quan , Huimin Lin , Qinqin Xu , Peixian Chen , Guangyu Yao , Dan Zhou , Meng Yu . Photo-manipulated polyunsaturated fatty acid-doped liposomal hydrogel for flexible photoimmunotherapy. Chinese Chemical Letters, 2024, 35(4): 108616-. doi: 10.1016/j.cclet.2023.108616
19. [19]
  Jianwen Zhao , Shuai Wang , Shanshan Zhao , Liwei Chen , Fangang Meng , Xuelin Tian . A non-fluorinated liquid-like membrane with excellent anti-scaling performance for membrane distillation. Chinese Chemical Letters, 2025, 36(1): 109883-. doi: 10.1016/j.cclet.2024.109883
20. [20]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(973)
HTML views(142)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Simple fabrication of Cu2+ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties

Metrics

通讯作者: 陈斌, bchen63@163.com

Simple fabrication of Cu²⁺ doped calcium alginate hydrogel filtration membrane with excellent anti-fouling and antibacterial properties