Citation: Wang Chen, Liu Yubei, Zhou Tao, Huang Mingjie, Mao Juan, Wu Xiaohui. Efficient decomposition of sulfamethoxazole in a novel neutral Fered-Fenton like/oxalate system based on effective heterogeneous-homogeneous iron cycle[J]. Chinese Chemical Letters, ;2019, 30(12): 2231-2235. doi: 10.1016/j.cclet.2019.08.055 shu

Efficient decomposition of sulfamethoxazole in a novel neutral Fered-Fenton like/oxalate system based on effective heterogeneous-homogeneous iron cycle

Wang Chen ^a,b,1 ,
Liu Yubei ^a,1 ,
Zhou Tao ^a,*, ,
Huang Mingjie ^a ,
Mao Juan ^a,b ,
Wu Xiaohui ^a,b,*,

a.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
Key Laboratory of Water and Wastewater Treatment(HUST), MOHURD, Wuhan 430074, China

zhoutao@hust.edu.cn

xhwoo@hust.edu.cn

Received Date: 18 July 2019
Revised Date: 29 August 2019
Accepted Date: 30 August 2019
Available Online: 31 December 2019

Figures(4)

In this study, efficient sulfamethoxazole (SMX) degradation was demonstrated in a novel neutral Fered-Fenton like/oxalate (electro-Fe²⁺/PDS/Ox, Fered-FL/Ox) system adopting pre-anodized Ti@TiO₂ cathode. Optimization of operational parameters was conducted and the whole reaction mechanism based on the critical solid-liquid interfacial reactions was explored. An efficient neutral heterogeneous-homogenous iron cycle would exist in the Fered-FL/Ox system, depending on the formation of specific C—O—Ti bonds through the inner sphere surface complex (ISSC) of Fe(C₂O₄)₃^3-. It would induce ultrafast electron transfer from the cathode to the Fe^Ⅲ core, effectively accelerating the neutral Fenton-like reactions and complete mineralization of SMX with relative low dosage of ferrous catalyst and applied voltage. The result of this study is expected to supply a good alternative in treating complex neutral industrial wastewaters
- Fered-fenton like,
- Heterogeneous iron cycle,
- Iron-oxalate complexes,
- Surface electron transfer,
- Persulfate
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