Citation: Xuemei Fu, Xinzhang Lin, Xiuqing Ren, Hengjiang Cong, Chao Liu, Jiahui Huang. Synthesis and structure of Au₁₉Ag₄(S-Adm)₁₅ nanocluster: Polymorphs and optical properties[J]. Chinese Chemical Letters, ;2021, 32(1): 565-568. doi: 10.1016/j.cclet.2020.02.041 shu

Synthesis and structure of Au₁₉Ag₄(S-Adm)₁₅ nanocluster: Polymorphs and optical properties

Xuemei Fu ^{a, b} ,
Xinzhang Lin ^{a, b} ,
Xiuqing Ren ^a ,
Hengjiang Cong ^c ,
Chao Liu ^{a, *,} ,
Jiahui Huang ^{a, *,}

a.
Gold Catalysis Research Center, State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
College of Chemistry and Molecular Sciences, Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, Wuhan University, Wuhan 430072, China

chaoliu@dicp.ac.cn

jiahuihuang@dicp.ac.cn

Received Date: 23 December 2019
Revised Date: 14 February 2020
Accepted Date: 20 February 2020
Available Online: 21 February 2020

Figures(4)

Polymorphism is a common phenomenon in nature. Here, we report one-pot wet chemical method to synthesize two polymorphs of Au₁₉Ag₄(S-Adm)₁₅ nanocluster protected by 1-adamantanethiol (HS-Adm), which adopt P-1 and P2₁/c space group respectively. The crystal structures of two polymorphs were determined by X-ray crystallography. Compared to the previously reported Au₁₉Ag₄(S-Adm)₁₅ nanocluster adopting P2₁/n space group, polymorphs of Au₁₉Ag₄(S-Adm)₁₅ with P-1 and P2₁/c space group show the different optical properties. Moreover, Au₁₉Ag₄(S-Adm)₁₅ with P-1 space group exhibits good thermal stability. Meanwhile, we investigated the effect of solvent and molar ratio of metal precursors on the polymorphs. This work provides an insight to polymorphs of metal nanoclusters.
- Au₁₉Ag₄(S-Adm)₁₅,
- Alloy nanocluster,
- Polymorph,
- Fluorescence,
- Thermal stability
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Synthesis and structure of Au₁₉Ag₄(S-Adm)₁₅ nanocluster: Polymorphs and optical properties