Citation: Hou Xiankun, Li Wenhao, Wang Yingying, Li Shaofang, Meng Yunfeng, Yu Haiyue, Chen Baokuan, Wu Xinglong. Sodium-based dual-ion batteries via coupling high-capacity selenium/graphene anode with high-voltage graphite cathode[J]. Chinese Chemical Letters, ;2020, 31(9): 2314-2318. doi: 10.1016/j.cclet.2020.04.021 shu

Sodium-based dual-ion batteries via coupling high-capacity selenium/graphene anode with high-voltage graphite cathode

Hou Xiankun ^a ,
Li Wenhao ^a ,
Wang Yingying ^b ,
Li Shaofang ^a ,
Meng Yunfeng ^a ,
Yu Haiyue ^a ,
Chen Baokuan ^c,*, ,
Wu Xinglong ^a,b,*,

a.
National & Local United Engineering Lab for Power Battery, Department of Chemistry, Northeast Normal University, Changchun 130024, China
b.
Key Laboratory for UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, Changchun 130024, China
c.
College of Chemistry, Chemical Engineering and Environmental Engineering, Liaoning Shihua University, Fushun 113001, China

^**

chenbaokuan@lnpu.edu.cn

xinglong@nenu.edu.cn

Received Date: 19 February 2020
Revised Date: 8 April 2020
Accepted Date: 28 April 2020
Available Online: 4 May 2020

Figures(4)

Dual ion batteries (DIBs) exhibit broad application prospects in the field of electrical energy storage (EES) devices with excellent properties, such as high voltage, high energy density, and low cost. In the graphitebased DIBs, high voltage is needed to store enough anions with the formation of anion intercalation compound XC_n (X = AlCl₄^-, PF₆^-, TFSI^-, etc.). Hence, it is difficult for graphite-based DIBs to match proper anodes and electrolytes. Here, an Se/graphene composite is prepared via a convenient method, and assembled into a dual-ion full battery (DIFB) as anode with graphite cathode and 1 mol/L NaPF₆ in EC: EMC (1:1, v:v). This DIFB has achieved a high discharge capacity of 75.9 mAh/g and high medium output voltage of 3.5 V at 0.1 A/g. Actually, the suitable anode materials, such as the present Se/graphene composite, are extremely important for the development and application of graphite-based DIBs. This study is enlightening for the design of future low-cost EES devices including graphite-based DIBs.
- Dual ion batteries,
- High-capacity anode,
- Se/grapheme,
- High-voltage cathode,
- Graphite
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