Citation: Chen Jia, Chand Ali Mohammad, Liu Ruirui, Claude Munyemana Jean, Li Zhan, Zhai Honglin, Qiu Hongdeng. Basic deep eutectic solvents as reactant, template and solvents for ultra-fast preparation of transition metal oxide nanomaterials[J]. Chinese Chemical Letters, ;2020, 31(6): 1584-1587. doi: 10.1016/j.cclet.2019.09.055 shu

Basic deep eutectic solvents as reactant, template and solvents for ultra-fast preparation of transition metal oxide nanomaterials

a.
CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
b.
University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100039, China
c.
Department of Chemistry, Lanzhou University, Lanzhou 730000, China

chandali1979@yahoo.com

hdqiu@licp.cas.cn

Received Date: 17 September 2019
Revised Date: 29 September 2019
Accepted Date: 30 September 2019
Available Online: 3 October 2019

Figures(3)

Developing a new type of deep eutectic solvents (DESs) is indispensable for expanding their application in various fields. Here, we report a series of new highly basic DESs. FT-IR, quantitative ¹H NMR, MD simulation and physical properties show that these basic liquids are made up of hydroxide acceptor of alkali metal hydroxides in which the hydrogen bonding interactions coordinate the donor. These DESs can be played three roles as new solvents, template and reactant for facile and ultra-fast preparation of transition metal oxide nanomaterials such as NiCo₂O₄, MnCo₂O₄, NiMn₂O₄, CoCu₂O₄ and Co₃O₄ under mild condition. This work shows one of the low energy-intensive methods for nanomaterial preparation. These initial findings of basic deep eutectic solvents provide a potential applicability around the systematic development of transition metal oxide nanosheets.
- Basic deep eutectic solvents,
- Hydrogen-bonding acceptors,
- Hydrogen-bonding donors,
- Transition metal oxide,
- Nanomaterials
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