Citation: Su Lijun, Liu Lingyang, Wang Yue, Lu Yulan, Yan Xingbin. Synergetic ternary metal oxide nanodots-graphene cathode for high performance zinc energy storage[J]. Chinese Chemical Letters, ;2020, 31(9): 2358-2364. doi: 10.1016/j.cclet.2020.03.014 shu

Synergetic ternary metal oxide nanodots-graphene cathode for high performance zinc energy storage

Su Lijun ^a,b,d ,
Liu Lingyang ^a,b,d ,
Wang Yue ^c,d ,
Lu Yulan ^c,d ,
Yan Xingbin ^a,b,c,d,*,

a.
Laboratory of Clean Energy Chemistry and Materials, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
c.
School of Physical Science and Technology, Lanzhou University, Lanzhou 730000, China
d.
Dalian National Laboratory for Clean Energy, Chinese Academy of Sciences, Dalian 116023, China

xbyan@licp.cas.cn

Received Date: 14 February 2020
Revised Date: 25 February 2020
Accepted Date: 25 February 2020
Available Online: 6 March 2020

Figures(5)

Zinc-based electrochemistry energy storage with high safety and high theoretical capacity is considered to be a competitive candidate to replace lithium-ion batteries. In electrochemical energy storage, multimetal oxide cathode materials can generally provide a wider electrochemical stability window and a higher capacity compared with single metal oxides cathode. Here, a new type of cathode material, MnFe₂Co₃O₈ nanodots/functional graphene sheets, is designed and used for aqueous hybrid Zn-based energy storage. Coupling with a hybrid electrolyte based on zinc sulfate and potassium hydroxide, the asfabricated battery was able to work with a wide electrochemical window of 0.1~1.8 V, showed a high specific capacity of 660 mAh/g, delivered an ultrahigh energy density of 1135 Wh/kg and a scalable power density of 5754 W/kg (calculated based on the cathode), and displayed a long cycling life of 1000 cycles. These are mainly attributed to the valence charge density distribution in MnFe₂Co₃O₈ nanodots, the good structural strengthening as well as high conductivity of the cathode, and the right electrolyte. Such cathode material also exhibited high electrocatalytic activity for oxygen evolution reaction and thus could be used for constructing a Zn-air battery with an ultrahigh reversible capacity of 9556 mAh/g.
- Hybrid zinc battery,
- Cathode,
- Ternary metal oxide,
- Energy storage,
- Electrochemical performance
1. [1]
  [1] D. Larcher, J.M. Tarascon, Nat. Chem. 7 (2015) 19-29. doi: 10.1038/nchem.2085
2. [2]
  J.M. Tarascon, M. Armand, World Scientific (2011) 171-179.
3. [3]
  H. Pan, Y. Shao, P. Yan, et al., Nat. Energy 1 (2016) 16039. doi: 10.1038/nenergy.2016.39
4. [4]
  M. Song, H. Tan, D. Chao, et al., Adv. Funct. Mater. 28 (2018) 1802564. doi: 10.1002/adfm.201802564
5. [5]
  G. Fang, J. Zhou, A. Pan, et al., ACS Energy Lett. 3 (2018) 2480-2501. doi: 10.1021/acsenergylett.8b01426
6. [6]
  W. Sun, F. Wang, S. Hou, et al., J. Am. Chem. Soc. 139 (2017) 9775-9778. doi: 10.1021/jacs.7b04471
7. [7]
  F. Wan, Y. Zhang, L. Zhang, et al., Angew. Chem. Int. Ed. 58 (2019) 7062-7067. doi: 10.1002/anie.201902679
8. [8]
  G.Z. Fang, C.Y. Zhu, M.H. Chen, et al., Adv. Funct. Mater. 29 (2019) 1808375. doi: 10.1002/adfm.201808375
9. [9]
  G.Z. Fang, S.Q. Liang, Z.X. Chen, et al., Adv. Funct. Mater. 29 (2019) 1905267. doi: 10.1002/adfm.201905267
10. [10]
  L.T. Ma, S.M. Chen, H.F. Li, et al., Energy Environ. Sci. 11 (2018) 2521-2530. doi: 10.1039/C8EE01415A
11. [11]
  J.A. Dean, Lange's Handbook of Chemistry, McGraw-Hill, Inc., New York, 1999.
