Citation: Du Wei, Bai Yue-Ling, Yang Zhen, Li Runlong, Zhang Dan, Ma Zhiheng, Yuan Anbao, Xu Jiaqiang. A conductive anionic Co-MOF cage with zeolite framework for supercapacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2309-2313. doi: 10.1016/j.cclet.2020.04.017 shu

A conductive anionic Co-MOF cage with zeolite framework for supercapacitors

College of Science, Shanghai University, Shanghai 200444, China

yuelingbai@shu.edu.cn

xujiaqiang@shu.edu.cn

Received Date: 20 February 2020
Revised Date: 7 April 2020
Accepted Date: 8 April 2020
Available Online: 20 April 2020

Figures(7)

Conductive MOFs could exhibit full potential as integrated electrode materials for supercapacitors without interference from additional conductive additives. Here we report an anionic Co-MOF cage with zeolite framework, which was balanced by the redox-active guest [Co(H₂O)₆]²⁺ and protonated [(CH₃)₂NH₂]²⁺ ions. Benefit from the unique ion skeleton structure, Co-MOF exhibits a conductivity higher than most of reported MOFs with the value of 1.42×10^-3 S/cm, which can be directly fabricated as electrode for supercapacitors. A maximum specific capacitance of 236.2 F/g can be achieved at a current density of 1 A/g of Co-MOF. Additionally, the electric performance and morphology of this Co-MOF can be modified by cetyltrimethylammonium bromide (CTAB) and the maximum specific capacitance could increase up to 334 F/g at 1 A/g when the ratio of ligand and CTAB is 1:6 (Co-MOF-6). Furthermore, the specific capacitance can retain at 64.04% and 77.92% of the initial value after 3000 cycles of Co-MOF and Co-CTAB-6, respectively. Obviously, the addition of CTAB further improves both capacitance and cycle stability.
- Metal organic frameworks,
- Supercapacitors,
- Cetyltrimethylammonium bromide,
- In-situ growth,
- Redox-active guest
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