Citation: Yan Xu, Chenguang Wu, Yan Wang, Ying Zhang, Han Sun, Haijun Chen, Yujun Zhao. Cooperation between Pt and Ru on RuPt/AC bimetallic catalyst in the hydrogenation of phthalates[J]. Chinese Chemical Letters, ;2021, 32(1): 516-520. doi: 10.1016/j.cclet.2020.04.016 shu

Cooperation between Pt and Ru on RuPt/AC bimetallic catalyst in the hydrogenation of phthalates

Yan Xu ^a ,
Chenguang Wu ^a ,
Yan Wang ^a ,
Ying Zhang ^a ,
Han Sun ^b ,
Haijun Chen ^b ,
Yujun Zhao ^{a, *,}

a.
Key Laboratory for Green Chemical Technology of Ministry of Education, Collaborative Innovation Center of Chemical Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
b.
College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300350, China

yujunzhao@tju.edu.cn

Received Date: 1 March 2020
Revised Date: 14 March 2020
Accepted Date: 8 April 2020
Available Online: 18 January 2020

Figures(4)

RuPt/AC bimetallic catalysts were prepared by two-step incipient impregnation method and evaluated in the hydrogenation of phthalates. According to the characterization results, well dispersed RuPt bimetallic nanoparticles were formed on the catalyst, and the strong interaction between the two metals resulted in the formation of RuPt alloy. It was found that Ru can donate electrons to Pt on RuPt alloy nanoparticles, leading to the formation of electron-deficient Ru which significantly promotes the hydrogenation rate of dioctyl phthalate and improves the selectivity of dioctyl di-2-ethylhexylcyclohexane-1, 4-dicarboxylate by accelerating the further hydrogenation of intermediate products. The bimetallic RuPt catalyst also presented excellent stability and versatility in the hydrogenation of phthalates, demonstrating its prospective future in the hydrogenation of aromatic ring contained compounds.
- Ru,
- RuPt alloy,
- Bimetallic catalyst,
- Phthalates,
- Hydrogenation
1. [1]
  Z.L. Ye, C.Q. Cao, J.C. He, R.X. Zhang, H.Q. Hou, Chin. Chem. Lett. 20(2009) 706-710. doi: 10.1016/j.cclet.2008.12.033
2. [2]
  J. Li, Y. Li, Z. Xiong, G. Yao, B. Lai, Chin. Chem. Lett. 30(2019) 2139-2146. doi: 10.1016/j.cclet.2019.04.057
3. [3]
  A. Jankowska, K. Polńnska, H. M. Koch, et al., Environ. Res. 179(2019) 108829. doi: 10.1016/j.envres.2019.108829
4. [4]
  A. Schuetze, C. Paelmke, J. Angerer, et al., J. Chromatogr. B-Analyt. Technol. Biomed. Life Sci. 895(2012) 123-130.
5. [5]
  B.L. Wadey, J. Vinyl Add. Technol. 9(2003) 172-176. doi: 10.1002/vnl.10080
6. [6]
  E. Qu, J. Luo, X. Di, C. Li, C. Liang, J. Nanosci. Nanotechnol. 20(2020) 1140-1147. doi: 10.1166/jnn.2020.16965
7. [7]
  J. Chen, X. Liu, F. Zhang, Chem. Eng. J. 259(2015) 43-52. doi: 10.1016/j.cej.2014.07.049
8. [8]
  Z. Yang, J. Han, Q. Fan, H. Jia, F. Zhang, Appl. Catal. A: Gen. 568(2018) 183-190. doi: 10.1016/j.apcata.2018.09.021
9. [9]
  H. Jia, Z. Yang, X. Yun, et al., Ind. Eng. Chem. Res. 58(2019) 22702-22708. doi: 10.1021/acs.iecr.9b03315
10. [10]
  X. Li, Z. Sun, J. Chen, Y. Zhu, F. Zhang, Ind. Eng. Chem. Res. 53(2014) 619-625. doi: 10.1021/ie402987c
11. [11]
  Y. Xu, Y. Wang, C. Wu, et al., Catal. Commun. 132(2019) 105825. doi: 10.1016/j.catcom.2019.105825
12. [12]