12. [12]
  Y. Marcus, Chem. Rev. 88 (1988) 1475-1498. doi: 10.1021/cr00090a003
13. [13]
  B. Tansel, Sep. Purif. Technol. 86 (2012) 119-126. doi: 10.1016/j.seppur.2011.10.033
14. [14]
  C. Xu, B. Li, H. Du, et al., Angew. Chem. Int. Ed. 51 (2012) 933-935. doi: 10.1002/anie.201106307
15. [15]
  Y. Li, H. Dai, Chem. Soc. Rev. 43 (2014) 5257-5275. doi: 10.1039/C4CS00015C
16. [16]
  P. Gu, M. Zheng, Q. Zhao, et al., J. Mater. Chem. A 5 (2017) 7651-7666. doi: 10.1039/C7TA01693J
17. [17]
  J.F. Parker, C.N. Chervin, I.R. Pala, et al., Science 356 (2017) 415-418. doi: 10.1126/science.aak9991
18. [18]
  S.D. Han, N.N. Rajput, X. Qu, et al., ACS Appl. Mater. Inter. 8 (2016) 3021-3031. doi: 10.1021/acsami.5b10024
19. [19]
  C. Pan, R. Zhang, R.G. Nuzzo, et al., Adv. Energy Mater. 8 (2018) 1800589. doi: 10.1002/aenm.201800589
20. [20]
  Z. Zhao, J. Zhao, Z. Hu, et al., Energy Environ. Sci. 12 (2019) 1938-1949. doi: 10.1039/C9EE00596J
21. [21]
  F. Wang, E. Hu, W. Sun, et al., Energy Environ. Sci. 11 (2018) 3168-3175. doi: 10.1039/C8EE01883A
22. [22]
  Y. Huang, Z. Li, Z. Pei, et al., Adv. Energy Mater. 8 (2018) 1802288. doi: 10.1002/aenm.201802288
23. [23]
  V. Yufit, F. Tariq, D.S. Eastwood, et al., Joule 3 (2018) 485-502.
24. [24]
  D. Chao, C. Zhu, M. Song, et al., Adv. Mater. 30 (2018) 1803181. doi: 10.1002/adma.201803181
25. [25]
  H.Y. Shi, Y.J. Ye, K. Liu, et al., Angew. Chem. Int. Ed. 130 (2018) 16597-16601. doi: 10.1002/ange.201808886
26. [26]
  Y. Yang, Y. Tang, G. Fang, et al., Energy Environ. Sci. 11 (2018) 3157-3162. doi: 10.1039/C8EE01651H
27. [27]
  J. Huang, Z. Wang, M. Hou, et al., Nat. Commun. 9 (2018) 1-8. doi: 10.1038/s41467-017-02088-w
28. [28]
  L. Wang, Y. Lu, J. Liu, et al., Angew. Chem. Int. Ed. 52 (2013) 1964-1967. doi: 10.1002/anie.201206854
29. [29]
  C.D. Wessells, R.A. Huggins, Y. Cui, Nat. Commun. 2 (2011) 550. doi: 10.1038/ncomms1563
30. [30]
  X. Wu, M. Sun, S. Guo, et al., ChemNanoMat 1 (2015) 188-193. doi: 10.1002/cnma.201500021
31. [31]
  C. Julien, A. Mauger, K. Zaghib, et al., Materials 9 (2016) 595. doi: 10.3390/ma9070595
32. [32]
  H. Guan, X. Wang, H. Li, et al., Chem. Commun. 48 (2012) 4878-4880. doi: 10.1039/c2cc30843f
33. [33]
  A. Jena, C.H. Lee, W.K. Pang, et al., Electrochim. Acta 236 (2017) 10-17. doi: 10.1016/j.electacta.2017.03.163
34. [34]
  M. Thackeray, A. De Kock, M. Rossouw, et al., J. Electrochem. Soc. 139 (1992) 363-366. doi: 10.1149/1.2069222
35. [35]
