Citation: Dong Yan, Feng Yuezhan, Deng Jiwei, He Pengbin, Ma Jianmin. Electrospun Sb₂Se₃@C nanofibers with excellent lithium storage properties[J]. Chinese Chemical Letters, ;2020, 31(3): 909-914. doi: 10.1016/j.cclet.2019.11.039 shu

Electrospun Sb₂Se₃@C nanofibers with excellent lithium storage properties

Dong Yan ^a ,
Feng Yuezhan ^b,*, ,
Deng Jiwei ^c,*, ,
He Pengbin ^a ,
Ma Jianmin ^a,*,

a.
School of Physics and Electronics, Hunan University, Changsha 410082, China
b.
Key Laboratory of Materials Processing and Mold(Zhengzhou University), Ministry of Education, Zhengzhou University, Zhengzhou 450002, China
c.
College of Mechanical and Electrical Engineering, Central South University, Changsha 410083, China

yzfeng@zzu.edu.cn

dengjw@csu.edu.cn

nanoelechem@hnu.edu.cn

Received Date: 15 September 2019
Revised Date: 22 October 2019
Accepted Date: 25 November 2019
Available Online: 26 November 2019

Figures(5)

Antimony-based materials have become promising anodes within lithium-ion batteries (LIBs) due to their low cost and the high theoretical capacity. However, there is a potential to further enhance the electrochemical performance of such antimony-based materials. Herein, Sb₂Se₃@C nanofibers (Sb₂Se₃@CNFs) are designed and obtained via a novel electrospinning method. Upon electrochemically testing as an anode within LIBs, the Sb₂Se₃@CNFs (annealed at 600 ℃) delivers a remarkably good cycling performance of 625 mAh/g at 100 mA/g after 100 cycles. Moreover, it still remains at 490 mAh/g after 500 cycles with an applied current density of 1.0 A/g. The excellent performance of the Sb₂Se₃@CNFs can be attributed to the fact that the N-doped C matrices not only remit the volume expansion of materials, but also enhance the electrical and ionic conductivity thusly increasing the lithium-ion diffusion. The obtained Sb₂Se₃@CNFs are promising anode for LIBs in the future.
- Sb₂Se₃,
- Nanofibers,
- Electrospinning,
- Anode,
- Li-ion battery
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Electrospun Sb₂Se₃@C nanofibers with excellent lithium storage properties