Citation: Xie Xiuqiang, Wu Zhenjun, Zhang Nan. Robust and easily retrievable Pd/Ti₃C₂T_x⊂graphene hydrogels for efficient catalytic hydrogenation of nitroaromatic compounds[J]. Chinese Chemical Letters, ;2020, 31(4): 1014-1017. doi: 10.1016/j.cclet.2019.10.012 shu

Robust and easily retrievable Pd/Ti₃C₂T_x⊂graphene hydrogels for efficient catalytic hydrogenation of nitroaromatic compounds

Xie Xiuqiang ^a,*, ,
Wu Zhenjun ^b ,
Zhang Nan ^a,*,

a.
College of Materials Science and Engineering, Hunan University, Changsha 410082, China
b.
College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

xiuqiang_xie@hnu.edu.cn

nanzhang@hnu.edu.cn

Received Date: 14 September 2019
Revised Date: 10 October 2019
Accepted Date: 12 October 2019
Available Online: 22 October 2019

Figures(3)

Ti₃C₂T_x has been emerging as an attractive platform to prepare composite catalysts, and their assembly into integrated catalytic materials represents a key step forward toward practical applications. However, the swelling behavior of Ti₃C₂T_x leads to significant structure change, which challenges the stability of Ti₃C₂T_x-based integrated functional materials for catalytic applications. Here we report a facile synthesis of Pd/Ti₃C₂T_x⊂graphene hydrogels in which Pd/Ti₃C₂T_x are spatially encapsulated in the 3D porous graphene framework. The porous interconnected structure not only affords efficient mass transfer and desirable functional accessibility to catalytic active sites, but also effectively buffers the swelling behavior of Ti₃C₂T_x. When applied for catalytic hydrogenation of nitroaromatic compounds, the mechanically robust Pd/Ti₃C₂T_x⊂graphene hydrogels exhibit efficient activities, easy separability, and good cyclability. This work is expected to promote the application of Ti₃C₂T_x-based functional materials for practical applications involving interactions with salt solutions, such as supercapacitors, catalysis, and water purification.
- Ti₃C₂T_x,
- Hydrogels,
- Robust structure,
- Convenient recyclability,
- Nitroaromatic compounds hydrogenation
1. [1]
  M. Naguib, M. Kurtoglu, V. Presser, et al., Adv. Mater. 23(2011) 4248-4253. doi: 10.1002/adma.201102306
2. [2]
  B. Anasori, M.R. Lukatskaya, Y. Gogotsi, Nat. Rev. Mater. 2(2017) 16098. doi: 10.1038/natrevmats.2016.98
3. [3]
  H. He, Q. Xia, B. Wang, et al., Chin. Chem. Lett. 31(2020) 984- doi: 10.1016/j.cclet.2019.08.025
4. [4]
  M. Li, J. Lu, K. Luo, et al., J. Am. Chem. Soc. 141(2019) 4730-4737. doi: 10.1021/jacs.9b00574
5. [5]
  E. Satheeshkumar, T. Makaryan, A. Melikyan, et al., Sci. Rep. 6(2016) 32049. doi: 10.1038/srep32049
6. [6]
  X. Xie, C. Chen, N. Zhang, et al., Nature Sustain. 2(2019) 856-862. doi: 10.1038/s41893-019-0373-4
7. [7]
  J. Luo, W. Zhang, H. Yuan, et al., ACS Nano 11(2017) 2459-2469. doi: 10.1021/acsnano.6b07668
8. [8]
  J. Yan, C.E. Ren, K. Maleski, et al., Adv. Funct. Mater. 27(2017) 1701264. doi: 10.1002/adfm.201701264
9. [9]
  M.Q. Zhao, X. Xie, C.E. Ren, et al., Adv. Mater. 29(2017) 1702410. doi: 10.1002/adma.201702410
10. [10]
  X. Tang, X. Guo, W. Wu, G. Wang, Adv. Energy Mater. 8(2018) 1801897. doi: 10.1002/aenm.201801897
11. [11]
  Y.T. Liu, P. Zhang, N. Sun, et al., Adv. Mater. 30(2018) 1707334. doi: 10.1002/adma.201707334
12. [12]
  Y. Dong, S. Zheng, J. Qin, et al., ACS Nano 12(2018) 2381-2388. doi: 10.1021/acsnano.7b07672
13. [13]
  Y. Fang, B. Yang, D. He, et al., Chin. Chem. Lett. 31(2020) 1004-1008. doi: 10.1016/j.cclet.2019.08.043
14. [14]
  L. Ding, Y. Wei, L. Li, et al., Nat. Commun. 9(2018) 155. doi: 10.1038/s41467-017-02529-6
