Citation: Qian Xiu, Deng Siyu, Chen Xiang, Gao Qiang, Hou Yun-Long, Wang Aiwu, Chen Lizhuang. A highly stable, luminescent and layered zinc(Ⅱ)-MOF: Iron(Ⅲ)/copper(Ⅱ) dual sensing and guest-assisted exfoliation[J]. Chinese Chemical Letters, ;2020, 31(9): 2211-2214. doi: 10.1016/j.cclet.2019.09.024 shu

A highly stable, luminescent and layered zinc(Ⅱ)-MOF: Iron(Ⅲ)/copper(Ⅱ) dual sensing and guest-assisted exfoliation

Qian Xiu ^a ,
Deng Siyu ^a ,
Chen Xiang ^a ,
Gao Qiang ^a ,
Hou Yun-Long ^a,b,*, ,
Wang Aiwu ^c ,
Chen Lizhuang ^a,*,

a.
School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
b.
Department of Materials Science and Engineering, City University of Hong Kong, Hong Kong SAR, China
c.
Center for Advanced material Diagnostic Technology, Shenzhen Technology University, Shenzhen 518118, China

ylhou8@just.edu.cn

clz1977@sina.com

Received Date: 6 July 2019
Revised Date: 4 September 2019
Accepted Date: 5 September 2019
Available Online: 12 September 2019

Figures(3)

