Citation: Huo Gui-Fei, Tu Qian, Zhao Xiao-Li, Shi Xueliang, Yang Hai-Bo. Synthesis and characterization of an unexpected mechanochromicbistricyclic aromatic ene[J]. Chinese Chemical Letters, ;2020, 31(7): 1847-1850. doi: 10.1016/j.cclet.2020.02.010 shu

Synthesis and characterization of an unexpected mechanochromicbistricyclic aromatic ene

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China

xlshi@chem.ecnu.edu.cn

hbyang@chem.ecnu.edu.cn

Received Date: 6 December 2019
Revised Date: 30 January 2020
Accepted Date: 7 February 2020
Available Online: 8 February 2020

Figures(5)

An unexpected bistricyclic aromatic ene AF was synthesized in a tin(Ⅱ) chloride-mediated reductive aromatization reaction. The obtained AF showed a highly overcrowded structural conformation as revealed by X-ray crystallography. Interestingly, AF exhibited reversible high-contrast mechanochromism and thermochromism between pale and red color. The obvious chromism is likely ascribed to the conformation transformation and trace amount of diradical species formation upon stimulus.
- Bistricyclic aromatic ene,
- Mechanochromism,
- Thermochromism,
- 1, 2-Migration reaction,
- Triplet diradical
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