15. [15]
  C. Zhang, S. -H. Park, A. Seral-Ascaso, et al., Nat. Commun. 10(2019) 849. doi: 10.1038/s41467-019-08383-y
16. [16]
  H. Liu, X. Zhang, Y. Zhu, et al., Nano-Micro Lett. 11(2019) 65. doi: 10.1007/s40820-019-0296-7
17. [17]
  X. Zhang, Y. Guo, Y. Li, Y. Liu, S. Dong, Chin. Chem. Lett. 30(2019) 502-504. doi: 10.1016/j.cclet.2018.07.007
18. [18]
  Q. Zhao, Q. Zhu, J. Miao, P. Zhang, B. Xu, Nanoscale 11(2019) 8442-8448. doi: 10.1039/C8NR09653H
19. [19]
  Y. Gao, Y. Cao, Y. Gu, et al., Appl. Surf. Sci. 465(2019) 911-918. doi: 10.1016/j.apsusc.2018.09.254
20. [20]
  S.J. Tauster, S.C. Fung, R.L. Garten, J. Am. Chem. Soc. 100(1978) 170-175. doi: 10.1021/ja00469a029
21. [21]
  C.T. Campbell, Nat. Chem. 4(2012) 597. doi: 10.1038/nchem.1412
22. [22]
  N. Acerbi, S.C.E. Tsang, G. Jones, S. Golunski, P. Collier, Angew. Chem. Int. Ed. 52(2013) 7737-7741. doi: 10.1002/anie.201300130
23. [23]
  B.D. Chandler, Nat. Chem. 9(2017) 108. doi: 10.1038/nchem.2724
24. [24]
  K. Li, T. Jiao, R. Xing, et al., Green Energy Environ. 3(2018) 147-155. doi: 10.1016/j.gee.2017.11.004
25. [25]
  Z. Li, Z. Qi, S. Wang, et al., Nano Lett. 19(2019) 5102-5108. doi: 10.1021/acs.nanolett.9b01381
26. [26]
  S.Min, Y.Xue, F.Wang, Z.Zhang, H.Zhu, Chem.Commun.55(2019)10631-10634. doi: 10.1039/C9CC05489H
27. [27]
  C. Cui, R. Cheng, C. Zhang, X. Wang, Chin. Chem. Lett. 31(2020) 988- doi: 10.1016/j.cclet.2019.08.026
28. [28]
  X. Zhang, Z. Su, Adv. Mater. 24(2012) 4574-4577. doi: 10.1002/adma.201201712
29. [29]
  Y. Chen, X. Xie, X. Xin, Z.R. Tang, Y.J. Xu, ACS Nano 13(2019) 295-304. doi: 10.1021/acsnano.8b06136
30. [30]
  C.E.Ren, M. Alhabeb, B.W. Byles, et al., ACSAppl. Nano Mater.1(2018) 3644-3652. doi: 10.1021/acsanm.8b00762
31. [31]
  X. Xie, N. Zhang, Z.R. Tang, Y.J. Xu, Chem. Sci. 9(2018) 8876-8882. doi: 10.1039/C8SC03679A
32. [32]
  N. Zhang, S. Xie, B. Weng, Y.J. Xu, J. Mater. Chem. A 4(2016) 18804-18814. doi: 10.1039/C6TA07845A
33. [33]
  W. Wu, G. Liu, Q. Xie, et al., Green Chem. 14(2012) 1705-1709. doi: 10.1039/c2gc35231a
34. [34]
  X. Xie, N. Zhang, Z. R. Tang, M. Anpo, Y. J. Xu, Appl. Catal. B:Environ. 237(2018)43-49. doi: 10.1016/j.apcatb.2018.05.070
35. [35]
  P. Deka, R. Choudhury, R.C. Deka, P. Bharali, RSC Adv. 6(2016) 71517-71528. doi: 10.1039/C6RA16301G
36. [36]
  M.R. Lukatskaya, O. Mashtalir, C.E. Ren, et al., Science 341(2013) 1502. doi: 10.1126/science.1241488
37. [37]
  M. Ghidiu, J. Halim, S. Kota, et al., Chem. Mater. 28(2016) 3507-3514. doi: 10.1021/acs.chemmater.6b01275
1. [1]
  Jiajia Wang , XinXin Ge , Yajing Xiang , Xiaoliang Qi , Ying Li , Hangbin Xu , Erya Cai , Chaofan Zhang , Yulong Lan , Xiaojing Chen , Yizuo Shi , Zhangping Li , Jianliang Shen . An ionic liquid functionalized sericin hydrogel for drug-resistant bacteria-infected diabetic wound healing. Chinese Chemical Letters, 2025, 36(2): 109819-. doi: 10.1016/j.cclet.2024.109819
2. [2]
  Junqi Wang , Shuai Zhang , Jingjing Ma , Xiangjun Liu , Yayun Ma , Zhimin Fan , Jingfeng Wang . Augmenting levoglucosan production through catalytic pyrolysis of biomass exploiting Ti₃C₂T_x MXene. Chinese Chemical Letters, 2024, 35(12): 109725-. doi: 10.1016/j.cclet.2024.109725
3. [3]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477
4. [4]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
5. [5]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
6. [6]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
7. [7]
