Citation: Zhou Shuyu, Jin Xiaozhe, Zhu Shengming, Luo Qian, Qiu Zhiwen, Wu Aimin, Huang Hao. S-O bond chemically constrained NiS₂/rGO nanocomposite with enhanced Na-ion storage capacity[J]. Chinese Chemical Letters, ;2020, 31(9): 2353-2357. doi: 10.1016/j.cclet.2020.02.042 shu

S-O bond chemically constrained NiS₂/rGO nanocomposite with enhanced Na-ion storage capacity

Key Laboratory of Energy Materials and Devices(Liaoning Province), School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China

huanghao@dlut.edu.cn

Received Date: 18 January 2020
Revised Date: 16 February 2020
Accepted Date: 20 February 2020
Available Online: 24 February 2020

Figures(4)

NiS₂ has become a research hotspot of anode materials for Na-ion batteries due to its high theoretical specific capacity. However, the volume effect, the dissolution of polysulfide intermediates and the low conductivity during the charge/discharge process lead to the low specific capacity and poor cycling stability. NiS₂/rGO nanocomposite was prepared by a facile two-step process: GO was prepared by modified Hummers method, and then NiS₂/rGO nanocomposite was synthesized by L-cys assisted hydrothermal method. NiS₂/rGO nanocomposite shows excellent cycle performance and rate performance, which could be attributed to the mesoporous structure on the graphene skeleton with high conductivity. Besides, the chemical constraint of a unique S-O bond on NiS₂ could inhibit the dissolution of intermediates and the loss of irreversible capacity.
- Na-ion batteries,
- NiS₂/rGO nanocomposite,
- Hydrothermal reaction,
- Anode,
- Chemical constraint
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S-O bond chemically constrained NiS2/rGO nanocomposite with enhanced Na-ion storage capacity

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通讯作者: 陈斌, bchen63@163.com

S-O bond chemically constrained NiS₂/rGO nanocomposite with enhanced Na-ion storage capacity