Citation: Shang Wen, Du Huanzhou, Wu Yage, Xu Jianlin, Ran Fen. Hierarchical porous nanofibers of carbon@nickel oxide nanoparticles derived from polymer/block copolymer system[J]. Chinese Chemical Letters, ;2020, 31(9): 2202-2206. doi: 10.1016/j.cclet.2019.10.017 shu

Hierarchical porous nanofibers of carbon@nickel oxide nanoparticles derived from polymer/block copolymer system

Shang Wen ^a,b ,
Du Huanzhou ^a ,
Wu Yage ^a ,
Xu Jianlin ^a,b ,
Ran Fen ^a,b,*,

a.
State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals, School of Material Science and Engineering, Lanzhou University of Technology, Lanzhou 730050, China
b.
BaiYin Research Institute of Novel Materials, Lanzhou University of Technology, Lanzhou 730050, China

ranfen@163.com

ranfen@lut.cn

Received Date: 20 August 2019
Revised Date: 12 September 2019
Accepted Date: 16 September 2019
Available Online: 9 November 2019

Figures(4)

The triblock copolymer (PAA-b-PAN-b-PAA) iSs prepared by reversible addition-fragmentation chain-transfer polymerization, and then blended with polymer (PAN) and metal hydroxide (Ni(OH)₂) as a precursor for heat-treatment. A composite material of hierarchical porous nanofibers and nickel oxide nanoparticles (HPCF@NiO) is prepared by electrospinning combined with high-temperature carbonization. The effects of the ratio of PAA and PAA-b-PAN-b-PAA on the internal structure of nanofibers and their electrochemical properties as positive electrode materials are investigated. The experimental results show that when the ratio of PAA to PAA-b-PAN-b-PAA is 1.3 to 0.4, it has good pore structure and excellent electrochemical performance. At the current density of 1 A/g, the specific capacitance is 188.7 F/g and the potential window is -1 V to 0.37 V. The asymmetric supercapacitor assembled with activated carbon as the negative electrode materials has a specific capacitance of 21.2 F/g in 2 mol/L KOH and a capacitance retention of 85.7% after 12, 500 cycles at different current density.
- Electrospinning,
- Block copolymer,
- Nickel oxide,
- Hierarchical porous carbon fiber,
- Supercapacitors
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