A highly stable and luminescent metal-organic framework (LMOF) with layered structure, namely, C₆H₄N₅OZn (1) has been successfully achieved and fully characterized by single crystal X-ray diffraction, powder X-ray diffractions, fluorescence titration and thermogravimetry. This blue-light emitting compound 1 exhibit outstanding stability and can detect Fe³⁺ and Cu²⁺ in water specifically, presenting potential application in the field of fluorescent probe technology. Fluorescence titration experiments indicate that the detection of Fe³⁺ ions by 1 is more significant than that of Cu²⁺ ions in terms of K_sv value. Furthermore, guest-assisted exfoliation of layered MOF 1 is efficiently carried out through ether O—H hydrogen bond or π…π interactions between the layered host structure and intercalated guest molecules (4, 4'-oxybisbenzoic acid and triphenylamine). Tyndal scattering was observed in the suspensions of obtained MOF nanosheets. This study shows that the compound 1 with unique metal ion sensing properties can be applied as a probe material in water pollution treatment field, but also opens up the opportunity for synthesizing luminescent MONs through the "bottom-up" guest intercalation methodology.
- LMOF,
- Fluorescence titration,
- Tyndal scattering,
- MONs,
- Exfoliation
1. [1]
  Y. Cui, Y. Yue, G. Qian, B. Chen, Chem. Rev. 112(2012) 1126-1162. doi: 10.1021/cr200101d
2. [2]
  Y. Zhang, S. Yuan, G. Day, et al., Coord. Chem. Rev. 354(2018) 28-45. doi: 10.1016/j.ccr.2017.06.007
3. [3]
  T. Islamoglu, S. Goswami, Z. Li, et al., Acc. Chem. Res. 50(2017) 805-813. doi: 10.1021/acs.accounts.6b00577
4. [4]
  Q. Zhang, C. Zhang, L. Cao, et al., J. Am. Chem. Soc. 138(2016) 5308-5315. doi: 10.1021/jacs.6b01345
5. [5]
  S.Z. Zhan, M. Li, S.W. Ng, D. Li, Chem. Eur. J. 19(2013) 10217-10225. doi: 10.1002/chem.201204632
6. [6]
  G. Liu, D.Q. Feng, X. Mu, et al., J. Mater. Chem. B 1(2013) 2128-2131. doi: 10.1039/c3tb20208a
7. [7]
  A. Wang, Y.L. Hou, F. Kang, et al., J. Mater. Chem. 7(2012) 2207-2211.
8. [8]
  S. Pramanik, C. Zheng, X. Zhang, T.J. Emge, J. Li, J. Am. Chem. Soc. 133(2012) 4153-4155.
9. [9]
  Z. Hu, K. Tan, W.P. Lustig, et al., Chem. Sci. 5(2014) 4873-4877. doi: 10.1039/C4SC02157F
10. [10]
  S.M. Zhang, Z. Chang, T.L. Hu, X.H. Bu, Inorg. Chem. 49(2010) 11581-11586. doi: 10.1021/ic1017467
11. [11]
  Z. Chang, D.H. Yang, J. Xu, T.L. Hu, X.H. Bu, Adv. Mater. 27(2015) 5432-5441. doi: 10.1002/adma.201501523
12. [12]
  J. Liu, H.B. Zhang, Y.X. Tan, et al., Inorg. Chem. 53(2014) 1500-1506. doi: 10.1021/ic402467g
13. [13]
  B. Gole, A.K. Bar, P.S. Mukherjee, Chem. Commun. (Camb.) 47(2011) 12137-12139. doi: 10.1039/c1cc15594f
14. [14]
  S.S. Nagarkar, B. Joarder, A.K. Chaudhari, S. Mukherjee, S.K. Ghosh, Angew. Chem. Int. Ed. 125(2013) 2953-2957. doi: 10.1002/ange.201208885
15. [15]
  S.S. Nagarkar, A.V. Desai, S.K. Ghosh, Chem. Commun. (Camb.) 50(2014) 8915-8918. doi: 10.1039/C4CC03053B
16. [16]
  Y. Xiao, Y. Cui, Q. Zheng, S. Xiang, G. Qian, Chem. Commun. (Camb.) 30(2010) 5503-5505.
17. [17]
  J. Geng, Y. Liu, J. Li, et al., Sensor. Actuat. B -Chem. 222(2016) 612-617. doi: 10.1016/j.snb.2015.08.076
18. [18]
  D.K. Singha, P. Mahata, Inorg. Chem. 13(2015) 6373-6375.
19. [19]
  M.D. Allendorf, C.A. Bauer, R.K. Bhaktaa, R.J.T. Houk, Chem. Soc. Rev. 38(2009) 1330-1352. doi: 10.1039/b802352m
20. [20]
  Z. Hu, B.J. Deibert, J. Li, Chem. Soc. Rev. 43(2014) 5815-5840. doi: 10.1039/C4CS00010B
21. [21]
  H.J. Kalinowski, J.L. Fabris, W.J. Bock, 24th International Conference on Optical Fibre Sensors, 2015.
22. [22]
  X. Zhao, D. Liu, H. Huang, C. Zhong, Microporous Mesoporous Mater. 224(2016) 149-154. doi: 10.1016/j.micromeso.2015.11.042
23. [23]
  Y.J. Ding, Y.P. Chen, X.L. Zhang, et al., J. Am. Chem. Soc. 27(2017) 9136-9139.
24. [24]
