Citation: Mi Xia, Kong Yuanfang, Zhang Jingyu, Pi Chao, Cui Xiuling. Visible-light-promoted sulfonylmethylation of imidazopyridines[J]. Chinese Chemical Letters, ;2019, 30(12): 2295-2298. doi: 10.1016/j.cclet.2019.09.040 shu

Visible-light-promoted sulfonylmethylation of imidazopyridines

Mi Xia ^a ,
Kong Yuanfang ^a ,
Zhang Jingyu ^a,*, ,
Pi Chao ^b ,
Cui Xiuling ^b,*,

a.
College of Pharmacy, Henan University of Chinese Medicine, Zhengzhou, China
b.
College of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou, China

jyzhang2004@hactcm.edu.cn

cuixl@zzu.edu.cn

Received Date: 7 September 2019
Revised Date: 16 September 2019
Accepted Date: 19 September 2019
Available Online: 19 December 2019

Figures(5)

The visible light promoted C-H sulfonylmethylation of imidazopyridines with easily accessible bromomethyl sulfones under mild reaction conditions was described. This protocol provides an effective and practical access to sulfonylmethylated imidazopyridines with good functional group tolerance. The desired products were provided in moderate to excellent yields for 50 examples at room temperature. The method could also be an attractive strategy to install a methyl group on imidazopyridines.
- Visible light promoted,
- Imidazopyridine,
- Sulfonylmethylation,
- Radical process,
- Desulfonylation
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