Citation: Fu-Sheng He, Min Yang, Shengqing Ye, Jie Wu. Sulfonylation from sodium dithionite or thiourea dioxide[J]. Chinese Chemical Letters, ;2021, 32(1): 461-464. doi: 10.1016/j.cclet.2020.04.043 shu

Sulfonylation from sodium dithionite or thiourea dioxide

Fu-Sheng He ^a ,
Min Yang ^b ,
Shengqing Ye ^a ,
Jie Wu ^{a, c, *,}

a.
School of Pharmaceutical and Materials Engineering & Institute for Advanced Studies, Taizhou University, Taizhou 318000, China
b.
School of Basic Medicine, Gannan Medical University, Ganzhou 341000, China
c.
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

jie_wu@fudan.edu.cn

Received Date: 31 March 2020
Revised Date: 21 April 2020
Accepted Date: 23 April 2020
Available Online: 12 February 2020

Figures(6)

The cheap and easily available sodium dithionite and thiourea dioxide have been used as the source of sulfonyl group in the synthesis of sulfones and sulfonamides recently. Compared with other methods for the sulfonylation reactions, the strategies using sodium dithionite or thiourea dioxide provide an alternative and complementary route to diverse sulfonyl compounds. During the reaction process, sulfur dioxide anion radical is the key intermediate, which is usually generated from a single electron transfer under suitable conditions. The advantages using sodium dithionite or thiourea dioxide in the sulfonylation reactions include mild conditions and broad substrate scope with excellent functional group compatibility. Further applications by using sodium dithionite and thiourea dioxide in organic transformations will be anticipated.
- Sodium dithionite,
- Thioureadioxide,
- Sulfones,
- Sulfonamides,
- Sulfur dioxide anion radical
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