Citation: Zhan Kan, Lu Ping, Dong Jian, Hou Xu. Polymer hydrogel confined palladium nanoparticles as recyclable catalysts for Suzuki and Heck cross-coupling reactions[J]. Chinese Chemical Letters, ;2020, 31(6): 1630-1634. doi: 10.1016/j.cclet.2019.09.006 shu

Polymer hydrogel confined palladium nanoparticles as recyclable catalysts for Suzuki and Heck cross-coupling reactions

Zhan Kan ^a,b,*, ,
Lu Ping ^a ,
Dong Jian ^a,*, ,
Hou Xu ^b

a.
School of Chemistry and Chemical Engineering, Shaoxing University, Shaoxing 312000, China
b.
School of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

kanzhan@xmu.edu.cn

jiandong@usx.edu.cn

Received Date: 16 July 2019
Revised Date: 23 August 2019
Accepted Date: 5 September 2019
Available Online: 5 September 2019

Figures(3)

Reusable palladium nanoparticles highly dispersed in porous and hydrophilic interpenetrating polymer networks (IPN), i.e., Pd@IPN hybrid gels, are employed for catalysis of Suzuki and Heck coupling reactions. Good yields are obtained with high turnover frequencies when the reactions are run with very low Pdloadings. The use of IPN gives better recyclability than that of crosslinked polyvinyl alcohol alone. The polymer networks allow the reactants to have easy access to the Pd metals. The catalysts combine high activity with the reusability offered by the heterogeneous system, without the need for strong coordination or chelating ligands.
- Nanoparticle,
- Catalysis,
- Hydrogels,
- Palladium,
- Water
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