Citation: Hou Xiankun, Li Wenhao, Wang Yingying, Li Shaofang, Meng Yunfeng, Yu Haiyue, Chen Baokuan, Wu Xinglong. Sodium-based dual-ion batteries via coupling high-capacity selenium/graphene anode with high-voltage graphite cathode[J]. Chinese Chemical Letters, ;2020, 31(9): 2314-2318. doi: 10.1016/j.cclet.2020.04.021 shu

Sodium-based dual-ion batteries via coupling high-capacity selenium/graphene anode with high-voltage graphite cathode

Hou Xiankun ^a ,
Li Wenhao ^a ,
Wang Yingying ^b ,
Li Shaofang ^a ,
Meng Yunfeng ^a ,
Yu Haiyue ^a ,
Chen Baokuan ^c,*, ,
Wu Xinglong ^a,b,*,

a.
National & Local United Engineering Lab for Power Battery, Department of Chemistry, Northeast Normal University, Changchun 130024, China
b.
Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun 130024, China
c.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China

^**

chenbaokuan@lnpu.edu.cn

xinglong@nenu.edu.cn

Received Date: 19 February 2020
Revised Date: 8 April 2020
Accepted Date: 28 April 2020
Available Online: 4 May 2020

Figures(4)

Dual ion batteries (DIBs) exhibit broad application prospects in the field of electrical energy storage (EES) devices with excellent properties, such as high voltage, high energy density, and low cost. In the graphitebased DIBs, high voltage is needed to store enough anions with the formation of anion intercalation compound XC_n (X = AlCl₄^-, PF₆^-, TFSI^-, etc.). Hence, it is difficult for graphite-based DIBs to match proper anodes and electrolytes. Here, an Se/graphene composite is prepared via a convenient method, and assembled into a dual-ion full battery (DIFB) as anode with graphite cathode and 1 mol/L NaPF₆ in EC: EMC (1:1, v:v). This DIFB has achieved a high discharge capacity of 75.9 mAh/g and high medium output voltage of 3.5 V at 0.1 A/g. Actually, the suitable anode materials, such as the present Se/graphene composite, are extremely important for the development and application of graphite-based DIBs. This study is enlightening for the design of future low-cost EES devices including graphite-based DIBs.
- Dual ion batteries,
- High-capacity anode,
- Se/grapheme,
- High-voltage cathode,
- Graphite
1. [1]
  B. Scrosati, J. Hassoun, Y.K. Sun, Energy Environ. Sci. 4(2011) 3287. doi: 10.1039/c1ee01388b
2. [2]
  J. Song, D.W. Shin, Y. Lu, et al., Chem. Mater. 24(2012) 3101-3109. doi: 10.1021/cm301825h
3. [3]
  L.X. Yuan, Z.H. Wang, W.X. Zhang, et al., Energy Environ. Sci. 4(2011) 269-284. doi: 10.1039/C0EE00029A
4. [4]
  Y. Yang, J.Z. Guo, Z.Y. Gu, et al., ACS Sustainable Chem. Eng. 7(2019) 12014-12022.
5. [5]
  Z. Jian, W. Wang, M. Wang, et al., Chin. Chem. Lett. 29(2018) 1768-1772. doi: 10.1016/j.cclet.2018.11.002
6. [6]
  M.D. Slater, D. Kim, E. Lee, C.S. Johnson, Adv. Funct. Mater. 23(2013) 947-958. doi: 10.1002/adfm.201200691
7. [7]
  L. Wang, J. Song, R. Qiao, et al., J. Am. Chem. Soc. 137(2015) 2548-2554. doi: 10.1021/ja510347s
8. [8]
  N. Yabuuchi, K. Kubota, M. Dahbi, S. Komaba, Chem. Rev. 114(2014) 11636-11682. doi: 10.1021/cr500192f
9. [9]
  J.Z. Guo, P.F. Wang, X.L. Wu, et al., Adv. Mater. 29(2017) 1701968. doi: 10.1002/adma.201701968
10. [10]
  Z.Y. Gu, J.Z. Guo, Z.H. Sun, et al., Sci. Bull. 65(2020) 702-710. doi: 10.1016/j.scib.2020.01.018
11. [11]
  H.J. Liang, B.H. Hou, W.H. Li, et al., Energy Environ. Sci. 12(2019) 3575-3584. doi: 10.1039/C9EE02759A
12. [12]
  W. Luo, J. Wan, B. Ozdemir, et al., Nano Lett. 15(2015) 7671-7677. doi: 10.1021/acs.nanolett.5b03667
13. [13]
  S. Komaba, T. Hasegawa, M. Dahbi, K. Kubota, Electrochem. Commun. 60(2015) 172-175. doi: 10.1016/j.elecom.2015.09.002