  N. Du, H. Zhang, B. Chen, et al., Adv. Mater. 19 (2007) 4505-4509. doi: 10.1002/adma.200602513
36. [36]
  C.A. Fisher, V.M. Hart Prieto, M.S. Islam, Chem. Mater. 20 (2008) 5907-5915. doi: 10.1021/cm801262x
37. [37]
  J. Liu, M. Chen, L. Zhang, et al., Nano Lett. 14 (2014) 7180-7187. doi: 10.1021/nl503852m
38. [38]
  H. Wang, Y. Liang, M. Gong, et al., Nat. Commun. 3 (2012) 917. doi: 10.1038/ncomms1921
39. [39]
  X. Yan, J. Chen, J. Yang, et al., ACS Appl. Mater. Inter. 2 (2010) 2521-2529. doi: 10.1021/am100293r
40. [40]
  W.S. Hummers Jr., R.E. Offeman, J. Am. Chem. Soc. 80 (1958) 1339. doi: 10.1021/ja01539a017
41. [41]
  L. Ma, S. Chen, Z. Pei, et al., ACS Nano 12 (2018) 8597-8605. doi: 10.1021/acsnano.8b04317
42. [42]
  G. Kresse, J. Furthmüller, Comp. Mater. Sci. 6 (1996) 15-50. doi: 10.1016/0927-0256(96)00008-0
43. [43]
  G. Kresse, J. Furthmüller, Phys. Rev. B 54 (1996) 11169. doi: 10.1103/PhysRevB.54.11169
44. [44]
  G. Kresse, D. Joubert, Phys. Rev. B 59 (1999) 1758.
45. [45]
  J.P. Perdew, K. Burke, M. Ernzerhof, Phys. Rev. Lett. 80 (1998) 891. doi: 10.1103/PhysRevLett.80.891
46. [46]
  L. Su, S. Lei, L. Liu, et al., J. Mater. Chem. A 6 (2018) 9997-10007. doi: 10.1039/C8TA02982B
47. [47]
  L. Liu, J. Lang, P. Zhang, et al., ACS Appl. Mater. Inter. 8 (2016) 9335-9344. doi: 10.1021/acsami.6b00225
48. [48]
  L. Liu, L. Su, J. Lang, et al., J. Mater. Chem. A 5 (2017) 5523-5531.
49. [49]
  X. Min, W. Zhang, D. Xu, Chem. Bio. Engin. 22 (2005) 38.
50. [50]
  H. Wang, C. Zhang, Z. Liu, et al., J. Mater. Chem. 21 (2011) 5430-5434. doi: 10.1039/c1jm00049g
51. [51]
  Z. Jin, J. Yao, C. Kittrell, et al., ACS Nano 5 (2011) 4112-4117. doi: 10.1021/nn200766e
52. [52]
  D. Deng, X. Pan, L. Yu, et al., Chem. Mater. 23 (2011) 1188-1193. doi: 10.1021/cm102666r
53. [53]
  S. Yang, X. Song, P. Zhang, et al., ACS Appl. Mater. Inter. 5 (2013) 3317-3322. doi: 10.1021/am400385g
54. [54]
  H.M. Jeong, J.W. Lee, W.H. Shin, et al., Nano Lett. 11 (2011) 2472-2477. doi: 10.1021/nl2009058
55. [55]
  Y. Liu, N. Zhang, L. Jiao, et al., Adv. Mater. 27 (2015) 6702-6707. doi: 10.1002/adma.201503015
56. [56]
  P. Zhao, W. Li, G. Wang, et al., J. Alloy. Compd. 604 (2014) 87-93. doi: 10.1016/j.jallcom.2014.03.106
57. [57]
  X. Zhu, Y. Zhu, S. Murali, et al., ACS Nano 5 (2011) 3333-3338. doi: 10.1021/nn200493r
58. [58]
  S.K. Bikkarolla, F. Yu, W. Zhou, et al., J. Mater. Chem. A 2 (2014) 14493-14501. doi: 10.1039/C4TA02279C
59. [59]
