Citation: Ma Mingfeng, Chen Long, Zhao Jingzhu, Liu Wen, Ji Haodong. Efficient activation of peroxymonosulfate by hollow cobalt hydroxide for degradation of ibuprofen and theoretical study[J]. Chinese Chemical Letters, ;2019, 30(12): 2191-2195. doi: 10.1016/j.cclet.2019.09.031 shu

Efficient activation of peroxymonosulfate by hollow cobalt hydroxide for degradation of ibuprofen and theoretical study

Ma Mingfeng ^a,b ,
Chen Long ^c ,
Zhao Jingzhu ^a,b,**, ,
Liu Wen ^c,d,e ,
Ji Haodong ^c,d,*,

a.
State Key Laboratory of Urban and Regional Ecology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China
b.
University of Chinese Academy of Sciences, Beijing 100049, China
c.
The Key Laboratory of Water and Sediment Science, Ministry of Education, College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China
d.
The Beijing Innovation Center for Engineering Science and Advanced Technology(BIC-ESAT), Peking University, Beijing 100871, China
e.
Beijing Engineering Research Center for Advanced Wastewater Treatment, Peking University, Beijing 100871, China

^**

jzhao@rcees.ac.cn

jihaodong@pku.edu.cn

Received Date: 5 June 2019
Revised Date: 15 September 2019
Accepted Date: 17 September 2019
Available Online: 18 December 2019

Figures(5)

Hollow microsphere structure cobalt hydroxide (h-Co(OH)₂) was synthesized via an optimized solvothermal-hydrothermal process and applied to activate peroxymonosulfate (PMS) for degradation of a typical pharmaceutically active compound, ibuprofen (IBP). The material characterizations confirmed the presence of the microscale hollow spheres with thin nanosheets shell in h-Co(OH)₂, and the crystalline phase was assigned to α-Co(OH)₂. h-Co(OH)₂ could efficiently activate PMS for radicals production, and 98.6% of IBP was degraded at 10 min. The activation of PMS by h-Co(OH)₂ was a pHindependent process, and pH 7 was the optimum condition for the activation-degradation system. Scavenger quenching test indicated that the sulfate radical (SO₄^·-) was the primary reactive oxygen species for IBP degradation, which contributed to 75.7%. Fukui index (f^-) based on density functional theory (DFT) calculation predicted the active sites of IBP molecule for SO₄^·- attack, and then IBP degradation pathway was proposed by means of intermediates identification and theoretical calculation. The developed hollow Co(OH)₂ used to efficiently activate PMS is promising and innovative alternative for organic contaminants removal from water and wastewater.
- Cobalt hydroxid,
- Pharmaceuticals,
- Peroxymonosulfate,
- Activation,
- DFT calculation
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