Citation: Deng Siyu, Li Junyi, Chen Xiang, Hou Yunlong, Chen Lizhuang. A novel ferroelectric based on quinuclidine derivatives[J]. Chinese Chemical Letters, ;2020, 31(6): 1686-1689. doi: 10.1016/j.cclet.2019.11.011 shu

A novel ferroelectric based on quinuclidine derivatives

School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China

ylhou8@just.edu.cn

clz1977@sina.com

Received Date: 26 September 2019
Revised Date: 3 November 2019
Accepted Date: 7 November 2019
Available Online: 15 November 2019

Figures(3)

The compound[(CH₃)₂CH-C₃H₁₇N] [CoBr₄] (1) based on quinuclidine derivatives was achieved by the solution synthetic method and characterized by elemental analysis, infrared spectroscopy, single-crystal X-ray structural analysis and dielectric measurement, respectively. Variable-temperature single-crystal X-ray diffraction suggested that the compound underwent the phase transition from the space group C2/c to Cc. The polarization curve was measured using the Sawyer-Tower circuit. The structural phase transitions of 1 was ascribed to the distortion of a[(CH₃)₂CH-C₃H₁₇N]²⁺ cation from this inorganic-organic hybrid material[(CH₃)₂CH-C₃H₁₇N] [CoBr₄]. The strong change in dielectric anomalies makes compound 1 a suitable candidate for promising switchable dielectric materials. This work represents a feasible strategy thought for the targeted harvesting of low temperature ferroelectrics.
- Ferroelectric,
- Quinuclidine,
- Phase transition,
- Polarization,
- Dielectric
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