Citation: Liu Wenjie, Zhang Xiong, Li Chen, Wang Kai, Sun Xianzhong, Ma Yanwei. Carbon-coated Li₃VO₄ with optimized structure as high capacity anode material for lithium-ion capacitors[J]. Chinese Chemical Letters, ;2020, 31(9): 2225-2229. doi: 10.1016/j.cclet.2019.11.015 shu

Carbon-coated Li₃VO₄ with optimized structure as high capacity anode material for lithium-ion capacitors

Liu Wenjie ^a,b ,
Zhang Xiong ^a,b,c,*, ,
Li Chen ^a ,
Wang Kai ^a,b ,
Sun Xianzhong ^a ,
Ma Yanwei ^a,b,*,

a.
Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
b.
School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
c.
Dalian National Laboratory for Clean Energy, Dalian 116023, China

zhangxiong@mail.iee.ac.cn

ywma@mail.iee.ac.cn

Received Date: 18 September 2019
Revised Date: 6 November 2019
Accepted Date: 7 November 2019
Available Online: 13 November 2019

Figures(6)

Due to the high capacity, moderate voltage platform, and stable structure, Li₃VO₄ (LVO) has attracted close attention as feasible anode material for lithium-ion capacitor. However, the intrinsic low electronic conductivity and sluggish kinetics of the Li⁺ insertion process severely impede its practical application in lithium-ion capacitors (LICs). Herein, a carbon-coated Li₃VO₄ (LVO/C) hierarchical structure was prepared by a facial one-step solid-state method. The synthesized LVO/C composite delivers an impressive capacity of 435 mAh/g at 0.07 A/g, remarkable rate capability, and nearly 100% capacity retention after 500 cycles at 0.5 A/g. The superior electrochemical properties of LVO/C composite materials are attributed to the improved conductivity of electron and stable carbon/LVO composite structures. Besides, the LIC device based on activated carbon (AC) cathode and optimal LVO/C as anode reveals a maximum energy density of 110 Wh/kg and long-term cycle life. These results provide a potential way for assembling the advanced hybrid lithium-ion capacitors.
- Carbon-coated,
- Li₃VO₄,
- Lithium-ion capacitors,
- Anode material,
- Capacity matching
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Carbon-coated Li₃VO₄ with optimized structure as high capacity anode material for lithium-ion capacitors