Citation: Sun Jinxia, Luo Rong, Xia Yunsheng. Getting rid of NaBH₄: Gold seeds reduced by air-stable agents for synthesizing quasi one-dimensional gold nanoparticles[J]. Chinese Chemical Letters, ;2020, 31(7): 1946-1950. doi: 10.1016/j.cclet.2019.12.037 shu

Getting rid of NaBH₄: Gold seeds reduced by air-stable agents for synthesizing quasi one-dimensional gold nanoparticles

Key Laboratory of Functional Molecular Solids, Ministry of Education, College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China

xiayuns@mail.ahnu.edu.cn

Received Date: 15 November 2019
Revised Date: 26 December 2019
Accepted Date: 27 December 2019
Available Online: 28 December 2019

Figures(4)

Herein, we have presented a novel and easy to operate seed-mediated system for fabricating gold bipyramids (AuBPs) with 85% yields without any separation/purification processes. The used gold seeds are reduced by tannin and citrate, two kinds of air stable ligands, and conventionally employed unstable NaBH₄ are thoroughly cast off. In addition, the as-proposed gold seeds can also be employed for AuNRs fabrication with rather larger diameters (22.2-60.3 nm), which is difficult to be achieved by conventional seed mediated fabrication system.
- Gold seeds,
- Air stable reducing agents,
- Gold bipyramids,
- Nanorods
1. [1]
  (a) B. Hvolbæk, T.V. Janssens, B.S. Clausen, et al., Nano Today 2 (2007) 14-18;
  (b) M. Homberger, U. Simon, Philos. Trans. R. Soc. 368 (2010) 1405-1453;
  (c) R.A. Sperling, P.R. Gil, F. Zhang, et al., Chem. Soc. Rev. 37 (2008) 1896-1908;
  (d) Y. Xia, Anal. Bioanal. Chem. 408 (2016) 2813-2825;
  (e) T.T. Song, W. Wang, L.L. Meng, et al., Chin. Chem. Lett. 28 (2017) 226-230;
  (f) J. Feng, L. Chen, Y. Xia, et al., ACS Biomater. Sci. Eng. 3 (2017) 608-618;
  (g) C. Niu, Q. Song, G. He, et al., Anal. Chem. 88 (2016) 11062-11069;
  (h) D. Yuan, H. Yan, J. Liu, et al., Chin. Chem. Lett. 31 (2020) 455-458;
  (i) B. Zhang, Y. Xia, Chin. Chem. Lett. 30 (2019) 1663-1666.
2. [2]
  N.R. Jana, L. Gearheart, C.J. Murphy, Adv. Mater. 13(2001) 1389-1393. doi: 10.1002/1521-4095(200109)13:18<1389::AID-ADMA1389>3.0.CO;2-F
3. [3]
  B. Nikoobakht, M.A. El-Sayed, Chem. Mater. 15(2003) 1957-1962. doi: 10.1021/cm020732l
4. [4]
  M. Liu, P. Guyot-Sionnest, J. Phys. Chem. B 109(2005) 22192-22200. doi: 10.1021/jp054808n
5. [5]
  (a) H. Chen, L. Shao, K.C. Woo, et al., J. Phys. Chem. C 113 (2009) 17691-17697;
  (b) H. Chen, X. Kou, Z. Yang, et al., Langmuir 24 (2008) 5233-5237;
  (c) S. Lee, K.M. Mayer, J.H. Hafner, Anal. Chem. 81 (2009) 4450-4455.
6. [6]
  X. Kou, W. Ni, C.K. Tsung, et al., Small 3(2007) 2103-2113. doi: 10.1002/smll.200700379
7. [7]
  (a) M. Hanauer, S. Pierrat, I. Zins, et al., Nano Lett. 7 (2007) 2881-2885;
  (b) W. Liu, D. Liu, Z. Zhu, et al., Nanoscale 6 (2014) 4498-4502;
  (c) K. Park, H. Koerner, R.A. Vaia, Nano Lett. 10 (2010) 1433-1439.
8. [8]
  A. Sa'nchez-Iglesias, N. Winckelmans, T. Altantzis, et al., J. Am. Chem. Soc. 139(2016) 107-110.
9. [9]
  (a) W. Niu, Y. Duan, Z. Qing, et al., J. Am. Chem. Soc. 139 (2017) 5817-5826;
  (b) J.H. Lee, K.J. Gibson, G. Chen, Y. Weizmann, Nat. Commun. 6 (2015) 7571;
  (c) W. Niu, S. Zheng, D. Wang, et al., J. Am. Chem. Soc. 131 (2008) 697-703.
10. [10]