  B. Liu, X. Hu, H. Xu, et al., Sci. Rep. 4 (2014) 4229.
60. [60]
  P. He, Y. Quan, X. Xu, et al., Small 13 (2017) 1702551. doi: 10.1002/smll.201702551
61. [61]
  F. Wan, L. Zhang, X. Dai, et al., Nat. Commun. 9 (2018) 1656. doi: 10.1038/s41467-018-04060-8
62. [62]
  D. Kundu, B.D. Adams, V. Duffort, et al., Nat. Energy 1 (2016) 16119. doi: 10.1038/nenergy.2016.119
63. [63]
  P. Hu, T. Zhu, X. Wang, et al., Nano Lett. 18 (2018) 1758-1763. doi: 10.1021/acs.nanolett.7b04889
64. [64]
  P. He, G. Zhang, X. Liao, et al., Adv. Energy Mater. 8 (2018) 1702463. doi: 10.1002/aenm.201702463
65. [65]
  A. Yamada, S.C. Chung, K. Hinokuma, J. Electrochem. Soc. 148 (2001) A224-A229. doi: 10.1149/1.1348257
66. [66]
  D.E. Ellis, D. Guenzburger, Adv. Quantum Chem. 34 (1999) 51-141. doi: 10.1016/S0065-3276(08)60531-6
67. [67]
  J. Gomez, D. Guenzburger, Phys. Rev. B 63 (2001) 134404.
68. [68]
  Y. Lu, L. Su, J. Qi, et al., J. Mater. Chem. A 6 (2018) 13717-13724. doi: 10.1039/C8TA03451F
1. [1]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
2. [2]
  Jian Wang , Baohui Wang , Pin Ma , Yifei Zhang , Honghong Gong , Biyun Peng , Sen Liang , Yunchuan Xie , Hailong Wang . Regulation of uniformity and electric field distribution achieved highly energy storage performance in PVDF-based nanocomposites via continuous gradient structure. Chinese Chemical Letters, 2025, 36(4): 109714-. doi: 10.1016/j.cclet.2024.109714
3. [3]
  Zhuangzhuang Zhang , Yaru Qiao , Jun Zhao , Dai-Huo Liu , Mengmin Jia , Hongwei Tang , Liang Wang , Dongmei Dai , Bao Li . Fluorine-doped K_0.39Mn_0.77Ni_0.23O_1.9F_0.1 microspheres with highly reversible oxygen redox reaction for potassium-ion battery cathode. Chinese Chemical Letters, 2025, 36(3): 109907-. doi: 10.1016/j.cclet.2024.109907
4. [4]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
5. [5]
  Ningning Zhao , Yuyan Liang , Wenjie Huo , Xinyan Zhu , Zhangxing He , Zekun Zhang , Youtuo Zhang , Xianwen Wu , Lei Dai , Jing Zhu , Ling Wang , Qiaobao Zhang . Separator functionalization enables high-performance zinc anode via ion-migration regulation and interfacial engineering. Chinese Chemical Letters, 2024, 35(9): 109332-. doi: 10.1016/j.cclet.2023.109332
6. [6]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
7. [7]
  Yunyu Zhao , Chuntao Yang , Yingjian Yu . A review on covalent organic frameworks for rechargeable zinc-ion batteries. Chinese Chemical Letters, 2024, 35(7): 108865-. doi: 10.1016/j.cclet.2023.108865
8. [8]
  Guihuang Fang , Wei Chen , Hongwei Yang , Haisheng Fang , Chuang Yu , Maoxiang Wu . Improved performance of LiMn_0.8Fe_0.2PO₄ by addition of fluoroethylene carbonate electrolyte additive. Chinese Chemical Letters, 2024, 35(6): 108799-. doi: 10.1016/j.cclet.2023.108799
9. [9]
  Shilong Li , Ming Zhao , Yefei Xu , Zhanyi Liu , Mian Li , Qing Huang , Xiang Wu . Performance optimization of aqueous Zn/MnO₂ batteries through the synergistic effect of PVP intercalation and GO coating. Chinese Chemical Letters, 2025, 36(3): 110701-. doi: 10.1016/j.cclet.2024.110701
