Citation: Huang Zhiling, Xu Qin, Hu Xiaoya. Covalent organic frameworks functionalized carbon fiber paper for the capture and detection of hydroxyl radical in the atmosphere[J]. Chinese Chemical Letters, ;2020, 31(9): 2495-2498. doi: 10.1016/j.cclet.2020.06.017 shu

Covalent organic frameworks functionalized carbon fiber paper for the capture and detection of hydroxyl radical in the atmosphere

Huang Zhiling ^a ,
Xu Qin ^a,*, ,
Hu Xiaoya ^a,b,*,

a.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China
b.
Guangling College, Yangzhou University, Yangzhou 225002, China

xuqin@yzu.edu.cn

xyhu@yzu.edu.cn

Received Date: 17 March 2020
Revised Date: 8 June 2020
Accepted Date: 10 June 2020
Available Online: 11 June 2020

Figures(6)

Developing a fast, sensitive and convenient method for the detection of hydroxyl radicals (^·OH) in the atmosphere could help us know the precursor levels of atmospheric species and control air pollution. In this work, the carbon fiber paper (CFP) functionalizing with a kind of covalent organic frameworks (COFs), formed from 1, 3, 5-triformylphloroglucinol (Tp) and benzidine (BD) (COF(TpBD)), was firstly used a new platform for ^·OH trapping and detection. The COF(TpBD) modified CFP was acted as a filter to impregnate salicylic acid (SA) and a detector to detect 2, 5-dihydroxybenzoic acid (2, 5-DHBA) which was produced from the reaction between the impregnated SA and ^·OH in the atmosphere. This method provided a linearity for 2, 5-DHBA from 5.0×10^-14 mol/L 1.0×10^-9 mol/L with a detection limit of 6.9×10^-15 mol/L, which is corresponding to the amount of ^·OH from 3.0×10⁷ to 6.0×10¹¹ molecules/cm³ with the detection limit of 4.1×10⁶ molecules/cm³. This COF(TpBD)-CFP platform has been successfully applied for the detection of ^·OH concentration under different conditions of Yangzhou when the sampling time was shortened to 30 min. This work has provided a new method for atmospheric ^·OH detection with excellent sensitivity, simplicity, and high speed.
- Covalent organic frameworks,
- Hydroxyl radical,
- Electrochemical,
- Detection
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