Citation: Muhammad Waseem, Ni Jie, Jagličić Zvonko, Cui Ping, Gao Linna, Sun Di. Synthesis, structure and magnetic properties of a decanuclear Fe(Ⅲ)/oxo cluster[J]. Chinese Chemical Letters, ;2020, 31(9): 2503-2506. doi: 10.1016/j.cclet.2020.01.031 shu

Synthesis, structure and magnetic properties of a decanuclear Fe(Ⅲ)/oxo cluster

Muhammad Waseem ^a ,
Ni Jie ^a ,
Jagličić Zvonko ^d,*, ,
Cui Ping ^a,b,c,*, ,
Gao Linna ^e ,
Sun Di ^a,f,*,

a.
School of Chemistry and Chemical Engineering, Key Lab of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Ji'nan 250100, China
b.
Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), College of Chemistry, Nankai University, Tianjin 300071, China
c.
College of Chemistry, Chemical Engineering and Materials Science, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Ji'nan 250014, China
d.
Institute of Mathematics, Physics and Mechanics & Faculty of Civil and Geodetic Engineering, University of Ljubljana, Jadranska 19, Ljubljana, Slovenia
e.
College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266590, China
f.
Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, and School of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China

^**

zvonko.jaglicic@imfm.si

cuiping@sdu.edu.cn

dsun@sdu.edu.cn

Received Date: 14 October 2019
Revised Date: 5 January 2020
Accepted Date: 13 January 2020
Available Online: 14 January 2020

Figures(4)

An iron (Ⅲ) cluster, namely [Fe₁₀(μ₃-O)₈L₈(NO₃)₆] (1), has been synthesized by treatment of Fe (NO₃)₃·9H₂O with 3, 5-dimethyl-1-(hydroxymethyl)-pyrazole (HL) under ambient temperature. The core skeleton of {Fe^Ⅲ₁₀} can be regarded as a pear-like cage with eight triangular {Fe^Ⅲ₃(μ₃-O)} units, in which each three Fe^Ⅲ centers is held together by one μ₃-O^2- group with Fe^Ⅲ centers as corner-sharing triangle units. Importantly, {Fe^Ⅲ₁₀} cluster is not only stable in solid state but also in solution, which is confirmed by powder X-ray diffraction (PXRD) pattern and electrospray ionization mass spectrometry (ESI-MS), respectively. Furthermore, 1 shows antiferromagnetic exchange behavior arising from the interactions between the iron(Ⅲ) centers.
- Fe cluster,
- X-ray structure,
- Hydroxymethyl-pyrazole ligand,
- ESI-MS,
- Magnetic property
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