  J. Piella, N.G. Bastu's, V. Puntes, Chem. Mater. 28(2016) 1066-1075. doi: 10.1021/acs.chemmater.5b04406
11. [11]
  Q. Li, X. Zhuo, S. Li, et al., Adv. Opt. Mater. 3(2015) 801-812. doi: 10.1002/adom.201400505
12. [12]
  C. Fang, G. Zhao, Y. Xiao, et al., Sci. Rep. 6(2016) 36706. doi: 10.1038/srep36706
13. [13]
  (a) X. Kou, S. Zhang, C.K. Tsung, et al., J. Phys. Chem. B 110 (2006) 16377-16383;
  (b) D. Chateau, A. Liotta, F. Vadcard, et al., Nanoscale 7 (2015) 1934-1943.
14. [14]
  H. Jia, C. Fang, X.M. Zhu, et al., Langmuir 31(2015) 7418-7426. doi: 10.1021/acs.langmuir.5b01444
15. [15]
  X. Ye, C. Zheng, J. Chen, et al., Nano Lett. 13(2013) 765-771. doi: 10.1021/nl304478h
1. [1]
  Min Huang , Ru Cheng , Shuai Wen , Liangtong Li , Jie Gao , Xiaohui Zhao , Chunmei Li , Hongyan Zou , Jian Wang . Ultrasensitive detection of microRNA-21 in human serum based on the confinement effect enhanced chemical etching of gold nanorods. Chinese Chemical Letters, 2024, 35(9): 109379-. doi: 10.1016/j.cclet.2023.109379
2. [2]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
3. [3]
  Zhi Li , Wenpei Li , Shaoping Jiang , Chuan Hu , Yuanyu Huang , Maxim Shevtsov , Huile Gao , Shaobo Ruan . Legumain-triggered aggregable gold nanoparticles for enhanced intratumoral retention. Chinese Chemical Letters, 2024, 35(7): 109150-. doi: 10.1016/j.cclet.2023.109150
4. [4]
  Xiangqian Cao , Chenkai Yang , Xiaodong Zhu , Mengxin Zhao , Yilin Yan , Zhengnan Huang , Jinming Cai , Jingming Zhuang , Shengzhou Li , Wei Li , Bing Shen . Synergistic enhancement of chemotherapy for bladder cancer by photothermal dual-sensitive nanosystem with gold nanoparticles and PNIPAM. Chinese Chemical Letters, 2024, 35(8): 109199-. doi: 10.1016/j.cclet.2023.109199
5. [5]
  Ji Liu , Dongsheng He , Tianjiao Hao , Yumin Hu , Yan Zhao , Zhen Li , Chang Liu , Daquan Chen , Qiyue Wang , Xiaofei Xin , Yan Shen . Gold mineralized "hybrid nanozyme bomb" for NIR-II triggered tumor effective permeation and cocktail therapy. Chinese Chemical Letters, 2024, 35(9): 109296-. doi: 10.1016/j.cclet.2023.109296
6. [6]
  Ya-Wen Zhang , Ming-Ming Gan , Li-Ying Sun , Ying-Feng Han . Supramolecular dinuclear silver(I) and gold(I) tetracarbene metallacycles and fluorescence sensing of penicillamine. Chinese Journal of Structural Chemistry, 2024, 43(9): 100356-100356. doi: 10.1016/j.cjsc.2024.100356
7. [7]
  Chong-Yang Shi , Jian-Xing Gong , Zhen Li , Chao Shu , Long-Wu Ye , Qing Sun , Bo Zhou , Xin-Qi Zhu . Gold-catalyzed intermolecular amination of allyl azides with ynamides: Efficient construction of 3-azabicyclo[3.1.0] scaffold. Chinese Chemical Letters, 2025, 36(2): 109895-. doi: 10.1016/j.cclet.2024.109895
8. [8]
  Yunxia Liu , Guandong Wu , Lin Li , Yiming Niu , Bingsen Zhang , Botao Qiao , Junhu Wang . Construction of sintering-resistant gold catalysts via ascorbic-acid inducing strong metal-support interactions. Chinese Chemical Letters, 2025, 36(4): 110608-. doi: 10.1016/j.cclet.2024.110608
9. [9]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
10. [10]
  Xiangdong Lai , Tengfei Liu , Zengchao Guo , Yihan Wang , Jiang Xiao , Qingxiu Xia , Xiaohui Liu , Hui Jiang , Xuemei Wang . In situ formed fluorescent gold nanoclusters inhibit hair follicle regeneration in oxidative stress microenvironment via suppressing NFκB signal pathway. Chinese Chemical Letters, 2025, 36(2): 109762-. doi: 10.1016/j.cclet.2024.109762