  M. Zhao, Y. Huang, Y.W. Peng, et al., Chem. Soc. Rev. 16(2018) 6001-6046.
25. [25]
  D.J. Ashworth, J.A. Foster, J. Mater. Chem. A Mater. Energy Sustain. 6(2018) 16292-16307. doi: 10.1039/C8TA03159B
26. [26]
  W.W. Zhao, J.L. Peng, W.K. Wang, et al., Coord. Chem. Rev. 377(2018) 44-63. doi: 10.1016/j.ccr.2018.08.023
27. [27]
  M. Ko, L. Mendecki, K.A. Mirica, Chem. Commun. (Camb.) 54(2018) 7873-7891. doi: 10.1039/C8CC02871K
28. [28]
  Y.Z. Fu, Q. Han, Q. Chen, et al., Chem. Commun. (Camb.) 48(2012) 2322-2324. doi: 10.1039/c2cc17301h
29. [29]
  J.G. Li, H.C. Sun, L. Lv, et al., ACS Appl. Mater. Inter. 11(2019) 8106-8114. doi: 10.1021/acsami.8b22133
30. [30]
  L. Lv, Z.X. Yang, K. Chen, C.D. Wang, Y.J. Xiong, Adv. Energy Mater. (2019) 1803358.
31. [31]
  L.Z. Chen, F.M. Wang, X.X. Cao, Chin. J. Struct. Chem. 31(2012) 1417-1422.
32. [32]
  L.Z. Chen, X.X. Cao, F.M. Wang, G.L. Xie, Inorg. Chem. 28(2012) 1291-1297.
33. [33]
  L.Z. Chen, Q. Ji, Y.Y. Dan, Chin. J. Struct. Chem. 35(2016) 1728-1735.
34. [34]
  F.M. Wang, Z.Y. Zhou, W. Liu, et al., Dalton Trans. 46(2017) 956-961. doi: 10.1039/C6DT03883B
35. [35]
  L.Z. Chen, F.M. Wang, S. Hong, J. Coord. Chem. 65(2012) 439-452. doi: 10.1080/00958972.2012.654786
36. [36]
  P. Wang, J. Fu, K. Yao, et al., Sensor. Actuat. B -Chem. 273(2018) 1070-1076. doi: 10.1016/j.snb.2018.07.028
37. [37]
  A.J. Howarth, Y. Liu, P. Li, et al., Nat. Rev. Mater. 1(2016) 15018. doi: 10.1038/natrevmats.2015.18
38. [38]
  C.H. Chen, X.S. Wang, L. Li, Y.B. Huang, R. Cao, Dalton Trans. 47(2018) 3452-3458. doi: 10.1039/C8DT00088C
39. [39]
  X.X. Jia, R.X. Yao, F.Q. Zhang, X.M. Zhang, Inorg. Chem. 56(2017) 2690. doi: 10.1021/acs.inorgchem.6b02872
40. [40]
  C. Xing, Z. Shi, M. Yu, S. Wang, Polymer 49(2018) 2698-2703.
41. [41]
  Q. Jin, L.Z. Chen, Chin. J. Inorg. Chem. 33(2017) 8-15.
42. [42]
  R. Kagit, M. Yildirim, O. Ozay, et al., Inorg. Chem. 53(2014) 2144-2151. doi: 10.1021/ic402783x
43. [43]
  B.L. Sui, S. Tang, T.H. Liu, et al., ACS Appl. Mater. Interfaces 6(2014) 18408-18412. doi: 10.1021/am506262u
44. [44]
  X.Y. Mu, L. Qi, J. Qiao, H.M. Ma, Anal. Methods 6(2014) 6445-6451. doi: 10.1039/C4AY01137F
45. [45]
  A. Ananthanarayanan, X.W. Wang, P. Routh, et al., Adv. Funct. Mater. 24(2014) 3021-3026. doi: 10.1002/adfm.201303441
46. [46]
  X.Y. Dong, R. Wang, J.Z. Wang, et al., J. Mater. Chem. A:Mater. Energy Sustain. 3(2015) 641-647. doi: 10.1039/C4TA04421E
47. [47]
  Y.T. Liang, G.P. Yang, B. Liu, et al., Dalton Trans. 44(2015) 13325-13330. doi: 10.1039/C5DT01421B
48. [48]
  H. Xu, H.C. Hu, C.S. Cao, B. Zhao, Inorg. Chem. 54(2015) 4585-4587. doi: 10.1021/acs.inorgchem.5b00113
1. [1]
  Shu Tian , Wenxin Huang , Junrui Hu , Huiling Wang , Zhipeng Zhang , Liying Xu , Junrong Li , Yao Sun . Exploring the frontiers of plant health: Harnessing NIR fluorescence and surface-enhanced Raman scattering modalities for innovative detection. Chinese Chemical Letters, 2025, 36(3): 110336-. doi: 10.1016/j.cclet.2024.110336
2. [2]
  Ce Liang , Qiuhui Sun , Adel Al-Salihy , Mengxin Chen , Ping Xu . Recent advances in crystal phase induced surface-enhanced Raman scattering. Chinese Chemical Letters, 2024, 35(9): 109306-. doi: 10.1016/j.cclet.2023.109306
3. [3]
  Chengde Wang , Liping Huang , Shanshan Wang , Lihao Wu , Yi Wang , Jun Dong . A distinction of gliomas at cellular and tissue level by surface-enhanced Raman scattering spectroscopy. Chinese Chemical Letters, 2024, 35(5): 109383-. doi: 10.1016/j.cclet.2023.109383
4. [4]
  Jie Ren , Hao Zong , Yaqun Han , Tianyi Liu , Shufen Zhang , Qiang Xu , Suli Wu . Visual identification of silver ornament by the structural color based on Mie scattering of ZnO spheres. Chinese Chemical Letters, 2024, 35(9): 109350-. doi: 10.1016/j.cclet.2023.109350
5. [5]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
6. [6]
