Citation: He Wei-Bao, Gao Lan-Qing, Chen Xin-Jie, Wu Zhi-Lin, Huang Ying, Cao Zhong, Xu Xin-Hua, He Wei-Min. Visible-light-initiated malic acid-promoted cascade coupling/ cyclization of aromatic amines and KSCN to 2-aminobenzothiazoles without photocatalyst[J]. Chinese Chemical Letters, ;2020, 31(7): 1895-1898. doi: 10.1016/j.cclet.2020.02.011 shu

Visible-light-initiated malic acid-promoted cascade coupling/ cyclization of aromatic amines and KSCN to 2-aminobenzothiazoles without photocatalyst

He Wei-Bao ^a ,
Gao Lan-Qing ^a ,
Chen Xin-Jie ^c ,
Wu Zhi-Lin ^d ,
Huang Ying ^b ,
Cao Zhong ^b ,
Xu Xin-Hua ^a,*, ,
He Wei-Min ^b,*,

a.
Department of Chemistry, Hunan University, Changsha 410082, China
b.
Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation, Changsha University of Science and Technology, Changsha 410114, China
c.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
d.
School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China

xinhuaxu2019@yeah.net

weiminhe2016@yeah.net

Received Date: 24 December 2019
Revised Date: 21 January 2020
Accepted Date: 7 February 2020
Available Online: 8 February 2020

Figures(6)

By using ambient air as the oxidant and malic acid as the promoter, a practical method for the preparation of 2-aminobenzothiazoles through visible-light-initiated cascade reaction of aromatic amines and KSCN in eco-friendly bis(methoxypropy)ether under metal-, hazardous additive-, photocatalyst-free conditions was established.
- Air,
- Photocatalysis,
- Cascade reaction,
- Photocatalyst-free,
- 2-Aminobenzothiazoles
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