Citation: Zhang Li, Sun Yanan, Jiang Yanping, Li Yining, Song Gang, Huang Kunlun, Yao Zhiyi. Visual sensing of picric acid in 100% aqueous media based on supramolecular polythiophene assemblies with colorimetric and fluorescent dual response[J]. Chinese Chemical Letters, ;2020, 31(9): 2428-2432. doi: 10.1016/j.cclet.2020.04.003 shu

Visual sensing of picric acid in 100% aqueous media based on supramolecular polythiophene assemblies with colorimetric and fluorescent dual response

Zhang Li ^a,1 ,
Sun Yanan ^a,1 ,
Jiang Yanping ^a ,
Li Yining ^a ,
Song Gang ^b ,
Huang Kunlun ^a ,
Yao Zhiyi ^a,*,

a.
College of Food Science and Nutritional Engineering, China Agricultural University and Key Laboratory of Safety Assessment of Genetically Modified Organism(Food Safety), Ministry of Agriculture, Beijing 100083, China
b.
Guangdong Provincial Key Laboratory of Radionuclides Pollution Control and Resources, Guangzhou University, Guangzhou 510006, China

yaozy@cau.edu.cn

Received Date: 1 February 2020
Revised Date: 1 April 2020
Accepted Date: 2 April 2020
Available Online: 13 April 2020

Figures(5)

A colorimetric and fluorometric dual probe based on a water-soluble polythiophene derivative (PMTPBA) was designed and synthesized. It can be applied to determination of picric acid (PA) in 100% aqueous solution. The approach relies on the formation of supramolecular polythiophene assemblies in the presence of PA through electrostatic, charge transfer and π-π stacking interactions. This probe could be utilized for the rapid and visual detection of PA both in aqueous solution and solid support with high specificity and sensitivity. The detection limit of this sensor is as low as 5.0×10^-8 mol/L.
- Colorimetric,
- Fluorescent,
- Picric acid,
- Polythiophene,
- Supramolecular complex
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