Citation: Lu Bo, Liu Shuya, Yan Dongpeng. Recent advances in photofunctional polymorphs of molecular materials[J]. Chinese Chemical Letters, ;2019, 30(11): 1908-1922. doi: 10.1016/j.cclet.2019.09.012 shu

Recent advances in photofunctional polymorphs of molecular materials

Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China

Author Bio: Bo Lu is currently a Ph.D candidate under the supervision of Prof. Dongpeng Yan at the College of Chemistry, Beijing Normal University (BNU). He studied at Tsinghua University High School from 2009 to 2012. He obtained his bachelor's degree in materials science and engineering from Beijing University of Chemical Technology (BUCT) in 2016. His research interests focus on the design, synthesis and application of crystalline functional materials
Shuya Liu is currently a Ph.D candidate under thesupervision of Prof. Dongpeng Yan at the College of Chemistry, Beijing Normal University (BNU). She obtained her bachelor's degree in chemistry from Beijing Normal University (BNU) in 2018. Her research interests focus on crystalline phosphorescent materials
Dongpeng Yan obtained his Ph.D at Beijing University of Chemical Technology (BUCT) in 2012, and then became an associate professor at BUCT. In 2014, he moved to Beijing Normal University (BNU) as a full professor. In 2011 and 2013, as a visiting student/scholar, he studied at the Department of Chemistry, University of Cambridge and School of Pharmacy, University College London. His research topics are functional molecular materials, host-guest chemistry and photo/electrocatalysis. He has received an Award Nomination of Annual Figure among Chinese University Students (2011), a "Talent Model" Award in the Universities in Beijing (2010), the Tang Aoqing Chemical Scholarship (2011), and an Outstanding Doctoral Dissertation Prize in Beijing (2013), among many others

yandongpeng001@163.com

yandp@bnu.edu.cn

Received Date: 9 August 2019
Revised Date: 3 September 2019
Accepted Date: 9 September 2019
Available Online: 17 November 2019

Figures(12)

Recently, molecule-based luminescent materials have been drawing extensive attention due to their desirable properties and promising applications in the fields of sensors, lighting display and cell imaging. Crystalline polymorph is an intriguing phenomenon that the presence of multiple packing and aggregate architectures of the same molecular system. The studies on polymorphs for molecule-based fluorophores provide the opportunities to adjust the mode of molecular packing and photophysical properties, which will help to illustrate the structure-property relationship. In this review, we focus on the recent progress in various feasible methods of molecule-based crystalline polymorphism growth and their adjustable photofunctional properties, which will open up possibilities of variant optical applications. Firstly, several effective ways to prepare and screen polymorphs are sorted out. And then, we discuss the discrepant properties and multifunctional applications (such as sensors, laser and OFET). Finally, the development trends and future prospects of these polymorphs are also briefly introduced.
- Polymorphs,
- Organic molecular materials,
- Luminescence,
- Crystalline,
- Preparation,
- Optical applications,
- Structure-property relationship
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