  Deshuai Zhen , Chunlin Liu , Qiuhui Deng , Shaoqi Zhang , Ningman Yuan , Le Li , Yu Liu . A review of covalent organic frameworks for metal ion fluorescence sensing. Chinese Chemical Letters, 2024, 35(8): 109249-. doi: 10.1016/j.cclet.2023.109249
7. [7]
  Gongcheng Ma , Qihang Ding , Yuding Zhang , Yue Wang , Jingjing Xiang , Mingle Li , Qi Zhao , Saipeng Huang , Ping Gong , Jong Seung Kim . Palladium-free chemoselective probe for in vivo fluorescence imaging of carbon monoxide. Chinese Chemical Letters, 2024, 35(9): 109293-. doi: 10.1016/j.cclet.2023.109293
8. [8]
  Ying Xu , Chengying Shen , Hailong Yuan , Wei Wu . Mapping multiple phases in curcumin binary solid dispersions by fluorescence contrasting. Chinese Chemical Letters, 2024, 35(9): 109324-. doi: 10.1016/j.cclet.2023.109324
9. [9]
  Yuxin Li , Chengbin Liu , Qiuju Li , Shun Mao . Fluorescence analysis of antibiotics and antibiotic-resistance genes in the environment: A mini review. Chinese Chemical Letters, 2024, 35(10): 109541-. doi: 10.1016/j.cclet.2024.109541
10. [10]
  Ziyou Zhang , Te Ji , Hongliang Dong , Zhiqiang Chen , Zhi Su . Effect of coordination restriction on pressure-induced fluorescence evolution. Chinese Chemical Letters, 2024, 35(12): 109542-. doi: 10.1016/j.cclet.2024.109542
11. [11]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
12. [12]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
13. [13]
  Zhiqiang Liu , Qiang Gao , Wei Shen , Meifeng Xu , Yunxin Li , Weilin Hou , Hai-Wei Shi , Yaozuo Yuan , Erwin Adams , Hian Kee Lee , Sheng Tang . Removal and fluorescence detection of antibiotics from wastewater by layered double oxides/metal-organic frameworks with different topological configurations. Chinese Chemical Letters, 2024, 35(8): 109338-. doi: 10.1016/j.cclet.2023.109338
14. [14]
  Jia-Li Xie , Tian-Jin Xie , Yu-Jie Luo , Kai Mao , Cheng-Zhi Huang , Yuan-Fang Li , Shu-Jun Zhen . Octopus-like DNA nanostructure coupled with graphene oxide enhanced fluorescence anisotropy for hepatitis B virus DNA detection. Chinese Chemical Letters, 2024, 35(6): 109137-. doi: 10.1016/j.cclet.2023.109137
15. [15]
  Zhichao Zhou , Fuqian Chen , Xiaotong Xia , Dong Ye , Rong Zhou , Lei Li , Tao Deng , Zhenhua Ding , Fang Liu . Developing a fluorescence substrate for HRP-based diagnostic assays with superiorities over the commercial ADHP. Chinese Chemical Letters, 2024, 35(6): 108970-. doi: 10.1016/j.cclet.2023.108970
16. [16]
  Zixi Zou , Jingyuan Wang , Yian Sun , Qian Wang , Da-Hui Qu . Controlling molecular assembly on time scale: Time-dependent multicolor fluorescence for information encryption. Chinese Chemical Letters, 2024, 35(7): 108972-. doi: 10.1016/j.cclet.2023.108972
17. [17]
  Yiling Li , Zekun Gao , Xiuxiu Yue , Minhuan Lan , Xiuli Zheng , Benhua Wang , Shuang Zhao , Xiangzhi Song . FRET-based two-photon benzo[a] phenothiazinium photosensitizer for fluorescence imaging-guided photodynamic therapy. Chinese Chemical Letters, 2024, 35(7): 109133-. doi: 10.1016/j.cclet.2023.109133
18. [18]
  Peide Zhu , Yangjia Liu , Yaoyao Tang , Siqi Zhu , Xinyang Liu , Lei Yin , Quan Liu , Zhiqiang Yu , Quan Xu , Dixian Luo , Juncheng Wang . Bi-doped carbon quantum dots functionalized liposomes with fluorescence visualization imaging for tumor diagnosis and treatment. Chinese Chemical Letters, 2024, 35(4): 108689-. doi: 10.1016/j.cclet.2023.108689
19. [19]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
20. [20]
  Zheng Zhao , Ben Zhong Tang . An efficient strategy enabling solution processable thermally activated delayed fluorescence emitter with high horizontal dipole orientation. Chinese Journal of Structural Chemistry, 2024, 43(6): 100270-100270. doi: 10.1016/j.cjsc.2024.100270

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(1006)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142