10. [10]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
11. [11]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
12. [12]
  Liang Ming , Dan Liu , Qiyue Luo , Chaochao Wei , Chen Liu , Ziling Jiang , Zhongkai Wu , Lin Li , Long Zhang , Shijie Cheng , Chuang Yu . Si-doped Li₆PS₅I with enhanced conductivity enables superior performance for all-solid-state lithium batteries. Chinese Chemical Letters, 2024, 35(10): 109387-. doi: 10.1016/j.cclet.2023.109387
13. [13]
  Xiaoxing Ji , Xiaojuan Li , Chenggang Wang , Gang Zhao , Hongxia Bu , Xijin Xu . Ni_xB/rGO as the cathode for high-performance aqueous alkaline zinc-based battery. Chinese Chemical Letters, 2024, 35(10): 109388-. doi: 10.1016/j.cclet.2023.109388
14. [14]
  Zeyu XU , Tongzhou LU , Haibo SHAO , Jianming WANG . Preparation and electrochemical lithium storage performance of porous silicon microsphere composite with metal modification and carbon coating. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1995-2008. doi: 10.11862/CJIC.20240164
15. [15]
  Hangwen Zheng , Ziqian Wang , HuiJie Zhang , Jing Lei , Rihui Li , Jian Yang , Haiyan Wang . Synthesis and applications of B, N co-doped carbons for zinc-based energy storage devices. Chinese Chemical Letters, 2025, 36(3): 110245-. doi: 10.1016/j.cclet.2024.110245
16. [16]
  Bing Jiang , Gang Zou , Bi Luo , Yan Guo , Jingru Li , Wendi Zhang , Qianxiao Fan , Lehao Liu , Lihua Chu , Qiaobao Zhang , Meicheng Li . Enhanced electrochemical performance of lithium-rich layered oxide materials: Exploring advanced coating strategies. Chinese Chemical Letters, 2025, 36(4): 109801-. doi: 10.1016/j.cclet.2024.109801
17. [17]
  Ziling Jiang , Shaoqing Chen , Chaochao Wei , Ziqi Zhang , Zhongkai Wu , Qiyue Luo , Liang Ming , Long Zhang , Chuang Yu . Enabling superior electrochemical performance of NCA cathode in Li_5.5PS_4.5Cl_1.5-based solid-state batteries with a dual-electrolyte layer. Chinese Chemical Letters, 2024, 35(4): 108561-. doi: 10.1016/j.cclet.2023.108561
18. [18]
  Hengyi ZHU , Liyun JU , Haoyue ZHANG , Jiaxin DU , Yutong XIE , Li SONG , Yachao JIN , Mingdao ZHANG . Efficient regeneration of waste LiNi_0.5Co_0.2Mn_0.3O₂ cathode toward high-performance Li-ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 625-638. doi: 10.11862/CJIC.20240358
19. [19]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
20. [20]
  Kun Xu , Xinxin Song , Zhilei Yin , Jian Yang , Qisheng Song . Comprehensive Experimental Design of Preferential Orientation of Zinc Metal by Heat Treatment for Enhanced Electrochemical Performance. University Chemistry, 2024, 39(4): 192-197. doi: 10.3866/PKU.DXHX202309050

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(986)
HTML views(42)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142