Citation: Bao Qiwen, Li Gang, Yang Zhengchun, Pan Peng, Liu Jun, Chang Jiayuan, Wei Jun, Lin Ling. Electrochemical performance of a three-layer electrode based on Bi nanoparticles, multi-walled carbon nanotube composites for simultaneous Hg(Ⅱ) and Cu(Ⅱ) detection[J]. Chinese Chemical Letters, ;2020, 31(10): 2752-2756. doi: 10.1016/j.cclet.2020.06.021 shu

Electrochemical performance of a three-layer electrode based on Bi nanoparticles, multi-walled carbon nanotube composites for simultaneous Hg(Ⅱ) and Cu(Ⅱ) detection

Bao Qiwen ^a,1 ,
Li Gang ^a,1 ,
Yang Zhengchun ^b ,
Pan Peng ^b ,
Liu Jun ^b ,
Chang Jiayuan ^b ,
Wei Jun ^b,c ,
Lin Ling ^a,*,

a.
School of Precision Instrument and Optoelectronic Engineering, the State Key Laboratory of Precision Measuring Technology and Instruments, Tianjin University Tianjin 300072, China
b.
School of Electrical and Electronic Engineering, Tianjin Key Laboratory of Film Electronic & Communication Devices, Advanced Materials and Printed Electronics Center, Tianjin University of Technology, Tianjin 300384, China
c.
Agency for Science, Technology and Research(A*STAR), Singapore Institute of Manufacturing Technology, Singapore 638075, Singapore

linling@tju.edu.cn

Received Date: 5 April 2020
Revised Date: 23 May 2020
Accepted Date: 11 June 2020
Available Online: 18 June 2020

Figures(4)

Electrochemical analysis is a promising technique for detecting biotoxic and non-biodegradable heavy metals. This article proposes a novel composite electrode based on a polyaniline (PANi) framework doped with bismuth nanoparticle@graphene oxide multi-walled carbon nanotubes (Bi NPs@GO-MWCNTs) for the simultaneous detection of multiple heavy metal ions. Composite electrodes are prepared on screen-printed electrodes (SPCEs) using an efficient dispensing technique. We used a SM200SX-3A dispenser to load a laboratory-specific ink with optimized viscosity and adhesion to draw a pattern on the work area. The SPCE was used as substrate to facilitate cost-effective and more convenient real-time detection technology. Electrochemical techniques, such as cyclic voltammetry and differential pulse voltammetry, were used to demonstrate the sensing capabilities of the proposed sensor. The sensitivity, limit of detection, and linear range of the PANi-Bi NPs@GO-MWCNT electrode are 2.57×10² μA L μmol^-1 cm^-2, 0.01 nmol/L, and 0.01 nmol/L–5 mmol/L and 0.15×10^-1 μA L μmol^-1 cm^-2, 0.5 nmol/L, and 0.5 nmol/L–5 mmol/L for mercury ion (Hg(Ⅱ)) and copper ion (Cu(Ⅱ)) detection, respectively. In addition, the electrode exhibits a good selectivity and repeatability for Hg(Ⅱ) and Cu(Ⅱ) sensing when tested in a complex heavy metal ion solution. The constructed electrode system exhibits a detection performance superior to similar methods and also increases the types of heavy metal ions that can be detected. Therefore, the proposed device can be used as an efficient sensor for the detection of multiple heavy metal ions in complex environments.
- Bismuth nanoparticle,
- Multi-walled carbon nanotube,
- Electrochemical sensor,
- Hg(Ⅱ),
- Cu(Ⅱ)
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