  Binhan Zhao , Zheng Li , Lan Zheng , Zhichao Ye , Yuyang Yuan , Shanshan Zhang , Bo Liang , Tianyu Li . Recent progress in the biomedical application of PEDOT:PSS hydrogels. Chinese Chemical Letters, 2024, 35(10): 109810-. doi: 10.1016/j.cclet.2024.109810
8. [8]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2024.100416
9. [9]
  Zikang Hu , Hengjie Zhang , Zhengqiu Li , Tianbao Zhao , Zhipeng Gu , Qijuan Yuan , Baoshu Chen . Multifunctional photothermal hydrogels: Design principles, various functions, and promising biological applications. Chinese Chemical Letters, 2024, 35(10): 109527-. doi: 10.1016/j.cclet.2024.109527
10. [10]
  Zhe-Han Yang , Jie Yin , Lei Xin , Yuanfang Li , Yijie Huang , Ruo Yuan , Ying Zhuo . Research advancement of DNA-based intelligent hydrogels: Manufacture, characteristics, application of disease diagnosis and treatment. Chinese Chemical Letters, 2024, 35(10): 109558-. doi: 10.1016/j.cclet.2024.109558
11. [11]
  Yue Sun , Yingnan Zhu , Jiahang Si , Ruikang Zhang , Yalan Ji , Jinjie Fan , Yuze Dong . Glucose-activated nanozyme hydrogels for microenvironment modulation via cascade reaction in diabetic wound. Chinese Chemical Letters, 2025, 36(4): 110012-. doi: 10.1016/j.cclet.2024.110012
12. [12]
  Mengchen Liu , Yufei Zhang , Yi Xiao , Yang Wei , Meichen Bi , Huaide Jiang , Yan Yu , Shenghong Zhong . High stretchability and toughness of liquid metal reinforced conductive biocompatible hydrogels for flexible strain sensors. Chinese Journal of Structural Chemistry, 2025, 44(3): 100518-100518. doi: 10.1016/j.cjsc.2025.100518
13. [13]
  Shaojie Ding , Henan Wang , Xiaojing Dai , Yuru Lv , Xinxin Niu , Ruilian Yin , Fangfang Wu , Wenhui Shi , Wenxian Liu , Xiehong Cao . Mn-modulated Co–N–C oxygen electrocatalysts for robust and temperature-adaptative zinc-air batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100302-100302. doi: 10.1016/j.cjsc.2024.100302
14. [14]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
15. [15]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
16. [16]
  Qing Li , Yumei Feng , Yingjie Yu , Yazhou Chen , Yuhua Xie , Fang Luo , Zehui Yang . Engineering e_g filling of RuO₂ enables a robust and stable acidic water oxidation. Chinese Chemical Letters, 2025, 36(3): 110612-. doi: 10.1016/j.cclet.2024.110612
17. [17]
  Huirong Chen , Yingzhi He , Yan Han , Jianbo Hu , Jiantang Li , Yunjia Jiang , Basem Keshta , Lingyao Wang , Yuanbin Zhang . A new SIFSIX anion pillared cage MOF with crs topological structure for efficient C2H2/CO2 separation. Chinese Journal of Structural Chemistry, 2025, 44(2): 100508-100508. doi: 10.1016/j.cjsc.2024.100508
18. [18]
  Wenhao Chen , Muxuan Wu , Han Chen , Lue Mo , Yirong Zhu . Cu₂Se@C thin film with three-dimensional braided structure as a cathode material for enhanced Cu²⁺ storage. Chinese Chemical Letters, 2024, 35(5): 108698-. doi: 10.1016/j.cclet.2023.108698
19. [19]
  Yuan ZHU , Xiaoda ZHANG , Shasha WANG , Peng WEI , Tao YI . Conditionally restricted fluorescent probe for Fe³⁺ and Cu²⁺ based on the naphthalimide structure. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 183-192. doi: 10.11862/CJIC.20240232
20. [20]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(1315)
HTML views(27)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Robust and easily retrievable Pd/Ti3C2Tx⊂graphene hydrogels for efficient catalytic hydrogenation of nitroaromatic compounds

Metrics

通讯作者: 陈斌, bchen63@163.com

Robust and easily retrievable Pd/Ti₃C₂T_x⊂graphene hydrogels for efficient catalytic hydrogenation of nitroaromatic compounds