Citation: Ming Liu, Yang Zhou, Lixia Chen, Bing Bian, Xin Xiao, Zhu Tao. Cucurbit[n]uril-calix[n]arene-based supramolecular frameworks assembled using the outer surface interactions of cucurbit[n]urils[J]. Chinese Chemical Letters, ;2021, 32(1): 375-379. doi: 10.1016/j.cclet.2020.03.042 shu

Cucurbit[n]uril-calix[n]arene-based supramolecular frameworks assembled using the outer surface interactions of cucurbit[n]urils

Ming Liu ^a ,
Yang Zhou ^b ,
Lixia Chen ^a ,
Bing Bian ^c ,
Xin Xiao ^{a, *,} ,
Zhu Tao ^{a, *,}

a.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
b.
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Ji'nan 250014, China
c.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China

gyhxxiaoxin@163.com

gzutao@263.net

Received Date: 23 December 2019
Revised Date: 27 February 2020
Accepted Date: 15 March 2020
Available Online: 18 March 2020

Figures(8)

Based on the crystal structures of two cucurbit[6]uril/calix[n]arene-based supramolecular frameworks reported by Long and co-workers, we further investigated the interactions of cucurbit[6]uril with 4-sulfocalix[4]arene and 4-sulfocalix[6]arene using ¹H NMR spectroscopy and isothermal titration calorimetry (ITC), respectively. Moreover, solid fluorescent materials were prepared via the adsorption of fluorescent dyes by these porous supramolecular frameworks, which exhibit a selective response to certain volatile organic compounds.
- Cucurbit[n]urils,
- Calix[n]arene,
- Outer surface interaction of Q[n]s,
- Supramolecular frameworks,
- Functional properties
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沈阳化工大学材料科学与工程学院沈阳 110142