Citation: Guo Chao, Yue Dongting, Wang Songling, Qian Xufang, Zhao Yixin. Mechanochemically sulfured FeS_1.92 as stable and efficient heterogeneous Fenton catalyst[J]. Chinese Chemical Letters, ;2020, 31(7): 1978-1981. doi: 10.1016/j.cclet.2019.11.049 shu

Mechanochemically sulfured FeS_1.92 as stable and efficient heterogeneous Fenton catalyst

School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200242, China

yixin.zhao@sjtu.edu.cn

Received Date: 7 November 2019
Revised Date: 13 November 2019
Accepted Date: 28 November 2019
Available Online: 29 November 2019

Figures(4)

Fenton reaction is one of most promising approaches for efficient removal of various robust organic pollutants in wastewater, however it faces several intrinsic challenges such as acidic condition, sludge waste and sensitive to sulfide-containing compound. Here we reported a novel FeS_1.92 as an efficient and sulfide resistant heterogeneous Fenton catalyst under mild condition. This novel FeS_1.92 was facilely prepared through a mechanochemical synthesis of mackinawite (FeS) with sulfur powder (S) by ball milling. The sulfured mackinawite (FeS_1.92) exhibits high performance in activating H₂O₂ to generate hydroxyle radicals for organic waste remediation. Furthermore, this FeS_1.92 based heterogeneous Fenton catalyst is highly sulfide resistant and shows improved performance for degrading sulfide-containing organic pollutants. This study provides an effective mechanochemical approach to fabricate heterogeneous Fenton catalysts for sulfide-containing wastewater treatment.
- Mechanochemical,
- Ball milling,
- Sulfured mackinawite,
- Heterogeneous Fenton catalysts,
- Hydroxyl radicals
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Mechanochemically sulfured FeS1.92 as stable and efficient heterogeneous Fenton catalyst

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通讯作者: 陈斌, bchen63@163.com

Mechanochemically sulfured FeS_1.92 as stable and efficient heterogeneous Fenton catalyst