Citation: Li Ting, Sun Jiefang, Liu Jinyuan, Dong Baolei, Zhao Huachao, Qiao Xiaoting, Shan Wencong, Zhang Jing, Shao Bing. Constructing boronate-bridged core-satellite gold nanoassembly and its application in high sensitive colorimetric detection of benzoyl peroxide residues in food matrices[J]. Chinese Chemical Letters, ;2020, 31(2): 439-442. doi: 10.1016/j.cclet.2019.08.051 shu

Constructing boronate-bridged core-satellite gold nanoassembly and its application in high sensitive colorimetric detection of benzoyl peroxide residues in food matrices

Li Ting ^a,b,1 ,
Sun Jiefang ^b,1 ,
Liu Jinyuan ^a,b ,
Dong Baolei ^c ,
Zhao Huachao ^d ,
Qiao Xiaoting ^b ,
Shan Wencong ^c ,
Zhang Jing ^b ,
Shao Bing ^a,b,*

a.
School of Public Health, Capital Medical University, Beijing 100069, China
b.
Beijing Key Laboratory of Diagnostic and Traceability Technologies for Food Poisoning, Beijing Center for Disease Prevention and Control, Beijing 100013, China
c.
Beijing Advanced Innovation Center for Food Nutrition and Human Health, China Agricultural University, Beijing 100193, China
d.
College of Chemical Engineering and Materials Science, Tianjin University of Science and Technology, Tianjin 300457, China

shaobingch@sina.com

Received Date: 27 May 2019
Revised Date: 26 August 2019
Accepted Date: 27 August 2019
Available Online: 29 August 2019

Figures(4)

Here, a new designed core/satellite gold nanoprobe was developed for detecting trace mount of benzoyl peroxide (BPO) based on its deboronation. This gold nanoassembly (the BE-AuNPs_12/65) was constructed via borate ester formation between large 4-mercaptophenylboronic acid (MPBA) modified AuNPs (the MPBA-AuNPs₆₅, as cores)and smalldopamine modifiedAuNPs (theDPA-AuNPs₁₂, assatellites).Particularly, upon addition of BPO, it would trigger the deboronation for the BE-AuNPs_12/65 probes accompanying with distinct color changes from blue, purple to wine red, which implied the disassembly of the core/satellite nanostructure after the breakage of carbon to boron chemical bond. By measuring the absorbance ratio at 665 nm and 545 nm, quantification of BPO was achieved in the range of 10.0-100.0 nmol/L, which could also be easilyobserved bynaked eyes. The nanoprobeutilized a boronate deprotection mechanism and the LSPR properties of AuNPs to provide high selectivity for detecting BPO over similar ROS/RNS with the limit of detection as low as 7.2 nmol/L. The practical applicability of this assay was verified through successful determining BPO in flour samples, which demonstrated its great potentials in food safety field.
- Benzoyl peroxide,
- Colorimetric detection,
- Gold nanoassembly,
- Deboronation,
- Food safety
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