14. [14]
  W.H. Li, Q.L. Ning, X.T. Xi, et al., Adv. Mater. 31(2019) 1804766. doi: 10.1002/adma.201804766
15. [15]
  L. Fan, Q. Liu, S. Chen, et al., Small 13(2017) 1701011. doi: 10.1002/smll.201701011
16. [16]
  M. Sheng, F. Zhang, B. Ji, X. Tong, Y. Tang, Adv. Energy Mater. 7(2017) 1601963. doi: 10.1002/aenm.201601963
17. [17]
  X. Zhang, Y. Tang, F. Zhang, C.S. Lee, Adv. Energy Mater. 6(2016) 1502588. doi: 10.1002/aenm.201502588
18. [18]
  N. Jayaprakash, S.K. Das, L.A. Archer, Chem. Commun. 47(2011) 12610-12612. doi: 10.1039/c1cc15779e
19. [19]
  X. Qi, B. Blizanac, A. DuPasquier, et al., Phys. Chem. Chem. Phys. 16(2014) 25306-25313. doi: 10.1039/C4CP04113E
20. [20]
  M. Balabajew, T. Kranz, B. Roling, ChemElectroChem 2(2015) 1991-2000. doi: 10.1002/celc.201500320
21. [21]
  S. Wang, Z. Yu, J. Tu, et al., Adv. Energy Mater. 6(2016) 1600137. doi: 10.1002/aenm.201600137
22. [22]
  B. Ji, W. Yao, Y. Tang, Sustain. Energy Fuel. 4(2020) 101-107. doi: 10.1039/C9SE00744J
23. [23]
  W. Luo, F. Shen, C. Bommier, et al., Acc. Chem. Res. 49(2016) 231-240. doi: 10.1021/acs.accounts.5b00482
24. [24]
  Y. Kim, K.H. Ha, S.M. Oh, K.T. Lee, Chem. Eur. J. 20(2014) 11980-11992. doi: 10.1002/chem.201402511
25. [25]
  B.H. Hou, Y.Y. Wang, Q.L. Ning, et al., Adv. Mater. 31(2019) e1903125. doi: 10.1002/adma.201903125
26. [26]
  Y. Chen, B. Wang, T. Hou, et al., Chin. Chem. Lett. 29(2018) 187-190. doi: 10.1016/j.cclet.2017.06.019
27. [27]
  X. Yang, Y.Y. Wang, B.H. Hou, et al., Acta Metall. Sin. Engl. (2020), doi:http://dx.doi.org/10.1007/s40195-020-01001-7. doi: 10.1007/s40195-020-01001-7
28. [28]
  H. Xiong, M.D. Slater, M. Balasubramanian, C.S. Johnson, T. Rajh, J. Phys. Chem. Lett. 2(2011) 2560-2565. doi: 10.1021/jz2012066
29. [29]
  X. Wang, L. Qi, H. Wang, ACS Appl. Mater. Interfaces 11(2019) 30453-30459. doi: 10.1021/acsami.9b09703
30. [30]
  L. Sui, X. Shi, T. Deng, et al., J. Energy Chem. 37(2019) 7-12. doi: 10.1016/j.jechem.2018.11.009
31. [31]
  Z. Hu, Q. Liu, K. Zhang, et al., ACS Appl. Mater. Interfaces 10(2018) 35978-35983. doi: 10.1021/acsami.8b11824
32. [32]
  L. Fan, Q. Liu, S. Chen, Z. Xu, B. Lu, Adv. Energy Mater. 7(2017) 1602778. doi: 10.1002/aenm.201602778
33. [33]
  Y. Liu, Z. Tai, Q. Zhang, et al., Nano Energy 35(2017) 36-43. doi: 10.1016/j.nanoen.2017.03.029
34. [34]
  J. Xu, W. Wei, X. Zhang, L. Liang, M. Xu, Chin. Chem. Lett. 30(2019) 1341-1345. doi: 10.1016/j.cclet.2019.03.005
35. [35]
  J. Zhou, Y. Zhou, X. Zhang, et al., Nanoscale 12(2020) 79-84. doi: 10.1039/C9NR08783D
36. [36]
  Y.Y. Wang, B.H. Hou, J.Z. Guo, et al., Adv. Energy Mater. 8(2018) 1703252. doi: 10.1002/aenm.201703252
37. [37]
  A. Abouimrane, D. Dambournet, K.W. Chapman, et al., J. Am. Chem. Soc. 134(2012) 4505-4508. doi: 10.1021/ja211766q
38. [38]
  L.G. Guex, B. Sacchi, K.F. Peuvot, et al., Nanoscale 9(2017) 9562-9571. doi: 10.1039/C7NR02943H
39. [39]
  A. Li, P. Du, Z. Chen, et al., Ionics 21(2015) 2431-2438. doi: 10.1007/s11581-015-1429-8
40. [40]
  Q. Li, H. Liu, Z. Yao, et al., ACS Nano 10(2016) 8788-8795. doi: 10.1021/acsnano.6b04519
41. [41]
  S. Aladinli, F. Bordet, K. Ahlbrecht, J. Tübke, M. Holzapfel, Electrochim. Acta 231(2017) 468-478. doi: 10.1016/j.electacta.2017.02.041
42. [42]
  N. Li, Y. Xin, H. Chen, et al., J. Energy Chem. 29(2019) 122-128. doi: 10.1016/j.jechem.2018.03.003
43. [43]
  J. Xu, R.D. Deshpande, J. Pan, Y.T. Cheng, V.S. Battaglia, J. Electrochem. Soc. 162(2015) A2026-A2035. doi: 10.1149/2.0291510jes
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