Citation: Ou Wei, Zou Ru, Han Mengting, Yu Lei, Su Chenliang, Wei Ou, Ru Zou, Han Mengting, Yu Lei, Su Chenliang. Tailorable carbazolyl cyanobenzene-based photocatalysts for visible light-induced reduction of aryl halides[J]. Chinese Chemical Letters, ;2020, 31(7): 1899-1902. doi: 10.1016/j.cclet.2019.12.017 shu

Tailorable carbazolyl cyanobenzene-based photocatalysts for visible light-induced reduction of aryl halides

Ou Wei ^a,1 ,
Zou Ru ^a,1 ,
Han Mengting ^a,b ,
Yu Lei ^b ,
Su Chenliang ^a ,
Wei Ou ^a ,
Ru Zou ^a ,
Han Mengting ^a,b ,
Yu Lei ^b,*, ,
Su Chenliang ^a,*,

a.
International Collaborative Laboratory of 2D Materials for Optoelectronic Science & Technology of Ministry of Education, Engineering Technology Research Center for 2D Materials Information Functional Devices and Systems of Guangdong Province, Institute of Microscale Optoeletronics, Shenzhen University, Shenzhen 518060, China
b.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

yulei@yzu.edu.cn

chmsuc@szu.edu.cn

Received Date: 6 November 2019
Revised Date: 30 November 2019
Accepted Date: 9 December 2019
Available Online: 11 December 2019

Figures(5)

Herein, a series of carbazolyl cyanobenzene (CCB)-based organic photocatalysts with a broad range of photoredox capabilities were designed and synthesized, allowing precise control of the photocatalytic reactivity for the controllable reduction of aryl halides via a metal-free process. The screened-out CCB (5CzBN), a metal-free, low-cost, scalable and sustainable photocatalyst with both strong oxidative and reductive ability, exhibits superior performance for both dehalogenation and C-C bond-forming arylation reactions.
- Organic photocatalyst,
- Halide,
- C-C bond-formation,
- Photocatalyst,
- Reduction
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