Citation: Tianwei Cui, Guoxing Liu, Wenjing Zhang, Xinju Zhu, Juhua Leng, Xin-Qi Hao, Pu Mao, Mao-Ping Song. Metal-organic supramolecular nanoarchitectures by Ru(Ⅱ) bis-(terpyridine)-bridged pillar[5]arene dimers with triphenylamine[J]. Chinese Chemical Letters, ;2021, 32(1): 357-361. doi: 10.1016/j.cclet.2020.02.024 shu

Metal-organic supramolecular nanoarchitectures by Ru(Ⅱ) bis-(terpyridine)-bridged pillar[5]arene dimers with triphenylamine

Tianwei Cui ^a ,
Guoxing Liu ^{a, b, *,} ,
Wenjing Zhang ^a ,
Xinju Zhu ^a ,
Juhua Leng ^a ,
Xin-Qi Hao ^{a, *,} ,
Pu Mao ^b ,
Mao-Ping Song ^a

a.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China
b.
College of Chemistry and Chemical Engineering, Henan University of Technology, Zhengzhou 450001, China

gxliu@haut.edu.cn

xqhao@zzu.edu.cn

Received Date: 4 January 2020
Revised Date: 2 February 2020
Accepted Date: 13 February 2020
Available Online: 14 February 2020

Figures(7)

A metal-organic photoinduced electron transfer (PET) supramolecular nanoarchitecture comprised of Ru(Ⅱ) bis(terpyridine)-modified pillar[5]arene (electron acceptor) and triazole triphenylamine amyl cyanide (electron donor) has been designed and constructed. Through the comparison of diverse solvents and acceptors, the two conditions, i.e., modification of pillar[5]arene to donor and weak polar solvent are benefit for the occurrence of "efficient PET" because of shorter D-A distance in the presence of pillar[5]arene. Crucially, the fluorescence and PET process of the supramolecular assembly could be further modulated by solvent conversion and another competitive guest. The study provides a supramolecular method to design and construct tunable PET systems and PET-based smart materials.
- Supramolecular chemistry,
- Pillar[5]arene,
- Self-assemble,
- Tunable PET,
- Host-guest complexation
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