  Z. Zhao, T. Bao, Y. Zeng, G. Wang, T. Muhammad, Catal. Commun. 32(2013) 47-51. doi: 10.1016/j.catcom.2012.12.001
13. [13]
  N. Gong, Z. Zhao, Mol. Catal. 477(2019) 110543. doi: 10.1016/j.mcat.2019.110543
14. [14]
  K. Xiong, J. Li, K. Liew, X. Zhan, Appl. Catal. A: Gen. 389(2010) 173-178. doi: 10.1016/j.apcata.2010.09.012
15. [15]
  J. Zhang, J. Wang, Z. Shi, Z. Xu, Chin. Chem. Lett. 29(2018) 620-623. doi: 10.1016/j.cclet.2018.01.031
16. [16]
  J.Y. Park, Y.J. Lee, P.R. Karandikar, et al., J. Mol. Catal. A: Chem. 344(2011) 153-160. doi: 10.1016/j.molcata.2011.05.022
17. [17]
  P.P. Upare, M. Lee, S.K. Lee, et al., Catal. Today 265(2016) 174-183. doi: 10.1016/j.cattod.2015.09.042
18. [18]
  J. Teddy, A. Falqui, A. Corrias, et al., J. Catal. 278(2011) 59-70. doi: 10.1016/j.jcat.2010.11.016
19. [19]
  G.Y. Fan, W.J. Huang, Chin. Chem. Lett. 25(2014) 359-363. doi: 10.1016/j.cclet.2013.11.044
20. [20]
  J. Zhang, F. Lin, L. Yang, Z. He, et al., Chin. Chem. Lett. 31(2020) 2019-2022. doi: 10.1016/j.cclet.2019.11.042
21. [21]
  K. Guo, Y. Liu, M. Han, D. Xu, J. Bao, Chem. Commun. 55(2019) 11131-11134. doi: 10.1039/C9CC05686F
22. [22]
  X. Qin, L. Zhang, G.L. Xu, et al., ACS Catal. 9(2019) 9614-9621. doi: 10.1021/acscatal.9b01744
23. [23]
  D. Bernsmeier, M. Bernicke, E. Ortel, et al., J. Catal. 355(2017) 110-119. doi: 10.1016/j.jcat.2017.08.005
24. [24]
  L. Wang, J. Chen, A. Patel, V. Rudolph, Z. Zhu, Appl. Catal. A: Gen. 447-448(2012) 200-209. doi: 10.1016/j.apcata.2012.09.044
25. [25]
  Y. Ma, B. Liu, M. Jing, et al., Chem. Eng. J. 287(2016) 155-161. doi: 10.1016/j.cej.2015.10.119
26. [26]
  R.S. Suppino, R. Landers, A.J.G. Cobo, Appl. Catal. A: Gen. 525(2016) 41-49. doi: 10.1016/j.apcata.2016.06.038
27. [27]
  D. Gao, S. Li, X. Wang, et al., J. Catal. 370(2019) 385-403. doi: 10.1016/j.jcat.2019.01.011
28. [28]
  P.V. Duc-Ha, C.S. Tan, RSC Adv. 7(2017) 18178-18188. doi: 10.1039/C7RA02227A
1. [1]
  Bin Chen , Chaoyang Zheng , Dehuan Shi , Yi Huang , Renxia Deng , Yang Wei , Zheyuan Liu , Yan Yu , Shenghong Zhong . p-d orbital hybridization induced by CuGa2 promotes selective N2 electroreduction. Chinese Journal of Structural Chemistry, 2025, 44(1): 100468-100468. doi: 10.1016/j.cjsc.2024.100468
2. [2]
  Lingyun Shen , Shenxiang Yin , Qingshu Zheng , Zheming Sun , Wei Wang , Tao Tu . A rechargeable and portable hydrogen storage system grounded on soda water. Chinese Chemical Letters, 2025, 36(3): 110580-. doi: 10.1016/j.cclet.2024.110580
3. [3]
  Ming Huang , Xiuju Cai , Yan Liu , Zhuofeng Ke . Base-controlled NHC-Ru-catalyzed transfer hydrogenation and α-methylation/transfer hydrogenation of ketones using methanol. Chinese Chemical Letters, 2024, 35(7): 109323-. doi: 10.1016/j.cclet.2023.109323
4. [4]
  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
5. [5]
  Baokang Geng , Xiang Chu , Li Liu , Lingling Zhang , Shuaishuai Zhang , Xiao Wang , Shuyan Song , Hongjie Zhang . High-efficiency PdNi single-atom alloy catalyst toward cross-coupling reaction. Chinese Chemical Letters, 2024, 35(7): 108924-. doi: 10.1016/j.cclet.2023.108924
6. [6]
