Citation: Luyao Zhao, Chunbo Duan, Dongxue Ding, Shihui Liu, Debin Xia, Ying Guo, Hui Xu, Martin Baumgarten. Super rigid tris-spirobifluorenes: Syntheses and properties[J]. Chinese Chemical Letters, ;2021, 32(1): 397-400. doi: 10.1016/j.cclet.2020.02.001 shu

Super rigid tris-spirobifluorenes: Syntheses and properties

Luyao Zhao ^{a, b, 1} ,
Chunbo Duan ^{c, 1} ,
Dongxue Ding ^{c, 1} ,
Shihui Liu ^b ,
Debin Xia ^{b, *,} ,
Ying Guo ^{a, *,} ,
Hui Xu ^{c, *,} ,
Martin Baumgarten ^d

a.
College of Chemical and Environmental Engineering, Harbin University of Science and Technology, Harbin 150040, China
b.
MòT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
c.
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Material Science, Heilongjiang University, Harbin 150080, China
d.
Max Planck Institute for Polymer Research, Mainz 55128, Germany

xia@hit.edu.cn

gyingxinxiang@126.com

hxu@hlju.edu.cn

Received Date: 22 December 2019
Revised Date: 13 January 2020
Accepted Date: 2 February 2020
Available Online: 5 February 2020

Figures(6)

In this work, a blue emitter with a 3D rigid structure composed of multiple spirobifluorene (3-Spiro) has been synthesized and characterized. Through a detailed study of the electrochemical and photophysical properties of 3-Spiro, we have evidenced that 3-Spiro can be applied as an active component of organic light-emitting diodes (OLEDs). The device with 5% doping rate of 4CzPNPh exhibits high external quantum efficiency (EQE) of 11%, which proves the potential of 3D rigid structure emitters for OLEDs.
- OLEDs,
- Spirobifluorene,
- Blue emitter,
- Rigid structure,
- Three dimensional
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