Citation: Han Ying, Nie Cui-Yun, Jiang Shuo, Sun Jing, Yan Chao-Guo. Synthesis and characterization of bis-[1]rotaxanes via salen-bridged bis-pillar[5]arenes[J]. Chinese Chemical Letters, ;2020, 31(3): 725-728. doi: 10.1016/j.cclet.2019.09.014 shu

Synthesis and characterization of bis-[1]rotaxanes via salen-bridged bis-pillar[5]arenes

College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China

cgyan@yzu.edu.cn

Received Date: 17 July 2019
Revised Date: 29 August 2019
Accepted Date: 9 September 2019
Available Online: 10 September 2019

Figures(6)

The series of salen-bridged bis-pillar[1]arenes were conveniently prepared by condensation reaction of 5, 5'-methylenebis(2-hydroxybenzaldehyde) or 5, 5'-(propane-2, 2-diyl)bis(2-hydroxybenzaldehyde) with mono-amido-functionalized pillar[5]arenes containing different terminal aminoalkyl groups in refluxing ethanol. The ¹H NMR and 2D-NOESY spectra indicated that the salen-bridged bis-pillar[5]arenes with longer alkylene linker (n=3, 4, 6) formed the fascinating bis-[1]rotaxanes, while the salenbridged bis-pillar[5]arenes with short hydrazine and ethylenediamino linker (n=0, 2) predominately existed in free form. The single crystal structure of the bis-pillar[5]arene ambiguously indicated that two propylenediamino linker inserted in to two cavities of pillar[5]arene to form a novel bis-[1]rotaxanes.
- Pillar[5]arene,
- Salen,
- Rotaxane,
- Bis-[1]rotaxane,
- Interlocked molecule
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