  Yanling Yang , Zhenfa Ding , Huimin Wang , Jianhui Li , Yanping Zheng , Hongquan Guo , Li Zhang , Bing Yang , Qingqing Gu , Haifeng Xiong , Yifei Sun . Dynamic tracking of exsolved PdPt alloy/perovskite catalyst for efficient lean methane oxidation. Chinese Chemical Letters, 2024, 35(4): 108585-. doi: 10.1016/j.cclet.2023.108585
7. [7]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
8. [8]
  Haibin Yang , Duowen Ma , Yang Li , Qinghe Zhao , Feng Pan , Shisheng Zheng , Zirui Lou . Mo doped Ru-based cluster to promote alkaline hydrogen evolution with ultra-low Ru loading. Chinese Journal of Structural Chemistry, 2023, 42(11): 100031-100031. doi: 10.1016/j.cjsc.2023.100031
9. [9]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
10. [10]
  Minghui Zhang , Na Zhang , Qian Zhao , Chao Wang , Alexander Steiner , Jianliang Xiao , Weijun Tang . Cobalt pincer complex-catalyzed highly enantioselective hydrogenation of quinoxalines. Chinese Chemical Letters, 2025, 36(4): 110081-. doi: 10.1016/j.cclet.2024.110081
11. [11]
  Minying Wu , Xueliang Fan , Wenbiao Zhang , Bin Chen , Tong Ye , Qian Zhang , Yuanyuan Fang , Yajun Wang , Yi Tang . Highly dispersed Ru nanospecies on N-doped carbon/MXene composite for highly efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109258-. doi: 10.1016/j.cclet.2023.109258
12. [12]
  Tianyi Yang , Fangxi Su , Dehuan Shi , Shenghong Zhong , Yalin Guo , Zhaohui Liu , Jianfeng Huang . Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix. Chinese Chemical Letters, 2025, 36(2): 110444-. doi: 10.1016/j.cclet.2024.110444
13. [13]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
14. [14]
  Zuyou Song , Yong Jiang , Qiao Gou , Yini Mao , Yimin Jiang , Wei Shen , Ming Li , Rongxing He . Promoting the generation of active sites through "Co-O-Ru" electron transport bridges for efficient water splitting. Chinese Chemical Letters, 2025, 36(4): 109793-. doi: 10.1016/j.cclet.2024.109793
15. [15]
  Xinyu Hou , Xuelian Yu , Meng Liu , Hengxing Peng , Lijuan Wu , Libing Liao , Guocheng Lv . Ultrafast synthesis of Mo₂N with highly dispersed Ru for efficient alkaline hydrogen evolution. Chinese Chemical Letters, 2025, 36(4): 109845-. doi: 10.1016/j.cclet.2024.109845
16. [16]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
17. [17]
  Shaoming Dong , Yiming Niu , Yinghui Pu , Yongzhao Wang , Bingsen Zhang . Subsurface carbon modification of Ni-Ga for improved selectivity in acetylene hydrogenation reaction. Chinese Chemical Letters, 2024, 35(12): 109525-. doi: 10.1016/j.cclet.2024.109525
18. [18]
  Jinyuan Cui , Tingting Yang , Teng Xu , Jin Lin , Kunlong Liu , Pengxin Liu . Hydrogen spillover enhances the selective hydrogenation of α,β-unsaturated aldehydes on the Cu-O-Ce interface. Chinese Journal of Structural Chemistry, 2025, 44(1): 100438-100438. doi: 10.1016/j.cjsc.2024.100438
19. [19]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
20. [20]
  Yi Luo , Lin Dong . Multicomponent remote C(sp²)-H bond addition by Ru catalysis: An efficient access to the alkylarylation of 2H-imidazoles. Chinese Chemical Letters, 2024, 35(10): 109648-. doi: 10.1016/j.cclet.2024.109648

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(946)
HTML views(192)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142