11. [11]
  Jijoe Samuel Prabagar , Kumbam Lingeshwar Reddy , Dong-Kwon Lim . Visible-light responsive gold nanoparticle and nano-sized Bi2O3-x sheet heterozygote structure for efficient photocatalytic conversion of N2 to NH3. Chinese Journal of Structural Chemistry, 2025, 44(4): 100564-100564. doi: 10.1016/j.cjsc.2025.100564
12. [12]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
13. [13]
  Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796
14. [14]
  Dong-Ling Kuang , Song Chen , Shaoru Chen , Yong-Jie Liao , Ning Li , Lai-Hon Chung , Jun He . 2D Zirconium-based metal-organic framework/bismuth(III) oxide nanorods composite for electrocatalytic CO2-to-formate reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100301-100301. doi: 10.1016/j.cjsc.2024.100301
15. [15]
  Huaran Zhang , Yuting Huang , Yingjie Tang , Dekun Kong , Yi Zou . Genome mining of multi-substituted alkylresorcinols from a hybrid highly reducing- and type Ⅲ- polyketide pathway. Chinese Chemical Letters, 2024, 35(7): 108968-. doi: 10.1016/j.cclet.2023.108968
16. [16]
  Hui Zhang , Rong Feng , Wanyi Yu , Hongbei Wei , Tianhong Wu , Peng Zhang , Wenhai Bian , Xin Li , Di Gao , Guojun Weng , Zhe Yang , Tony D. James , Xiaolong Sun . Evaluating the global thiols redox state in living cells using a reducing sulfur species responsive fluorescence switching platform. Chinese Chemical Letters, 2025, 36(4): 110528-. doi: 10.1016/j.cclet.2024.110528
17. [17]
  Guangyao Wang , Zhitong Xu , Ye Qi , Yueguang Fang , Guiling Ning , Junwei Ye . Electrospun nanofibrous membranes with antimicrobial activity for air filtration. Chinese Chemical Letters, 2024, 35(10): 109503-. doi: 10.1016/j.cclet.2024.109503
18. [18]
  Jin Wang , Xiaoyan Pan , Junyu Zhang , Qingqing Zhang , Yanchen Li , Weiwei Guo , Jie Zhang . Active molecule-based theranostic agents for tumor vasculature normalization and antitumor efficacy. Chinese Chemical Letters, 2024, 35(8): 109187-. doi: 10.1016/j.cclet.2023.109187
19. [19]
  Zhikang Wu , Guoyong Dai , Qi Li , Zheyu Wei , Shi Ru , Jianda Li , Hongli Jia , Dejin Zang , Mirjana Čolović , Yongge Wei . POV-based molecular catalysts for highly efficient esterification of alcohols with aldehydes as acylating agents. Chinese Chemical Letters, 2024, 35(8): 109061-. doi: 10.1016/j.cclet.2023.109061
20. [20]
  Lan Yang , Yu Li , Mou Jiang , Rui Zhou , Hengjiang Cong , Minghui Yang , Lei Zhang , Shenhui Li , Yunhuang Yang , Maili Liu , Xin Zhou , Zhong-Xing Jiang , Shizhen Chen . Fluorinated [2]rotaxanes as sensitive ¹⁹F MRI agents: Threading for higher sensitivity. Chinese Chemical Letters, 2024, 35(10): 109512-. doi: 10.1016/j.cclet.2024.109512

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(754)
HTML views(62)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Getting rid of NaBH4: Gold seeds reduced by air-stable agents for synthesizing quasi one-dimensional gold nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Getting rid of NaBH₄: Gold seeds reduced by air-stable agents for synthesizing quasi one-dimensional gold nanoparticles