Citation: Li Chen, Zhang Xiong, Wang Kai, Sun Xianzhong, Ma Yanwei. Accordion-like titanium carbide (MXene) with high crystallinity as fast intercalative anode for high-rate lithium-ion capacitors[J]. Chinese Chemical Letters, ;2020, 31(4): 1009-1013. doi: 10.1016/j.cclet.2019.09.056 shu

Accordion-like titanium carbide (MXene) with high crystallinity as fast intercalative anode for high-rate lithium-ion capacitors

Li Chen ^a ,
Zhang Xiong ^a,b,*, ,
Wang Kai ^a ,
Sun Xianzhong ^a ,
Ma Yanwei ^a,b,*,

a.
Institute of Electrical Engineering, Chinese Academy of Sciences, Beijing 100190, China
b.
School of Engineering Sciences, University of Chinese Academy of Sciences, Beijing 100049, China

zhangxiong@mail.iee.ac.cn

ywma@mail.iee.ac.cn

Received Date: 15 August 2019
Revised Date: 24 September 2019
Accepted Date: 25 September 2019
Available Online: 2 October 2019

Figures(5)

Two-dimensional transition-metal carbide materials, or MXenes, have attracted great attention in energy-related fields due to their excellent electrical conductivity, and large interlayer spacing. In this work, a simple method involving combustion synthesis and acid treatment to prepare accordion-like Ti₃C₂T_x MXene with open structure and high crystallinity, which is employed as anode materials in lithium-ion capacitors. Due to the improved ion diffusion and electron transportation of Ti₃C₂T_x anode, the mismatched electrode kinetics can be largely alleviated to acquire an enhanced power performance. The assembled Ti₃C₂T_x-based lithium-ion capacitors provides a maximum energy density of 106 Wh/kg and still exhibits a superior energy density of 79 Wh/kg even at a higher power density of 5.2 kW/kg, which provides a new platform for MXene materials with porous and crystalline features toward both high energy and power densities.
- Combustion synthesis,
- MXene,
- Lithium-ion capacitors,
- Titanium carbide,
- High rate
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