Citation: Wei Li, Shilin Xu, Xiaoling Chen, Chengyong Xu. Structural transformations of carboxyl acids networks induced by concentration and oriented external electric field[J]. Chinese Chemical Letters, ;2021, 32(1): 480-484. doi: 10.1016/j.cclet.2020.06.012 shu

Structural transformations of carboxyl acids networks induced by concentration and oriented external electric field

School of Science, Nanchang Institute of Technology, Nanchang 330099, China

liweidting@nit.edu.cn

Received Date: 8 March 2020
Revised Date: 4 June 2020
Accepted Date: 5 June 2020
Available Online: 10 June 2020

Figures(5)

The effects of concentration and an oriented external electric field on the transformations of hydrogenbonded structures of trimesic acid (TMA) and terephthalic acid (TPA) have been investigated at a liquid–solid interface by scanning tunneling microscopy (STM). The triangular periodic TMA framework can be transformed into a flower-like structure by changing the STM sample bias sign in situ. Networks of TMA and TPA are porous at a negative substrate bias, but typically change to relatively compact forms when the polarity of the applied bias is reversed. This change is reversible if the applied bias is reversed. The effects have potentials to locally control the capture and release of analytes in host-guest systems and the 2D morphology in multicomponent layers.
- Concentration,
- Electric field,
- Structural transformation,
- Scanning tunneling microscopy
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